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BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure

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  • Xu, Xiwei
  • Jiang, Enchen
  • Du, Yanhong
  • Li, Bosong

Abstract

Biosourced aromatics (benzene–toluene–xylene (BTX) and phenols) could be obtained by catalytic hydrodeoxygenation (HDO) coupled with transmethylation at atmospheric pressure in a fixed-bed reactor. We choose guaiacol as a model compound to investigate the catalytic HDO over Fe/Ni/HBeta catalyst. The active amount (5%–15%), temperature (250–400 °C), and 1/WHSV (1.5–4.0) significantly influenced the hydrogenolysis of the CaromaticO bond and transmethylation. The mechanism showed that feed and intermediate products formed the “surface pool” on the catalyst surface, which enabled the HDO reaction by the reduced intermediate species (Z-FeH2+ and Z-NiH+). Fe/Ni/HBeta exhibited good activity for both methyl transfer and HDO. Moreover, the aromatic ring did not undergo catalytic hydrogenation, and most methyl or methoxyl molecules transferred onto the phenolic or benzene ring and remained after deoxygenation. Consequently, carbon loss was minimized, and hydrogen consumption was reduced.

Suggested Citation

  • Xu, Xiwei & Jiang, Enchen & Du, Yanhong & Li, Bosong, 2016. "BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure," Renewable Energy, Elsevier, vol. 96(PA), pages 458-468.
    • Handle: RePEc:eee:renene:v:96:y:2016:i:pa:p:458-468
    DOI: 10.1016/j.renene.2016.04.094
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    3. Xu, Xiwei & Enchen, Jiang & Mingfeng, Wang & Bosong, Li & Ling, Zhou, 2012. "Hydrogen production by catalytic cracking of rice husk over Fe2O3/γ-Al2O3 catalyst," Renewable Energy, Elsevier, vol. 41(C), pages 23-28.
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    Cited by:

    1. Tran, Quoc Khanh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Seung-Soo & Kim, Jinsoo, 2021. "Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts," Renewable Energy, Elsevier, vol. 173(C), pages 886-895.
    2. Fan, Xu-dong & Wu, Yu-jian & Li, Zhi-yu & Sun, Yan & Tu, Ren & Zhong, Pei-Dong & Jiang, En-chen & Xu, Xi-wei, 2020. "Benzene, toluene and xylene (BTX) from in-situ gas phase hydrodeoxygenation of guaiacol with liquid hydrogen donor over bifunctional non-noble-metal zeolite catalysts," Renewable Energy, Elsevier, vol. 152(C), pages 1391-1402.
    3. Xu, Xiwei & Jiang, Enchen & Li, Zhiyu & Zhu, Xiongfa & Sun, Yan & Tu, Ren, 2019. "Alkene and benzene derivate obtained from catalytic reforming of acetone-butanol-ethanol (ABE) from carbohydrates fermentation broth," Renewable Energy, Elsevier, vol. 135(C), pages 1213-1223.
    4. Li, Zhiyu & Jiang, Enchen & Xu, Xiwei & Sun, Yan & Tu, Ren, 2020. "Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga," Renewable Energy, Elsevier, vol. 146(C), pages 1991-2007.
    5. Guan, Weixiang & Chen, Xiao & Zhang, Jie & Hu, Haoquan & Liang, Changhai, 2020. "Catalytic transfer hydrogenolysis of lignin α-O-4 model compound 4-(benzyloxy)phenol and lignin over Pt/HNbWO6/CNTs catalyst," Renewable Energy, Elsevier, vol. 156(C), pages 249-259.
    6. Bakhtyari, Ali & Rahimpour, Mohammad Reza & Raeissi, Sona, 2020. "Cobalt-molybdenum catalysts for the hydrodeoxygenation of cyclohexanone," Renewable Energy, Elsevier, vol. 150(C), pages 443-455.
    7. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    8. Wu, Yujian & Xu, Xiwei & Sun, Yan & Jiang, Enchen & Fan, Xudong & Tu, Ren & Wang, Jiamin, 2020. "Gas-phase hydrodeoxygenation of guaiacol over Ni-based HUSY zeolite catalysts under atmospheric H2 pressure," Renewable Energy, Elsevier, vol. 152(C), pages 1380-1390.

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