IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i18p6572-d1238374.html
   My bibliography  Save this article

Development and Characteristics Analysis of Novel Hydrated Salt Composite Adsorbents for Thermochemical Energy Storage

Author

Listed:
  • Yihan Wang

    (School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China)

  • Zicheng Zhang

    (Faculty of Civil Engineering and Mechanics, Kunming University of Science and Technology, Kunming 650032, China)

  • Shuli Liu

    (School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China)

  • Zhihao Wang

    (Faculty of Civil Engineering and Mechanics, Kunming University of Science and Technology, Kunming 650032, China)

  • Yongliang Shen

    (School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China)

Abstract

New composite adsorbents are proposed to further improve the application of thermochemical energy storage technology in buildings. A volcanic is taken as an adsorption substance, which is impregnated in 36.50 wt% and 54.00 wt% saturated MgCl 2 and CaCl 2 solutions to prepare composite adsorbents, which are called composite-MgCl 2 and composite-CaCl 2 , respectively. According to the characterization, the main pore structure of the original volcanic is macropores (>100 nm), and hydrated salts tend to fill them. Compared with zeolite-MgCl 2 , the final water uptake of composite-MgCl 2 and composite-CaCl 2 increased by 0.15 g/g and 0.03 g/g. Meanwhile, the TG-DSC measurement results show that the thermochemical energy storage densities of composite-MgCl 2 and composite-CaCl 2 are 1.02 and 1.56 times that of zeolite-MgCl 2 , which are 642 kJ/kg and 983 kJ/kg, respectively. Moreover, the composition of the thermochemical energy storage densities of the composites is obtained by theoretical calculations, and the theoretically calculated results are close to the measured results. After several cycles, the composites still have high thermochemical energy storage capacity and low energy storage density cost.

Suggested Citation

  • Yihan Wang & Zicheng Zhang & Shuli Liu & Zhihao Wang & Yongliang Shen, 2023. "Development and Characteristics Analysis of Novel Hydrated Salt Composite Adsorbents for Thermochemical Energy Storage," Energies, MDPI, vol. 16(18), pages 1-21, September.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6572-:d:1238374
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/18/6572/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/18/6572/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Shkatulov, A.I. & Houben, J. & Fischer, H. & Huinink, H.P., 2020. "Stabilization of K2CO3 in vermiculite for thermochemical energy storage," Renewable Energy, Elsevier, vol. 150(C), pages 990-1000.
    2. Zhang, Y.N. & Wang, R.Z. & Zhao, Y.J. & Li, T.X. & Riffat, S.B. & Wajid, N.M., 2016. "Development and thermochemical characterizations of vermiculite/SrBr2 composite sorbents for low-temperature heat storage," Energy, Elsevier, vol. 115(P1), pages 120-128.
    3. Strong, Curtis & Carrier, Ye & Handan Tezel, F., 2022. "Experimental optimization of operating conditions for an open bulk-scale silica gel/water vapour adsorption energy storage system," Applied Energy, Elsevier, vol. 312(C).
    4. Scapino, Luca & Zondag, Herbert A. & Van Bael, Johan & Diriken, Jan & Rindt, Camilo C.M., 2017. "Sorption heat storage for long-term low-temperature applications: A review on the advancements at material and prototype scale," Applied Energy, Elsevier, vol. 190(C), pages 920-948.
    5. Xu, S.Z. & Wang, R.Z. & Wang, L.W. & Zhu, J., 2019. "Performance characterizations and thermodynamic analysis of magnesium sulfate-impregnated zeolite 13X and activated alumina composite sorbents for thermal energy storage," Energy, Elsevier, vol. 167(C), pages 889-901.
    6. Emanuela Mastronardo & Emanuele La Mazza & Davide Palamara & Elpida Piperopoulos & Daniela Iannazzo & Edoardo Proverbio & Candida Milone, 2022. "Organic Salt Hydrate as a Novel Paradigm for Thermal Energy Storage," Energies, MDPI, vol. 15(12), pages 1-13, June.
    7. Mehrabadi, Abbas & Farid, Mohammed, 2018. "New salt hydrate composite for low-grade thermal energy storage," Energy, Elsevier, vol. 164(C), pages 194-203.
    8. Ji, Wenjie & Zhang, Heng & Liu, Shuli & Wang, Zhihao & Deng, Shihan, 2022. "An experimental study on the binary hydrated salt composite zeolite for improving thermochemical energy storage performance," Renewable Energy, Elsevier, vol. 194(C), pages 1163-1173.
    9. Hui Yang & Chengcheng Wang & Lige Tong & Shaowu Yin & Li Wang & Yulong Ding, 2023. "Salt Hydrate Adsorption Material-Based Thermochemical Energy Storage for Space Heating Application: A Review," Energies, MDPI, vol. 16(6), pages 1-54, March.
    10. Johannes, Kévyn & Kuznik, Frédéric & Hubert, Jean-Luc & Durier, Francois & Obrecht, Christian, 2015. "Design and characterisation of a high powered energy dense zeolite thermal energy storage system for buildings," Applied Energy, Elsevier, vol. 159(C), pages 80-86.
    11. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    12. Lefebvre, Dominique & Tezel, F. Handan, 2017. "A review of energy storage technologies with a focus on adsorption thermal energy storage processes for heating applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 116-125.
    13. Gaeini, M. & Rouws, A.L. & Salari, J.W.O. & Zondag, H.A. & Rindt, C.C.M., 2018. "Characterization of microencapsulated and impregnated porous host materials based on calcium chloride for thermochemical energy storage," Applied Energy, Elsevier, vol. 212(C), pages 1165-1177.
    14. Yannan Zhang & Ruzhu Wang & Tingxian Li & Yanjie Zhao, 2016. "Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage," Energies, MDPI, vol. 9(10), pages 1-15, October.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    2. Salviati, Sergio & Carosio, Federico & Cantamessa, Francesco & Medina, Lilian & Berglund, Lars A. & Saracco, Guido & Fina, Alberto, 2020. "Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites," Renewable Energy, Elsevier, vol. 160(C), pages 698-706.
    3. Liu, Xiao & Liu, Xin & Yang, Fangming & Wu, Yupeng, 2024. "Experimental investigation of low-temperature fluidised bed thermochemical energy storage with salt-mesoporous silica composite materials," Applied Energy, Elsevier, vol. 362(C).
    4. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    5. Benjamin Fumey & Luca Baldini, 2021. "Static Temperature Guideline for Comparative Testing of Sorption Heat Storage Systems for Building Application," Energies, MDPI, vol. 14(13), pages 1-15, June.
    6. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2021. "Numerical analysis on the improved thermo-chemical behaviour of hierarchical energy materials as a cascaded thermal accumulator," Energy, Elsevier, vol. 232(C).
    7. Mazur, Natalia & Blijlevens, Melian A.R. & Ruliaman, Rick & Fischer, Hartmut & Donkers, Pim & Meekes, Hugo & Vlieg, Elias & Adan, Olaf & Huinink, Henk, 2023. "Revisiting salt hydrate selection for domestic heat storage applications," Renewable Energy, Elsevier, vol. 218(C).
    8. Hui Yang & Chengcheng Wang & Lige Tong & Shaowu Yin & Li Wang & Yulong Ding, 2023. "Salt Hydrate Adsorption Material-Based Thermochemical Energy Storage for Space Heating Application: A Review," Energies, MDPI, vol. 16(6), pages 1-54, March.
    9. Chao, Jingwei & Xu, Jiaxing & Yan, Taisen & Wang, Pengfei & Huo, Xiangyan & Wang, Ruzhu & Li, Tingxian, 2022. "Enhanced thermal conductivity and adsorption rate of zeolite 13X adsorbent by compression-induced molding method for sorption thermal battery," Energy, Elsevier, vol. 240(C).
    10. Feng, Changling & E, Jiaqiang & Han, Wei & Deng, Yuanwang & Zhang, Bin & Zhao, Xiaohuan & Han, Dandan, 2021. "Key technology and application analysis of zeolite adsorption for energy storage and heat-mass transfer process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    11. Strong, Curtis & Carrier, Ye & Handan Tezel, F., 2022. "Experimental optimization of operating conditions for an open bulk-scale silica gel/water vapour adsorption energy storage system," Applied Energy, Elsevier, vol. 312(C).
    12. Chen, Ziwei & Zhang, Yanan & Zhang, Yong & Su, Yuehong & Riffat, Saffa, 2023. "A study on vermiculite-based salt mixture composite materials for low-grade thermochemical adsorption heat storage," Energy, Elsevier, vol. 278(PB).
    13. Kuznik, Frédéric & Johannes, Kevyn & Obrecht, Christian & David, Damien, 2018. "A review on recent developments in physisorption thermal energy storage for building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 576-586.
    14. Ji, Wenjie & Zhang, Heng & Liu, Shuli & Wang, Zhihao & Deng, Shihan, 2022. "An experimental study on the binary hydrated salt composite zeolite for improving thermochemical energy storage performance," Renewable Energy, Elsevier, vol. 194(C), pages 1163-1173.
    15. Hamza Ayaz & Veerakumar Chinnasamy & Junhyeok Yong & Honghyun Cho, 2021. "Review of Technologies and Recent Advances in Low-Temperature Sorption Thermal Storage Systems," Energies, MDPI, vol. 14(19), pages 1-36, September.
    16. Andrea Frazzica & Vincenza Brancato & Belal Dawoud, 2020. "Unified Methodology to Identify the Potential Application of Seasonal Sorption Storage Technology," Energies, MDPI, vol. 13(5), pages 1-17, February.
    17. Kant, K. & Pitchumani, R., 2022. "Advances and opportunities in thermochemical heat storage systems for buildings applications," Applied Energy, Elsevier, vol. 321(C).
    18. N’Tsoukpoe, Kokouvi Edem & Kuznik, Frédéric, 2021. "A reality check on long-term thermochemical heat storage for household applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    19. Strelova, Svetlana V. & Gordeeva, Larisa G. & Grekova, Alexandra D. & Salanov, Aleksei N. & Aristov, Yuri I., 2023. "Composites “lithium chloride/vermiculite” for adsorption thermal batteries: Giant acceleration of sorption dynamics," Energy, Elsevier, vol. 263(PB).
    20. Courbon, Emilie & D'Ans, Pierre & Permyakova, Anastasia & Skrylnyk, Oleksandr & Steunou, Nathalie & Degrez, Marc & Frère, Marc, 2017. "A new composite sorbent based on SrBr2 and silica gel for solar energy storage application with high energy storage density and stability," Applied Energy, Elsevier, vol. 190(C), pages 1184-1194.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6572-:d:1238374. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.