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Upgrading bio-oil by catalytic fast pyrolysis of acid-washed Saccharina japonica alga in a fluidized-bed reactor

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  • Ly, Hoang Vu
  • Choi, Jae Hyung
  • Woo, Hee Chul
  • Kim, Seung-Soo
  • Kim, Jinsoo

Abstract

Macroalgae contain significant amounts of inorganic compounds (K, Na, Mg, and Ca) that cause problems during thermal processing (ash fouling or agglomeration of char and bed material). The macroalga Saccharina japonica (S.J) was demineralized with diluted acid solution to remove inorganic species before using this matter for fast pyrolysis in a bubbling fluidized-bed reactor. The effect of acid washing on the product yield and the quality of bio-oil was systematically investigated. When the pyrolysis temperature increased from 400 to 500 °C, the bio-oil yield was 39.70–45.36 wt%. The major compounds in the bio-oil were levoglucosan and di-anhydromannitol. The fractional catalytic pyrolysis of pre-treated S. japonica using HZSM-5 catalyst (calcined at 550 °C) was investigated in fluidized-bed reactor under the same conditions. Pyrolysis of the pretreated sample with catalyst resulted in 35.37–39.05 wt% liquid yield, which was lower than that from using silica sand. Using HZSM-5 catalytic pyrolysis bio-oil showed a decrease in dianhydromannitol and 2-furyl methyl ketone, and an increase in aromatic compounds such as derivatives of phenol, indole, and naphthalene. The effect of pretreatment by acid washing, and the effect of this catalyst on the pyrolysis product distribution and composition were clarified in relation to previous work.

Suggested Citation

  • Ly, Hoang Vu & Choi, Jae Hyung & Woo, Hee Chul & Kim, Seung-Soo & Kim, Jinsoo, 2019. "Upgrading bio-oil by catalytic fast pyrolysis of acid-washed Saccharina japonica alga in a fluidized-bed reactor," Renewable Energy, Elsevier, vol. 133(C), pages 11-22.
  • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:11-22
    DOI: 10.1016/j.renene.2018.09.103
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    1. Ly, Hoang Vu & Kim, Seung-Soo & Woo, Hee Chul & Choi, Jae Hyung & Suh, Dong Jin & Kim, Jinsoo, 2015. "Fast pyrolysis of macroalga Saccharina japonica in a bubbling fluidized-bed reactor for bio-oil production," Energy, Elsevier, vol. 93(P2), pages 1436-1446.
    2. Zhang, Le & Liu, Ronghou & Yin, Renzhan & Mei, Yuanfei, 2013. "Upgrading of bio-oil from biomass fast pyrolysis in China: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 66-72.
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    1. Tran, Quoc Khanh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Seung-Soo & Kim, Jinsoo, 2021. "Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts," Renewable Energy, Elsevier, vol. 173(C), pages 886-895.
    2. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    3. Chen, Chao & Liang, Rui & Ge, Yadong & Li, Jian & Yan, Beibei & Cheng, Zhanjun & Tao, Junyu & Wang, Zhenyu & Li, Meng & Chen, Guanyi, 2022. "Fast characterization of biomass pyrolysis oil via combination of ATR-FTIR and machine learning models," Renewable Energy, Elsevier, vol. 194(C), pages 220-231.
    4. Ly, Hoang Vu & Park, Jeong Woo & Kim, Seung-Soo & Hwang, Hyun Tae & Kim, Jinsoo & Woo, Hee Chul, 2020. "Catalytic pyrolysis of bamboo in a bubbling fluidized-bed reactor with two different catalysts: HZSM-5 and red mud for upgrading bio-oil," Renewable Energy, Elsevier, vol. 149(C), pages 1434-1445.
    5. Apip Amrullah & Obie Farobie & Asep Bayu & Novi Syaftika & Edy Hartulistiyoso & Navid R. Moheimani & Surachai Karnjanakom & Yukihiko Matsumura, 2022. "Slow Pyrolysis of Ulva lactuca (Chlorophyta) for Sustainable Production of Bio-Oil and Biochar," Sustainability, MDPI, vol. 14(6), pages 1-14, March.
    6. Park, Jeong-Woo & Heo, Juheon & Ly, Hoang Vu & Kim, Jinsoo & Lim, Hankwon & Kim, Seung-Soo, 2019. "Fast pyrolysis of acid-washed oil palm empty fruit bunch for bio-oil production in a bubbling fluidized-bed reactor," Energy, Elsevier, vol. 179(C), pages 517-527.

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