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Catalytic conversion of spent frying oil into biodiesel over raw and 12-tungsto-phosphoric acid modified clay

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  • Khan, Ihtisham Wali
  • Naeem, Abdul
  • Farooq, Muhammad
  • Mahmood, Tahira
  • Ahmad, Bashir
  • Hamayun, Muhammad
  • Ahmad, Zahoor
  • Saeed, Tooba

Abstract

In the present work, locally available clay has been utilized to develop cost effective catalyst for biodiesel production from low cost feedstock. The selected clay was modified with different concentrations (5 wt%, 10 wt%, 20 wt%, 30 wt% and 40 wt %) of 12-tungstophosphoric acid (TPA) to enhance the capability of the selected clay in biodiesel production from spent frying oil. The synthesized catalyst was characterized with different analytical techniques to evaluate its physiochemical properties. The result suggested that the catalyst containing 10 wt% 12-tungstophosphoric acid (TPA) loading exhibited good trans-esterification activity to produce maximum biodiesel yield of 96% under the best reaction conditions: oil/methanol molar ratio, 1:10; catalyst amount, 0.7 g; reaction time, 4.5 h and reaction temperature, 85 °C.

Suggested Citation

  • Khan, Ihtisham Wali & Naeem, Abdul & Farooq, Muhammad & Mahmood, Tahira & Ahmad, Bashir & Hamayun, Muhammad & Ahmad, Zahoor & Saeed, Tooba, 2020. "Catalytic conversion of spent frying oil into biodiesel over raw and 12-tungsto-phosphoric acid modified clay," Renewable Energy, Elsevier, vol. 155(C), pages 181-188.
    • Handle: RePEc:eee:renene:v:155:y:2020:i:c:p:181-188
    DOI: 10.1016/j.renene.2020.03.123
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    References listed on IDEAS

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    1. Flores, Ken P. & Omega, Jan Laurence O. & Cabatingan, Luis K. & Go, Alchris W. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Simultaneously carbonized and sulfonated sugarcane bagasse as solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 130(C), pages 510-523.
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    1. Han, Xiaoxiang & Jiang, Shengchou & Chen, Ziyi & Zeng, Zhiwei & Chen, Qing & Niu, Fuge & Pan, Weichun & Tang, Xiujuan & Liu, Shang-Bin, 2023. "Highly active sulfonic ionic liquid modified heteropoly acid composite catalysts for efficient production of ethyl palmitate," Renewable Energy, Elsevier, vol. 215(C).
    2. Mohadesi, Majid & Aghel, Babak & Gouran, Ashkan & Razmehgir, Mohammad Hamed, 2022. "Transesterification of waste cooking oil using Clay/CaO as a solid base catalyst," Energy, Elsevier, vol. 242(C).
    3. Xie, Wenlei & Gao, Chunli & Li, Jiangbo, 2021. "Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites," Renewable Energy, Elsevier, vol. 168(C), pages 927-937.
    4. Singh, Himmat & Ali, Amjad, 2023. "Esterification as well as transesterification of waste oil using potassium imbued tungstophosphoric acid supported graphene oxide as heterogeneous catalyst: Optimization and kinetic modeling," Renewable Energy, Elsevier, vol. 207(C), pages 422-435.

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