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Potassium impregnated nanocrystalline mixed oxides of La and Mg as heterogeneous catalysts for transesterification

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  • Mutreja, Vishal
  • Singh, Satnam
  • Ali, Amjad

Abstract

Potassium impregnated mixed oxides of lanthanum and magnesium in 1:1 to 1:5 atomic ratios were prepared by co-precipitation at a constant pH. These were characterized by FEG–SEM–EDX, TEM, Powder XRD, Hammett indicators and acid/base titration and, were evaluated as heterogeneous catalysts for transesterification of used cotton seed oil with methanol. The optimized reaction conditions for the catalyst, prepared at pH 10 using 1:3 atomic ratio of lanthanum and magnesium, were the use of 1:54 molar ratio of oil to methanol and 5 wt.% of the catalyst at 65 °C that resulted into 96% conversion to biodiesel within 20 min. The catalyst showed tolerance of 1 wt.% of moisture. Concentration of potassium ions leached out from catalyst into biodiesel was within permissible limit of ASTM.

Suggested Citation

  • Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2014. "Potassium impregnated nanocrystalline mixed oxides of La and Mg as heterogeneous catalysts for transesterification," Renewable Energy, Elsevier, vol. 62(C), pages 226-233.
    • Handle: RePEc:eee:renene:v:62:y:2014:i:c:p:226-233
    DOI: 10.1016/j.renene.2013.07.015
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    References listed on IDEAS

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    1. Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2011. "Biodiesel from mutton fat using KOH impregnated MgO as heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(8), pages 2253-2258.
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    Cited by:

    1. Xie, Wenlei & Yang, Xinli & Fan, Mingliang, 2015. "Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine," Renewable Energy, Elsevier, vol. 80(C), pages 230-237.
    2. Essamlali, Younes & Amadine, Othmane & Fihri, Aziz & Zahouily, Mohamed, 2019. "Sodium modified fluorapatite as a sustainable solid bi-functional catalyst for biodiesel production from rapeseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 1295-1307.
    3. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    4. Singh, Veena & Bux, Faizal & Sharma, Yogesh Chandra, 2016. "A low cost one pot synthesis of biodiesel from waste frying oil (WFO) using a novel material, β-potassium dizirconate (β-K2Zr2O5)," Applied Energy, Elsevier, vol. 172(C), pages 23-33.
    5. Khan, Ihtisham Wali & Naeem, Abdul & Farooq, Muhammad & Mahmood, Tahira & Ahmad, Bashir & Hamayun, Muhammad & Ahmad, Zahoor & Saeed, Tooba, 2020. "Catalytic conversion of spent frying oil into biodiesel over raw and 12-tungsto-phosphoric acid modified clay," Renewable Energy, Elsevier, vol. 155(C), pages 181-188.
    6. Rokhum, Samuel Lalthazuala & Changmai, Bishwajit & Kress, Thomas & Wheatley, Andrew E.H., 2022. "A one-pot route to tunable sugar-derived sulfonated carbon catalysts for sustainable production of biodiesel by fatty acid esterification," Renewable Energy, Elsevier, vol. 184(C), pages 908-919.
    7. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    8. Singh, Himmat & Ali, Amjad, 2023. "Esterification as well as transesterification of waste oil using potassium imbued tungstophosphoric acid supported graphene oxide as heterogeneous catalyst: Optimization and kinetic modeling," Renewable Energy, Elsevier, vol. 207(C), pages 422-435.
    9. AlSharifi, Mariam & Znad, Hussein, 2020. "Transesterification of waste canola oil by lithium/zinc composite supported on waste chicken bone as an effective catalyst," Renewable Energy, Elsevier, vol. 151(C), pages 740-749.

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