IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v179y2021icp351-358.html
   My bibliography  Save this article

A sustainable biorefinery strategy: Conversion and fractionation in a facile biphasic system towards integrated lignocellulose valorizations

Author

Listed:
  • Zhang, Qilin
  • Guo, Zongwei
  • Zeng, Xianhai
  • Ramarao, Bandaru
  • Xu, Feng

Abstract

A sustainable and integrated biorefinery strategy was achieved by a facile biphasic system, ferric trichloride (FeCl3) solution assisted by methyl isobutyl ketone (MIBK), yielding multiple products: furfural, sugars, and lignin nano-particles simultaneously. For the highest yield of furfural, the conditions were optimized resulting in 75.55% and over 69.38% of the yields from xylose and some typical biomasses respectively. Both the catalyst and MIBK can be recycled. Eucalyptus was lucubrated on the valorizations of three major-components with 75.18% of furfural yield, 97.54% of cellulase digestibility from the residue and lignin nano-particles. Meanwhile, the regularities of biomass degradation under this biphasic system were summarized as well as high digestibility which was resulted by hemicellulose and lignin removal in cooperation with the amount of the cellulase binding sites. Based on the proposed biorefinery strategy, 65.82% of the initial mass can be valorized into high-value end-products.

Suggested Citation

  • Zhang, Qilin & Guo, Zongwei & Zeng, Xianhai & Ramarao, Bandaru & Xu, Feng, 2021. "A sustainable biorefinery strategy: Conversion and fractionation in a facile biphasic system towards integrated lignocellulose valorizations," Renewable Energy, Elsevier, vol. 179(C), pages 351-358.
    • Handle: RePEc:eee:renene:v:179:y:2021:i:c:p:351-358
    DOI: 10.1016/j.renene.2021.07.031
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121010363
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.07.031?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gabhane, Jagdish & Kumar, Sachin & Sarma, A.K., 2020. "Effect of glycerol thermal and hydrothermal pretreatments on lignin degradation and enzymatic hydrolysis in paddy straw," Renewable Energy, Elsevier, vol. 154(C), pages 1304-1313.
    2. Sheng, Yequan & Tan, Xin & Gu, Yuanjie & Zhou, Xin & Tu, Maobing & Xu, Yong, 2021. "Effect of ascorbic acid assisted dilute acid pretreatment on lignin removal and enzyme digestibility of agricultural residues," Renewable Energy, Elsevier, vol. 163(C), pages 732-739.
    3. Manzanares, P. & Ballesteros, I. & Negro, M.J. & González, A. & Oliva, J.M. & Ballesteros, M., 2020. "Processing of extracted olive oil pomace residue by hydrothermal or dilute acid pretreatment and enzymatic hydrolysis in a biorefinery context," Renewable Energy, Elsevier, vol. 145(C), pages 1235-1245.
    4. Li, Mengzhu & Wei, Junnan & Yan, Guihua & Liu, Huai & Tang, Xing & Sun, Yong & Zeng, Xianhai & Lei, Tingzhou & Lin, Lu, 2020. "Cascade conversion of furfural to fuel bioadditive ethyl levulinate over bifunctional zirconium-based catalysts," Renewable Energy, Elsevier, vol. 147(P1), pages 916-923.
    5. Song, Yanliang & Ji, Hairui & Shi, Xiaoyou & Yang, Xue & Zhang, Xu, 2020. "Successive organic solvent fractionation and structural characterization of lignin extracted from hybrid poplar by deep eutectic solvent for improving the homogeneity and isolating narrow fractions," Renewable Energy, Elsevier, vol. 157(C), pages 1025-1034.
    6. Zainol, Muzakkir Mohammad & Amin, Nor Aishah Saidina & Asmadi, Mohd, 2019. "Kinetics and thermodynamic analysis of levulinic acid esterification using lignin-furfural carbon cryogel catalyst," Renewable Energy, Elsevier, vol. 130(C), pages 547-557.
    7. Wang, Qiong & Qi, Wei & Wang, Wen & Zhang, Yu & Leksawasdi, Noppol & Zhuang, Xinshu & Yu, Qiang & Yuan, Zhenhong, 2019. "Production of furfural with high yields from corncob under extremely low water/solid ratios," Renewable Energy, Elsevier, vol. 144(C), pages 139-146.
    8. Fockink, Douglas H. & Andreaus, Jürgen & Ramos, Luiz P. & Łukasik, Rafał M., 2020. "Pretreatment of cotton spinning residues for optimal enzymatic hydrolysis: A case study using green solvents," Renewable Energy, Elsevier, vol. 145(C), pages 490-499.
    9. Sharma, Vishal & Nargotra, Parushi & Sharma, Surbhi & Bajaj, Bijender Kumar, 2021. "Efficacy and functional mechanisms of a novel combinatorial pretreatment approach based on deep eutectic solvent and ultrasonic waves for bioconversion of sugarcane bagasse," Renewable Energy, Elsevier, vol. 163(C), pages 1910-1922.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Nimmanterdwong, Prathana & Chalermsinsuwan, Benjapon & Piumsomboon, Pornpote, 2023. "Optimizing utilization pathways for biomass to chemicals and energy by integrating emergy analysis and particle swarm optimization (PSO)," Renewable Energy, Elsevier, vol. 202(C), pages 1448-1459.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tang, Yiwei & Liu, Xiaoning & Xi, Ran & Liu, Le & Qi, Xinhua, 2022. "Catalytic one-pot conversion of biomass-derived furfural to ethyl levulinate over bifunctional Nb/Ni@OMC," Renewable Energy, Elsevier, vol. 200(C), pages 821-831.
    2. Rosen, Yan & Mamane, Hadas & Gerchman, Yoram, 2021. "Immersed ozonation of agro-wastes as an effective pretreatment method in bioethanol production," Renewable Energy, Elsevier, vol. 174(C), pages 382-390.
    3. Dixit, Mandeep & Gupta, Guddu Kumar & Usmani, Zeba & Sharma, Minaxi & Shukla, Pratyoosh, 2021. "Enhanced bioremediation of pulp effluents through improved enzymatic treatment strategies: A greener approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    4. Shen, Guannan & Yuan, Xinchuan & Chen, Sitong & Liu, Shuangmei & Jin, Mingjie, 2022. "High titer cellulosic ethanol production from sugarcane bagasse via DLCA pretreatment and process development without washing/detoxifying pretreated biomass," Renewable Energy, Elsevier, vol. 186(C), pages 904-913.
    5. Wiranarongkorn, Kunlanan & Im-orb, Karittha & Panpranot, Joongjai & Maréchal, François & Arpornwichanop, Amornchai, 2021. "Exergy and exergoeconomic analyses of sustainable furfural production via reactive distillation," Energy, Elsevier, vol. 226(C).
    6. Guo, Haixin & Hirosaki, Yuta & Qi, Xinhua & Lee Smith, Richard, 2020. "Synthesis of ethyl levulinate over amino-sulfonated functional carbon materials," Renewable Energy, Elsevier, vol. 157(C), pages 951-958.
    7. Xie, Xinyu & Song, Kai & Wang, Jing & Hu, Jinguang & Wu, Shufang & Chu, Qiulu, 2024. "Efficient ethanol production from masson pine sawdust by various organosolv pretreatment and modified pre-hydrolysis simultaneous saccharification and fermentation," Renewable Energy, Elsevier, vol. 225(C).
    8. Tian, Hongli & Shao, Yuewen & Liang, Chuanfei & Xu, Qing & Zhang, Lijun & Zhang, Shu & Liu, Shuhua & Hu, Xun, 2020. "Sulfated attapulgite for catalyzing the conversion of furfuryl alcohol to ethyl levulinate: Impacts of sulfonation on structural transformation and evolution of acidic sites on the catalyst," Renewable Energy, Elsevier, vol. 162(C), pages 1576-1586.
    9. Li, Fenghai & Zhao, Chaoyue & Fan, Hongli & Xu, Meiling & Guo, Qianqian & Li, Yang & Wu, Lishun & Wang, Tao & Fang, Yitian, 2022. "Ash fusion behaviors of sugarcane bagasse and its modification with sewage sludge addition," Energy, Elsevier, vol. 251(C).
    10. Zhou, Tianxing & Zhang, Weiwei & Luo, Siyi & Zuo, Zongliang & Ren, Dongdong, 2023. "The effect of ash fusion characteristic on the structure characteristics of carbon and the migration of potassium during rice straw high-temperature gasification process," Energy, Elsevier, vol. 284(C).
    11. Carlo Pastore & Valeria D’Ambrosio, 2021. "Intensification of Processes for the Production of Ethyl Levulinate Using AlCl 3 ·6H 2 O," Energies, MDPI, vol. 14(5), pages 1-11, February.
    12. Hashemi, Seyed Sajad & Mirmohamadsadeghi, Safoora & Karimi, Keikhosro, 2020. "Biorefinery development based on whole safflower plant," Renewable Energy, Elsevier, vol. 152(C), pages 399-408.
    13. Zhao, Man & Wang, Yanan & Zhou, Wenting & Zhou, Wei & Gong, Zhiwei, 2023. "Co-valorization of crude glycerol and low-cost substrates via oleaginous yeasts to micro-biodiesel: Status and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 180(C).
    14. Xu, Ling-Hua & Ma, Cheng-Ye & Zhang, Chen & Xu, Ying & Wen, Jia-Long & Yuan, Tong-Qi, 2022. "An integrated acetic acid-catalyzed hydrothermal-pretreatment (AAP) and rapid ball-milling for producing high-yield of xylo-oligosaccharides, fermentable glucose and lignin from poplar wood," Renewable Energy, Elsevier, vol. 201(P1), pages 691-699.
    15. Kumar, Komal & Pathak, Shailesh & Upadhyayula, Sreedevi, 2021. "Acetalization of 5-hydroxymethyl furfural into biofuel additive cyclic acetal using protic ionic liquid catalyst- A thermodynamic and kinetic analysis," Renewable Energy, Elsevier, vol. 167(C), pages 282-293.
    16. Ortega, Julieth Orduña & Mora Vargas, Jorge Andrés & Metzker, Gustavo & Gomes, Eleni & da Silva, Roberto & Boscolo, Mauricio, 2021. "Enhancing the production of the fermentable sugars from sugarcane straw: A new approach to applying alkaline and ozonolysis pretreatments," Renewable Energy, Elsevier, vol. 164(C), pages 502-508.
    17. Bains, Rohit & Kumar, Ajay & Chauhan, Arvind Singh & Das, Pralay, 2022. "Dimethyl carbonate solvent assisted efficient conversion of lignocellulosic biomass to 5- hydroxymethylfurfural and furfural," Renewable Energy, Elsevier, vol. 197(C), pages 237-243.
    18. Barbara Mendecka & Giovanni Di Ilio & Lidia Lombardi, 2020. "Thermo-Fluid Dynamic and Kinetic Modeling of Hydrothermal Carbonization of Olive Pomace in a Batch Reactor," Energies, MDPI, vol. 13(16), pages 1-16, August.
    19. Huang, Rulu & Liu, Huai & Zhang, Junhua & Cheng, Yuan & He, Liang & Peng, Lincai, 2022. "Tea polyphenol and HfCl4 Co-doped polyacrylonitrile nanofiber for highly efficient transformation of levulinic acid to γ-valerolactone," Renewable Energy, Elsevier, vol. 200(C), pages 234-243.
    20. Tiong, Yong Wei & Yap, Chiew Lin & Gan, Suyin & Yap, Winnie Soo Ping, 2020. "Kinetic and thermodynamic studies of oil palm mesocarp fiber cellulose conversion to levulinic acid and upgrading to ethyl levulinate via indium trichloride-ionic liquids," Renewable Energy, Elsevier, vol. 146(C), pages 932-943.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:179:y:2021:i:c:p:351-358. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.