IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v202y2023icp154-171.html
   My bibliography  Save this article

Insight into kinetic and Thermodynamic Analysis methods for lignocellulosic biomass pyrolysis

Author

Listed:
  • Zhang, Zhiyi
  • Li, Yingkai
  • Luo, Laipeng
  • Yellezuome, Dominic
  • Rahman, Md Maksudur
  • Zou, Jianfeng
  • Hu, Hangli
  • Cai, Junmeng

Abstract

Pyrolysis is particularly attractive because it can convert lignocellulosic biomass into bio-oil, gases and solid charcoal in an efficient and environmentally friendly way. Determining the kinetic and thermodynamic parameters is fundamental to elucidate the reaction mechanisms and optimize biomass pyrolysis processes. The applicability and accuracy of kinetic and thermodynamic methods are systematically studied by analyzing theoretically simulated processes which simulate biomass pyrolysis processes and using statistical analyses. In terms of activation energy calculation, the Friedman method is capable of providing accurate activation energies, whereas the KAS and FWO isoconversional methods lead to some systematic errors in the resultant activation energies. The accuracy of the Kissinger method for estimating the frequency factor is dependent on the variation degree of kinetic parameters with conversion. The conventional method for determining thermodynamic parameters is based on the conversion rate peak temperature, which has no theoretical basis. Therefore, the concept of effective thermodynamic parameters is proposed, which are dependent on conversion and heating rate. And the thermodynamic analysis of the simulated processes is comprehensively investigated. Results revealed that the accuracy of the resulting thermodynamic parameters from the conventional method is dependent on the variation degree of kinetic parameters with conversion. It is expected that this study will provide an analysis framework and methodological guideline for the kinetic and thermodynamic analyses of biomass pyrolysis.

Suggested Citation

  • Zhang, Zhiyi & Li, Yingkai & Luo, Laipeng & Yellezuome, Dominic & Rahman, Md Maksudur & Zou, Jianfeng & Hu, Hangli & Cai, Junmeng, 2023. "Insight into kinetic and Thermodynamic Analysis methods for lignocellulosic biomass pyrolysis," Renewable Energy, Elsevier, vol. 202(C), pages 154-171.
    • Handle: RePEc:eee:renene:v:202:y:2023:i:c:p:154-171
    DOI: 10.1016/j.renene.2022.11.072
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122017128
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.11.072?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Luo, Laipeng & Zhang, Zhiyi & Li, Chong & Nishu, & He, Fang & Zhang, Xingguang & Cai, Junmeng, 2021. "Insight into master plots method for kinetic analysis of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 233(C).
    2. Mumbach, Guilherme Davi & Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Domenico, Michele Di & Arias, Santiago & Pacheco, Jose Geraldo A. & Marangoni, Cintia & Machado, Ricardo Anton, 2022. "Prospecting pecan nutshell pyrolysis as a source of bioenergy and bio-based chemicals using multicomponent kinetic modeling, thermodynamic parameters estimation, and Py-GC/MS analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    3. Cai, Junmeng & He, Yifeng & Yu, Xi & Banks, Scott W. & Yang, Yang & Zhang, Xingguang & Yu, Yang & Liu, Ronghou & Bridgwater, Anthony V., 2017. "Review of physicochemical properties and analytical characterization of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 309-322.
    4. Merdun, Hasan & Laougé, Zakari Boubacar, 2021. "Kinetic and thermodynamic analyses during co-pyrolysis of greenhouse wastes and coal by TGA," Renewable Energy, Elsevier, vol. 163(C), pages 453-464.
    5. Qing Yang & Hewen Zhou & Pietro Bartocci & Francesco Fantozzi & Ondřej Mašek & Foster A. Agblevor & Zhiyu Wei & Haiping Yang & Hanping Chen & Xi Lu & Guoqian Chen & Chuguang Zheng & Chris P. Nielsen &, 2021. "Prospective contributions of biomass pyrolysis to China’s 2050 carbon reduction and renewable energy goals," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    6. Tong, Wei & Cai, Zelong & Liu, Qingcai & Ren, Shan & Kong, Ming, 2020. "Effect of pyrolysis temperature on bamboo char combustion: Reactivity, kinetics and thermodynamics," Energy, Elsevier, vol. 211(C).
    7. Ciuta, Simona & Patuzzi, Francesco & Baratieri, Marco & Castaldi, Marco J., 2018. "Enthalpy changes during pyrolysis of biomass: Interpretation of intraparticle gas sampling," Applied Energy, Elsevier, vol. 228(C), pages 1985-1993.
    8. Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Siddiqi, Hammad & Bal, Manisha & Kumari, Usha & Meikap, B.C., 2020. "In-depth physiochemical characterization and detailed thermo-kinetic study of biomass wastes to analyze its energy potential," Renewable Energy, Elsevier, vol. 148(C), pages 756-771.
    10. Vikraman, V. Karuppasamy & Boopathi, G. & Kumar, D. Praveen & Mythili, R. & Subramanian, P., 2021. "Non-isothermal pyrolytic kinetics of milk dust powder using thermogravimetric analysis," Renewable Energy, Elsevier, vol. 180(C), pages 838-849.
    11. Yuan, Xinsong & He, Tao & Cao, Hongliang & Yuan, Qiaoxia, 2017. "Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods," Renewable Energy, Elsevier, vol. 107(C), pages 489-496.
    12. Cai, Junmeng & Xu, Di & Dong, Zhujun & Yu, Xi & Yang, Yang & Banks, Scott W. & Bridgwater, Anthony V., 2018. "Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2705-2715.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ahmed, Gaffer & Kishore, Nanda, 2024. "Synergistic effects on properties of biofuel and biochar produced through co-feed pyrolysis of Erythrina indica and Azadirachta indica biomass," Renewable Energy, Elsevier, vol. 227(C).
    2. Ahmed, Gaffer & Kishore, Nanda, 2023. "Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products," Renewable Energy, Elsevier, vol. 219(P1).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Luo, Laipeng & Zhang, Zhiyi & Li, Chong & Nishu, & He, Fang & Zhang, Xingguang & Cai, Junmeng, 2021. "Insight into master plots method for kinetic analysis of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 233(C).
    2. Chen, Long & Wang, Hong & Tu, Zhi & Hu, Jian & Wu, Fangfang, 2024. "Renewable fuel and value-added chemicals potential of reed straw waste (RSW) by pyrolysis: Kinetics, thermodynamics, products characterization, and biochar application for malachite green removal," Renewable Energy, Elsevier, vol. 229(C).
    3. Zhang, Pin & Li, Chong & Xu, Dong & Yellezuome, Dominic & Wang, Jiong & Cai, Junmeng, 2023. "Insight into kinetics and thermodynamics of distillers’ dried grains with solubles (DDGS) combustion using an approach simultaneously determining frequency factor and reaction model," Renewable Energy, Elsevier, vol. 219(P2).
    4. Zhang, Zhiqing & Duan, Hanqi & Zhang, Youjun & Guo, Xiaojuan & Yu, Xi & Zhang, Xingguang & Rahman, Md. Maksudur & Cai, Junmeng, 2020. "Investigation of kinetic compensation effect in lignocellulosic biomass torrefaction: Kinetic and thermodynamic analyses," Energy, Elsevier, vol. 207(C).
    5. Vikraman, V. Karuppasamy & Boopathi, G. & Kumar, D. Praveen & Mythili, R. & Subramanian, P., 2021. "Non-isothermal pyrolytic kinetics of milk dust powder using thermogravimetric analysis," Renewable Energy, Elsevier, vol. 180(C), pages 838-849.
    6. Kumar, Rakesh & Dubey, Pratik & Mondal, Monoj Kumar, 2024. "Analysis of kinetics, mechanism, thermodynamic properties and product distribution for pyrolysis of Ni–Fe impregnated coconut husk," Renewable Energy, Elsevier, vol. 222(C).
    7. Nishu, & Tang, Songbiao & Mei, Wenjie & Yang, Juntao & Wang, Zhongming & Yang, Gaixiu, 2024. "Effect of anaerobic digestion pretreatment on pyrolysis of distillers’ grain: Product distribution, kinetics and thermodynamics analysis," Renewable Energy, Elsevier, vol. 221(C).
    8. Cardarelli, Alessandro & Pinzi, Sara & Barbanera, Marco, 2022. "Effect of torrefaction temperature on spent coffee grounds thermal behaviour and kinetics," Renewable Energy, Elsevier, vol. 185(C), pages 704-716.
    9. Duan, Hanqi & Zhang, Zhiqing & Rahman, Md Maksudur & Guo, Xiaojuan & Zhang, Xingguang & Cai, Junmeng, 2020. "Insight into torrefaction of woody biomass: Kinetic modeling using pattern search method," Energy, Elsevier, vol. 201(C).
    10. Yang, Y. & Heaven, S. & Venetsaneas, N. & Banks, C.J. & Bridgwater, A.V., 2018. "Slow pyrolysis of organic fraction of municipal solid waste (OFMSW): Characterisation of products and screening of the aqueous liquid product for anaerobic digestion," Applied Energy, Elsevier, vol. 213(C), pages 158-168.
    11. Kung, Chih-Chun & Fei, Chengcheng J. & McCarl, Bruce A. & Fan, Xinxin, 2022. "A review of biopower and mitigation potential of competing pyrolysis methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    12. Zhang, Yuanbo & Zhang, Yutao & Li, Yaqing & Shi, Xueqiang & Che, Bo, 2022. "Determination of ignition temperature and kinetics and thermodynamics analysis of high-volatile coal based on differential derivative thermogravimetry," Energy, Elsevier, vol. 240(C).
    13. Yang, Yantao & Qu, Xia & Huang, Guorun & Ren, Suxia & Dong, Lili & Sun, Tanglei & Liu, Peng & Li, Yanling & Lei, Tingzhou & Cai, Junmeng, 2023. "Insight into lignocellulosic biomass torrefaction kinetics with case study of pinewood sawdust torrefaction," Renewable Energy, Elsevier, vol. 215(C).
    14. Hu, Mao & Guo, Kai & Zhou, Haiqin & Shen, Fei & Zhu, Wenkun & Dai, Lichun, 2024. "Insights into the kinetics, thermodynamics and evolved gases for the pyrolysis of freshly excreted and solid-liquid separated swine manures," Energy, Elsevier, vol. 288(C).
    15. Hou, Yanmei & Gao, Qi & He, Yuyu & Ni, Liangmeng & Ren, Hao & Su, Mengfu & Rong, Shaowen & Liu, Zhijia, 2023. "Pyrolysis characteristics and gaseous products of bamboo shoot shells under N2 and CO2 atmospheres," Renewable Energy, Elsevier, vol. 215(C).
    16. Chai, Meiyun & Xie, Li & Yu, Xi & Zhang, Xingguang & Yang, Yang & Rahman, Md. Maksudur & Blanco, Paula H. & Liu, Ronghou & Bridgwater, Anthony V. & Cai, Junmeng, 2021. "Poplar wood torrefaction: Kinetics, thermochemistry and implications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    17. Chen, Xuejiao & Wang, Hong & Yang, Rui & Lin, Wei & Qi, Zhiyong & Zhang, Dongdong, 2024. "Effect of severe torrefaction by superheated steam on pinewood pyrolysis kinetics and pyrolytic oil compounds," Renewable Energy, Elsevier, vol. 227(C).
    18. Chen, Wei-Hsin & Felix, Charles B., 2024. "Thermo-kinetics study of microalgal biomass in oxidative torrefaction followed by machine learning regression and classification approaches," Energy, Elsevier, vol. 301(C).
    19. Sun, Ce & Tan, Haiyan & Zhang, Yanhua, 2023. "Simulating the pyrolysis interactions among hemicellulose, cellulose and lignin in wood waste under real conditions to find the proper way to prepare bio-oil," Renewable Energy, Elsevier, vol. 205(C), pages 851-863.
    20. Kuang, Yucen & Jiang, Tao & Wu, Longqi & Liu, Xiaoqian & Yang, Xuke & Sher, Farooq & Wei, Zhifang & Zhang, Shengfu, 2023. "High-temperature rheological behavior and non-isothermal pyrolysis mechanism of macerals separated from different coals," Energy, Elsevier, vol. 277(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:202:y:2023:i:c:p:154-171. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.