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Preparation, characterization and application of a novel solid Brönsted acid catalyst SO42−/La3+/C for biodiesel production via esterification of oleic acid and methanol

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  • Shu, Qing
  • Tang, Guoqiang
  • Lesmana, Herry
  • Zou, Laixi
  • Xiong, Daolin

Abstract

Waste camellia seed shell was placed in the fluidized bed tubular reactor and carbonized at 700 °C for the preparation of a carbon material. The obtained-carbon material was simultaneously modified by La3+ and concentrated sulfuric acid for the synthesis of a novel solid Brönsted acid catalyst SO42−/La3+/C by performing impregnation method. Physical and chemical properties and structural characteristics of the SO42−/La3+/C catalyst were characterized and analyzed by several methods. The catalytic activity and stability of SO42−/La3+/C were evaluated from the catalytic synthesis of biodiesel via esterification of oleic acid and methanol. The highest conversion of oleic acid was 98.37 wt% when the mass ratio of catalyst/reactant, mass ratio of methanol to oleic acid, reaction temperature and reaction time were fixed at 0.75 wt%, 9:1, 62 °C and 5 h, respectively. Additionally in terms of reusability, the conversion of oleic acid was still 81.9 wt% after SO42−/La3+/C catalyst had been recycled for ten times. The high catalytic activity and stability can be ascribed to the formation of a six-coordination bond from the interactions of SO42−/La3+, COH oxygen of the carboxyl group and H2O. Hence, SO42−/La3+/C will exhibit strong Brönsted acidity and keep high stability in a reaction medium with large amount of H2O.

Suggested Citation

  • Shu, Qing & Tang, Guoqiang & Lesmana, Herry & Zou, Laixi & Xiong, Daolin, 2018. "Preparation, characterization and application of a novel solid Brönsted acid catalyst SO42−/La3+/C for biodiesel production via esterification of oleic acid and methanol," Renewable Energy, Elsevier, vol. 119(C), pages 253-261.
    • Handle: RePEc:eee:renene:v:119:y:2018:i:c:p:253-261
    DOI: 10.1016/j.renene.2017.12.013
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    References listed on IDEAS

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    1. Melero, Juan A. & Bautista, L. Fernando & Morales, Gabriel & Iglesias, Jose & Sánchez-Vázquez, Rebeca, 2015. "Acid-catalyzed production of biodiesel over arenesulfonic SBA-15: Insights into the role of water in the reaction network," Renewable Energy, Elsevier, vol. 75(C), pages 425-432.
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    1. Masera, Kemal & Hossain, Abul Kalam, 2023. "Advancement of biodiesel fuel quality and NOx emission control techniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 178(C).
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