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Synergistic effects on properties of biofuel and biochar produced through co-feed pyrolysis of Erythrina indica and Azadirachta indica biomass

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  • Ahmed, Gaffer
  • Kishore, Nanda

Abstract

Co-feed pyrolysis is a thermochemical conversion process that entails the simultaneous or sequential decomposition of various feedstock in an oxygen-free environment, concurrently improving the quality of the end products. The technique is widely used to produce a range of valuable products, including biofuels, chemicals and biochar, capitalizing on the synergies between various feedstock. The current study focuses on the synergistic effects of co-feed pyrolysis of Erythrina indica (EI) and Azadirachta indica (AI) biomass at different co-feed ratios (EI:AI) of 1:4, 1:3, 1:2, 1:1, 2:1, 3:1 and 4:1 on weight basis. The reactions were carried out at a temperature of 600 °C under a pressure of 1 bar using nitrogen as inert atmosphere. The bio-oil yield produced through the co-feed pyrolysis reactions ranged from 29.51 to 32.40 % by weight, while the biochar and non-condensable gases yields ranged from 38.25 to 42.48 % and 26.90 to 30.73 % by weight, respectively. Positive synergistic effects of co-feed pyrolysis led to a notable enhancement in physicochemical properties of the fuel phase, especially by virtue of calorific value, density and presence of low mol. wt. components when compared to their individual counterparts. Specifically, the fuel phase obtained at 1:1 co-feed ratio exhibited the peak calorific value of 36.80 MJ/kg along with lowest density of 0.82 g/ml and pH of 3.58 which is the pinnacle accomplishment of this work; and comparable with commercial gasoline. Gas chromatography and mass spectroscopy of biofuels revealed alkanes, alkenes, alcohols, aromatics, esters, nitro compounds and organosilicons as their main compounds. Specific compounds, including cyclopentane, methyl-, 1-cyclohexyl-2-propen-1-ol and 1-pentene, 3-methyl, are the most significant compounds at co-feed ratio of 1:1. Biochar produced at co-feed ratio of 1:1 also depicted excellent physiochemical properties with the highest elemental carbon of 79.23 wt % and lowest oxygen and hydrogen contents of 18.49 wt % and 2.28 wt %, respectively with a maximum calorific value of 29.23 MJ/kg; which can be utilized as solid fuels. The biochar produced from the co-feed pyrolysis reactions also possesses highly porous structure which can be useful as a soil conditioner, carbon sequestration water filtration or wastewater treatment. Additionally, non-condensable gases composed of 7.45 vol % hydrogen, 34.26 vol % carbon monoxide, 21.32 vol % methane and 36.97 vol % carbon dioxide when co-feed ratio is 1:1.

Suggested Citation

  • Ahmed, Gaffer & Kishore, Nanda, 2024. "Synergistic effects on properties of biofuel and biochar produced through co-feed pyrolysis of Erythrina indica and Azadirachta indica biomass," Renewable Energy, Elsevier, vol. 227(C).
    • Handle: RePEc:eee:renene:v:227:y:2024:i:c:s0960148124005731
    DOI: 10.1016/j.renene.2024.120508
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    1. Zhang, Zhiyi & Li, Yingkai & Luo, Laipeng & Yellezuome, Dominic & Rahman, Md Maksudur & Zou, Jianfeng & Hu, Hangli & Cai, Junmeng, 2023. "Insight into kinetic and Thermodynamic Analysis methods for lignocellulosic biomass pyrolysis," Renewable Energy, Elsevier, vol. 202(C), pages 154-171.
    2. Ahmed, Gaffer & Kishore, Nanda, 2023. "Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products," Renewable Energy, Elsevier, vol. 219(P1).
    3. Akhtar, Javaid & Saidina Amin, NorAishah, 2012. "A review on operating parameters for optimum liquid oil yield in biomass pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5101-5109.
    4. Aghbashlo, Mortaza & Almasi, Fatemeh & Jafari, Ali & Nadian, Mohammad Hossein & Soltanian, Salman & Lam, Su Shiung & Tabatabaei, Meisam, 2021. "Describing biomass pyrolysis kinetics using a generic hybrid intelligent model: A critical stage in sustainable waste-oriented biorefineries," Renewable Energy, Elsevier, vol. 170(C), pages 81-91.
    5. Nawaz, Ahmad & Kumar, Pradeep, 2022. "Pyrolysis behavior of low value biomass (Sesbania bispinosa) to elucidate its bioenergy potential: Kinetic, thermodynamic and prediction modelling using artificial neural network," Renewable Energy, Elsevier, vol. 200(C), pages 257-270.
    6. Kartal, Furkan & Dalbudak, Yağmur & Özveren, Uğur, 2023. "Prediction of thermal degradation of biopolymers in biomass under pyrolysis atmosphere by means of machine learning," Renewable Energy, Elsevier, vol. 204(C), pages 774-787.
    7. Sun, Yifan & Li, Chao & Zhang, Shu & Li, Qiaoling & Gholizadeh, Mortaza & Wang, Yi & Hu, Song & Xiang, Jun & Hu, Xun, 2021. "Pyrolysis of soybean residue: Understanding characteristics of the products," Renewable Energy, Elsevier, vol. 174(C), pages 487-500.
    8. Himeur, Yassine & Ghanem, Khalida & Alsalemi, Abdullah & Bensaali, Faycal & Amira, Abbes, 2021. "Artificial intelligence based anomaly detection of energy consumption in buildings: A review, current trends and new perspectives," Applied Energy, Elsevier, vol. 287(C).
    9. Tian, Jinfang & Yu, Longguang & Xue, Rui & Zhuang, Shan & Shan, Yuli, 2022. "Global low-carbon energy transition in the post-COVID-19 era," Applied Energy, Elsevier, vol. 307(C).
    10. Raheem, Abdul & Wan Azlina, W.A.K.G. & Taufiq Yap, Y.H. & Danquah, Michael K. & Harun, Razif, 2015. "Thermochemical conversion of microalgal biomass for biofuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 990-999.
    11. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
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