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Comprehensive study on thermochemical putrefaction of Delonix Regia in non-catalytic, catalytic and hydro-catalytic pyrolysis atmospheres

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  • Kawale, Harshal D.
  • Kishore, Nanda

Abstract

The need for cleaner energy and faster depleting conventional non-renewable energy resources gave rise to the quest for sustainable sources and their conversion technologies for renewable energy production. The H/C ratio is essential in estimating the fuel potential of any feedstock. In this study, authors have considered a biomass, Delonix Regia (DR), whose H/C ratio is 1.56 which is higher than other competitive biomass such as pinewood sawdust (1.43) and of coal (1–1.4). Thus, selection of DR based on its H/C value formulated the objective of this work as non-catalytic, catalytic and hydro-catalytic pyrolysis of DR at 600 °C in a tubular reactor. Further, the use of zeolite Y, sodium catalyst for the cases of catalytic and hydro-catalytic experiments added novelty to this work because this catalyst is extensively used as cracking catalyst for fractionating the high-boiling petroleum crude into lighter and useful fractions such as gasoline. Accordingly it is expected that this catalyst shall play similar role in the present study for fractionating the high volatile pyrolysis vapours into smaller fractions during the pyrolysis reaction. Thus, the novelty of this work is catalytic and hydro-pyrolysis of a rarely researched biomass using an economical zeolite Y, sodium catalyst. The HHV of bio-oils by non-catalytic, catalytic and hydro-pyrolysis of DR found to be 16.5 MJ/kg, 18.14 MJ/kg and 20.65 MJ/kg, respectively. GC-MS analyses indicated the formation of several value-added chemicals such as benzene, cresol, catechol etc. by hydro-pyrolysis. The fraction of furan in bio-oil by hydro-catalytic pyrolysis decreased substantially whereas the aromatics fraction increased compared to the other two cases.

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  • Kawale, Harshal D. & Kishore, Nanda, 2021. "Comprehensive study on thermochemical putrefaction of Delonix Regia in non-catalytic, catalytic and hydro-catalytic pyrolysis atmospheres," Renewable Energy, Elsevier, vol. 173(C), pages 223-236.
    • Handle: RePEc:eee:renene:v:173:y:2021:i:c:p:223-236
    DOI: 10.1016/j.renene.2021.03.139
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    References listed on IDEAS

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    1. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    2. Kawale, Harshal D. & Kishore, Nanda, 2019. "Production of hydrocarbons from a green algae (Oscillatoria) with exploration of its fuel characteristics over different reaction atmospheres," Energy, Elsevier, vol. 178(C), pages 344-355.
    3. Anqing Zheng & Liqun Jiang & Zengli Zhao & Zhen Huang & Kun Zhao & Guoqiang Wei & Haibin Li, 2017. "Catalytic fast pyrolysis of lignocellulosic biomass for aromatic production: chemistry, catalyst and process," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 6(3), May.
    4. Ali Imran & Eddy A. Bramer & Kulathuiyer Seshan & Gerrit Brem, 2016. "Catalytic Flash Pyrolysis of Biomass Using Different Types of Zeolite and Online Vapor Fractionation," Energies, MDPI, vol. 9(3), pages 1-17, March.
    5. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
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    1. Rammohan, Draksharapu & Kishore, Nanda & Uppaluri, Ramagopal V.S., 2022. "Pyro–catalytic co–pyrolysis of Delonix regia and butyl rubber tube: Kinetic modelling and thermodynamic insights," Renewable Energy, Elsevier, vol. 201(P1), pages 194-203.
    2. Ahmed, Gaffer & Kishore, Nanda, 2023. "Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products," Renewable Energy, Elsevier, vol. 219(P1).

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