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Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites

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  • Xie, Wenlei
  • Gao, Chunli
  • Li, Jiangbo

Abstract

The development of efficient and reusable catalysts is desired to improve biodiesel production process. For this purpose, the magnetic Fe3O4/ZIF-8 composites were first prepared by incorporating ZIF-8 MOF into Fe3O4 nanoparticles through in-situ approach, and then a vanadium-substituted heteropolyacid (HPA), H6PV3MoW8O40, was encapsulated in the support to afford the solid catalyst. The so-prepared catalysts were characterized by using XRD, FT-IR, TEM, SEM, TG, VSM, and nitrogen porosimetry measurement. Results revealed that the Fe3O4/ZIF-8 support was really formed, and the HPAs had been loaded on the magnetic composite. The catalytic performances of the developed catalysts were evaluated for the heterogeneous biodiesel production from the low-quantity oils. This catalyst had good magnetic responsiveness, and could catalyze the transesterification of soybean oil and esterification of free fatty acids (FFAs) simultaneously, thus achieving one-step transformation of triglycerides and FFAs to biodiesel in a heterogeneous manner. The transesterification conversion obtained was 92.6% with 30:1 methanol/oil molar ratio at a catalyst loading of 6 wt% and reaction temperature of 160 °C for 10 h. Moreover, the solid catalyst could be recycled by an external magnet, and displayed a good reusability with a minimal mass loss and a slight decrease in the activity after reuse for five runs. This protocol showed great potential for sustainable biodiesel production from the low-quantity oils due to the pronounced activity and good reusability of the solid catalyst.

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  • Xie, Wenlei & Gao, Chunli & Li, Jiangbo, 2021. "Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites," Renewable Energy, Elsevier, vol. 168(C), pages 927-937.
    • Handle: RePEc:eee:renene:v:168:y:2021:i:c:p:927-937
    DOI: 10.1016/j.renene.2020.12.129
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    4. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    5. Cheng, Yuan & Liu, Yao & Zhang, Junhua & Huang, Rulu & Wang, Yue & Cao, Shuwan & He, Liang & Peng, Lincai, 2022. "Acetic acid-regulated mesoporous zirconium-furandicarboxylate hybrid with high lewis acidity and lewis basicity for efficient conversion of furfural to furfuryl alcohol," Renewable Energy, Elsevier, vol. 184(C), pages 115-123.
    6. Wang, Quan & Wenlei Xie, & Guo, Lihong, 2022. "Molybdenum and zirconium oxides supported on KIT-6 silica: A recyclable composite catalyst for one–pot biodiesel production from simulated low-quality oils," Renewable Energy, Elsevier, vol. 187(C), pages 907-922.
    7. Xie, Wenlei & Wang, Xiangxiang & Guo, Lihong, 2024. "Utilization of Keplerate-type polyoxomolybdates {Mo132} supported on hierarchical porous SOM-ZIF-8 as reusable catalyst boosts biodiesel production from acidic soybean oils by simultaneous transesteri," Renewable Energy, Elsevier, vol. 225(C).
    8. Sun, Chihe & Hu, Yun & Sun, Fubao & Sun, Yahui & Song, Guojie & Chang, Haixing & Lunprom, Siriporn, 2022. "Comparison of biodiesel production using a novel porous Zn/Al/Co complex oxide prepared from different methods: Physicochemical properties, reaction kinetic and thermodynamic studies," Renewable Energy, Elsevier, vol. 181(C), pages 1419-1430.
    9. Zhang, Qiaofei & Xie, Wenlei & Li, Jiangbo & Guo, Lihong, 2023. "Bimetallic Zrx-Aly-KIT-6 modified with sulfate as acidic catalyst for biodiesel production from low-grade acidic oils," Renewable Energy, Elsevier, vol. 217(C).
    10. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    11. Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.
    12. Wang, Yue & Liu, Huai & Zhang, Junhua & Cheng, Yuan & Lin, Wansi & Huang, Rulu & Peng, Lincai, 2022. "Direct epitaxial synthesis of magnetic biomass derived acid/base bifunctional zirconium-based hybrid for catalytic transfer hydrogenation of ethyl levulinate into γ-valerolactone," Renewable Energy, Elsevier, vol. 197(C), pages 911-921.

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