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Cobalt-molybdenum catalysts for the hydrodeoxygenation of cyclohexanone

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  • Bakhtyari, Ali
  • Rahimpour, Mohammad Reza
  • Raeissi, Sona

Abstract

Cyclohexanone is an important oxygenated intermediate in the conversion of lignin to bio-fuel. Following the importance of bio-fuel production and conversion of lignin-derived bio-oils, the deoxygenation of cyclohexanone is pursued. Two hydrotreating catalysts composed of cobalt, molybdenum, and alumina support were evaluated at 300–400 °C and 1–15 bar. The catalysts showed high activity and selectivity toward the conversion of cyclohexanone in the presence of hydrogen. The major obtained hydrocarbons were cyclohexane, cyclohexene, benzene, and cyclohexylbenzene indicating the capability of producing hydrocarbon-rich products. The catalysts composed of 3.4 wt% cobalt and 13.6 wt% molybdenum gave more than 89% cyclohexanone conversion and 100% hydrocarbon selectivity at 400 °C and 15 bar.

Suggested Citation

  • Bakhtyari, Ali & Rahimpour, Mohammad Reza & Raeissi, Sona, 2020. "Cobalt-molybdenum catalysts for the hydrodeoxygenation of cyclohexanone," Renewable Energy, Elsevier, vol. 150(C), pages 443-455.
    • Handle: RePEc:eee:renene:v:150:y:2020:i:c:p:443-455
    DOI: 10.1016/j.renene.2019.12.119
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    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
    2. Xu, Xiwei & Jiang, Enchen & Du, Yanhong & Li, Bosong, 2016. "BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure," Renewable Energy, Elsevier, vol. 96(PA), pages 458-468.
    3. Ramesh, Arumugam & Tamizhdurai, Perumal & Shanthi, Kannan, 2019. "Catalytic hydrodeoxygenation of jojoba oil to the green-fuel application on Ni-MoS/Mesoporous zirconia-silica catalysts," Renewable Energy, Elsevier, vol. 138(C), pages 161-173.
    4. Cheng, Jay J. & Timilsina, Govinda R., 2011. "Status and barriers of advanced biofuel technologies: A review," Renewable Energy, Elsevier, vol. 36(12), pages 3541-3549.
    5. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    6. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    7. Resende, K.A. & de Souza, P.M. & Noronha, F.B. & Hori, C.E., 2019. "Thermodynamic analysis of phenol hydrodeoxygenation reaction system in gas phase," Renewable Energy, Elsevier, vol. 136(C), pages 365-372.
    8. Hewer, Thiago L.R. & Souza, Adriana G.F. & Roseno, Karina T.C. & Moreira, Paulo F. & Bonfim, Rodrigo & Alves, Rita M.B. & Schmal, Martin, 2018. "Influence of acid sites on the hydrodeoxygenation of anisole with metal supported on SBA-15 and SAPO-11," Renewable Energy, Elsevier, vol. 119(C), pages 615-624.
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    Cited by:

    1. Gao, Xueying & Li, Helong & Wang, Shuizhong & Liu, Zhenzhen & Ma, Jian-feng & Liu, Xing-e & Song, Guoyong, 2022. "Hydrodeoxygenation of lignin biophenolics to cyclohexanes over sub-nanometric Ru multifunctional catalyst," Renewable Energy, Elsevier, vol. 201(P1), pages 724-733.
    2. Ambursa, Murtala M. & Juan, Joon Ching & Yahaya, Y. & Taufiq-Yap, Y.H. & Lin, Yu-Chuan & Lee, Hwei Voon, 2021. "A review on catalytic hydrodeoxygenation of lignin to transportation fuels by using nickel-based catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    3. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.

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