IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v201y2022ip1p194-203.html
   My bibliography  Save this article

Pyro–catalytic co–pyrolysis of Delonix regia and butyl rubber tube: Kinetic modelling and thermodynamic insights

Author

Listed:
  • Rammohan, Draksharapu
  • Kishore, Nanda
  • Uppaluri, Ramagopal V.S.

Abstract

The target of the proposed work was to compute the kinetic modelling (KM) and thermodynamic insights (TI) for the pyro-catalytic co-pyrolysis (PCCP) of Delonix regia (DR) and Butyl rubber tube (BRT). For PCCP of DR and BRT (1:1 co-feed), three different types of catalysts were utilized: zeolite (Na–Y), noble metal on activated carbon (10 wt % Pt/C), and metal oxide (1:1 wt % TiO2–ZnO) catalysts of loading between 30 and 10 wt %. For computing KM and TI, several iso-conversional models such as Friedman (FM), Flynn–Wall– Ozawa (FWO), Kissinger–Akahira–Sunose (KAS), Starink (STK), and Distributed Activation Energy Method (DAEM) were applied. At DR:BRT:Na-Y (1:1:10 wt %), the FWO model ascertained the lowest average values of activation energy Eα (kJ/mol) and pre-exponential factor A (s−1) as 180 and 5.95E+16, respectively whereas ΔH (kJ/mol) and ΔG (kJ/mol) as 175 and 180 for TI correspondingly.

Suggested Citation

  • Rammohan, Draksharapu & Kishore, Nanda & Uppaluri, Ramagopal V.S., 2022. "Pyro–catalytic co–pyrolysis of Delonix regia and butyl rubber tube: Kinetic modelling and thermodynamic insights," Renewable Energy, Elsevier, vol. 201(P1), pages 194-203.
    • Handle: RePEc:eee:renene:v:201:y:2022:i:p1:p:194-203
    DOI: 10.1016/j.renene.2022.10.099
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122016019
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.10.099?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Liew, Jia Xin & Loy, Adrian Chun Minh & Chin, Bridgid Lai Fui & AlNouss, Ahmed & Shahbaz, Muhammad & Al-Ansari, Tareq & Govindan, Rajesh & Chai, Yee Ho, 2021. "Synergistic effects of catalytic co-pyrolysis of corn cob and HDPE waste mixtures using weight average global process model," Renewable Energy, Elsevier, vol. 170(C), pages 948-963.
    2. Kawale, Harshal D. & Kishore, Nanda, 2021. "Comprehensive study on thermochemical putrefaction of Delonix Regia in non-catalytic, catalytic and hydro-catalytic pyrolysis atmospheres," Renewable Energy, Elsevier, vol. 173(C), pages 223-236.
    3. Kawale, Harshal D. & Kishore, Nanda, 2019. "Production of hydrocarbons from a green algae (Oscillatoria) with exploration of its fuel characteristics over different reaction atmospheres," Energy, Elsevier, vol. 178(C), pages 344-355.
    4. Alam, Mahboob & Rammohan, Draksharapu & Peela, Nageswara Rao, 2021. "Catalytic co-pyrolysis of wet-torrefied bamboo sawdust and plastic over the zeolite H-ZSM-5: Synergistic effects and kinetics," Renewable Energy, Elsevier, vol. 178(C), pages 608-619.
    5. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ahmed, Gaffer & Kishore, Nanda, 2023. "Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products," Renewable Energy, Elsevier, vol. 219(P1).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chakraborty, Sourabh & Mohanty, Kaustubha & Vinu, Ravikrishnan, 2024. "Co-pyrolysis of bamboo biomass with polypropylene coverall: Distributed activation energy modeling and pyrolysate composition studies," Renewable Energy, Elsevier, vol. 220(C).
    2. Ahmed, Gaffer & Kishore, Nanda, 2023. "Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products," Renewable Energy, Elsevier, vol. 219(P1).
    3. Kawale, Harshal D. & Kishore, Nanda, 2021. "Comprehensive study on thermochemical putrefaction of Delonix Regia in non-catalytic, catalytic and hydro-catalytic pyrolysis atmospheres," Renewable Energy, Elsevier, vol. 173(C), pages 223-236.
    4. Ahmed, Gaffer & Kishore, Nanda, 2024. "Synergistic effects on properties of biofuel and biochar produced through co-feed pyrolysis of Erythrina indica and Azadirachta indica biomass," Renewable Energy, Elsevier, vol. 227(C).
    5. Kostyniuk, Andrii & Likozar, Blaž, 2024. "Wet torrefaction of biomass waste into high quality hydrochar and value-added liquid products using different zeolite catalysts," Renewable Energy, Elsevier, vol. 227(C).
    6. Tariq, Rumaisa & Mohd Zaifullizan, Yasmin & Salema, Arshad Adam & Abdulatif, Atiqah & Ken, Loke Shun, 2022. "Co-pyrolysis and co-combustion of orange peel and biomass blends: Kinetics, thermodynamic, and ANN application," Renewable Energy, Elsevier, vol. 198(C), pages 399-414.
    7. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
    8. Mariyam, Sabah & Shahbaz, Muhammad & Al-Ansari, Tareq & Mackey, Hamish. R & McKay, Gordon, 2022. "A critical review on co-gasification and co-pyrolysis for gas production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    9. Dessì, Federica & Mureddu, Mauro & Ferrara, Francesca & Fermoso, Javier & Orsini, Alessandro & Sanna, Aimaro & Pettinau, Alberto, 2021. "Thermogravimetric characterisation and kinetic analysis of Nannochloropsis sp. and Tetraselmis sp. microalgae for pyrolysis, combustion and oxy-combustion," Energy, Elsevier, vol. 217(C).
    10. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.
    11. Chen, Chunxiang & Fan, Dianzhao & Zhao, Jian & Qi, Qianhao & Huang, Xiaodong & Zeng, Tianyang & Bi, Yingxin, 2022. "Study on microwave-assisted co-pyrolysis and bio-oil of Chlorella vulgaris with high-density polyethylene under activated carbon," Energy, Elsevier, vol. 247(C).
    12. Al-Rumaihi, Aisha & Shahbaz, Muhammad & Mckay, Gordon & Mackey, Hamish & Al-Ansari, Tareq, 2022. "A review of pyrolysis technologies and feedstock: A blending approach for plastic and biomass towards optimum biochar yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    13. Chen, Wei-Hsin & Farooq, Wasif & Shahbaz, Muhammad & Naqvi, Salman Raza & Ali, Imtiaz & Al-Ansari, Tareq & Saidina Amin, Nor Aishah, 2021. "Current status of biohydrogen production from lignocellulosic biomass, technical challenges and commercial potential through pyrolysis process," Energy, Elsevier, vol. 226(C).
    14. Sahoo, Abhisek & Saini, Komal & Negi, Shweta & Kumar, Jitendra & Pant, Kamal K. & Bhaskar, Thallada, 2022. "Inspecting the bioenergy potential of noxious Vachellia nilotica weed via pyrolysis: Thermo-kinetic study, neural network modeling and response surface optimization," Renewable Energy, Elsevier, vol. 185(C), pages 386-402.
    15. Chen, Xuejiao & Wang, Hong & Yang, Rui & Lin, Wei & Qi, Zhiyong & Zhang, Dongdong, 2024. "Effect of severe torrefaction by superheated steam on pinewood pyrolysis kinetics and pyrolytic oil compounds," Renewable Energy, Elsevier, vol. 227(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:201:y:2022:i:p1:p:194-203. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.