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Cobalt-molybdenum catalysts for the hydrodeoxygenation of cyclohexanone

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  • Bakhtyari, Ali
  • Rahimpour, Mohammad Reza
  • Raeissi, Sona

Abstract

Cyclohexanone is an important oxygenated intermediate in the conversion of lignin to bio-fuel. Following the importance of bio-fuel production and conversion of lignin-derived bio-oils, the deoxygenation of cyclohexanone is pursued. Two hydrotreating catalysts composed of cobalt, molybdenum, and alumina support were evaluated at 300–400 °C and 1–15 bar. The catalysts showed high activity and selectivity toward the conversion of cyclohexanone in the presence of hydrogen. The major obtained hydrocarbons were cyclohexane, cyclohexene, benzene, and cyclohexylbenzene indicating the capability of producing hydrocarbon-rich products. The catalysts composed of 3.4 wt% cobalt and 13.6 wt% molybdenum gave more than 89% cyclohexanone conversion and 100% hydrocarbon selectivity at 400 °C and 15 bar.

Suggested Citation

  • Bakhtyari, Ali & Rahimpour, Mohammad Reza & Raeissi, Sona, 2020. "Cobalt-molybdenum catalysts for the hydrodeoxygenation of cyclohexanone," Renewable Energy, Elsevier, vol. 150(C), pages 443-455.
    • Handle: RePEc:eee:renene:v:150:y:2020:i:c:p:443-455
    DOI: 10.1016/j.renene.2019.12.119
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    1. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.
    2. Gao, Xueying & Li, Helong & Wang, Shuizhong & Liu, Zhenzhen & Ma, Jian-feng & Liu, Xing-e & Song, Guoyong, 2022. "Hydrodeoxygenation of lignin biophenolics to cyclohexanes over sub-nanometric Ru multifunctional catalyst," Renewable Energy, Elsevier, vol. 201(P1), pages 724-733.
    3. Ambursa, Murtala M. & Juan, Joon Ching & Yahaya, Y. & Taufiq-Yap, Y.H. & Lin, Yu-Chuan & Lee, Hwei Voon, 2021. "A review on catalytic hydrodeoxygenation of lignin to transportation fuels by using nickel-based catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).

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