IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i12p4339-d838307.html
   My bibliography  Save this article

Organic Salt Hydrate as a Novel Paradigm for Thermal Energy Storage

Author

Listed:
  • Emanuela Mastronardo

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Emanuele La Mazza

    (CNR ITAE “Nicola Giordano”, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • Davide Palamara

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Elpida Piperopoulos

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy
    CNR ITAE “Nicola Giordano”, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy
    National Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Florence, Italy)

  • Daniela Iannazzo

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Edoardo Proverbio

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Candida Milone

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy
    National Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Florence, Italy)

Abstract

The use of inorganic salt hydrates for thermochemical energy storage (TCS) applications is widely investigated. One of the drawbacks that researchers face when studying this class of materials is their tendency to undergo deliquescence phenomena. We here proposed and investigated, for the first time, the possibility of using organic salt hydrates as a paradigm for novel TCS materials with low water solubility, that is, more resistance to deliquescence, a tendency to coordinate a high number of water molecules and stability under operating conditions. The organic model compound chosen in this study was calcium; 7-[[2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoacetyl]amino]-3-[(2-methyl-5,6-dioxo-1H-1,2,4-triazin-3-yl)sulfanylmethyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate, known as calcium ceftriaxone, hereafter named CaHS (calcium hydrated salt), a water-insoluble organic salt, which can combine up to seven water molecules. The CaHS was prepared by precipitation from the water-soluble disodium triaxone. The thermal behavior of CaHS, in terms of stability and dehydration–hydration cyclability, was assessed. The material can operate in the temperature range of 30–150 °C, suitable for TCS. No deliquescence phenomena occurred upon exposure to a relative humidity (RH) between 10 and 100%. Its heat storage capacity, so far unknown, was measured to be ~595.2 kJ/kg (or ~278.6 kWh/m 3 ). The observed heat storage capacity, thermal stability, and good reversibility after dehydration–hydration cycles highlight the potential of this class of materials, thus opening new research paths for the development and investigation of innovative organic salt hydrates.

Suggested Citation

  • Emanuela Mastronardo & Emanuele La Mazza & Davide Palamara & Elpida Piperopoulos & Daniela Iannazzo & Edoardo Proverbio & Candida Milone, 2022. "Organic Salt Hydrate as a Novel Paradigm for Thermal Energy Storage," Energies, MDPI, vol. 15(12), pages 1-13, June.
  • Handle: RePEc:gam:jeners:v:15:y:2022:i:12:p:4339-:d:838307
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/12/4339/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/15/12/4339/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Donkers, P.A.J. & Sögütoglu, L.C. & Huinink, H.P. & Fischer, H.R. & Adan, O.C.G., 2017. "A review of salt hydrates for seasonal heat storage in domestic applications," Applied Energy, Elsevier, vol. 199(C), pages 45-68.
    2. N’Tsoukpoe, Kokouvi Edem & Schmidt, Thomas & Rammelberg, Holger Urs & Watts, Beatriz Amanda & Ruck, Wolfgang K.L., 2014. "A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage," Applied Energy, Elsevier, vol. 124(C), pages 1-16.
    3. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    4. N'Tsoukpoe, K. Edem & Liu, Hui & Le Pierrès, Nolwenn & Luo, Lingai, 2009. "A review on long-term sorption solar energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2385-2396, December.
    5. Michel, Benoit & Neveu, Pierre & Mazet, Nathalie, 2014. "Comparison of closed and open thermochemical processes, for long-term thermal energy storage applications," Energy, Elsevier, vol. 72(C), pages 702-716.
    6. Mehrabadi, Abbas & Farid, Mohammed, 2018. "New salt hydrate composite for low-grade thermal energy storage," Energy, Elsevier, vol. 164(C), pages 194-203.
    7. Gaeini, M. & Rouws, A.L. & Salari, J.W.O. & Zondag, H.A. & Rindt, C.C.M., 2018. "Characterization of microencapsulated and impregnated porous host materials based on calcium chloride for thermochemical energy storage," Applied Energy, Elsevier, vol. 212(C), pages 1165-1177.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yihan Wang & Zicheng Zhang & Shuli Liu & Zhihao Wang & Yongliang Shen, 2023. "Development and Characteristics Analysis of Novel Hydrated Salt Composite Adsorbents for Thermochemical Energy Storage," Energies, MDPI, vol. 16(18), pages 1-21, September.
    2. Wojtacha-Rychter, Karolina & Król, Magdalena & Lalik, Erwin & Śliwa, Michał & Kucharski, Piotr & Magdziarczyk, Małgorzata & Smoliński, Adam, 2024. "Experimental study of the new composite materials for thermochemical energy storage," Energy, Elsevier, vol. 296(C).
    3. Rozeline Wijnhorst & Menno Demmenie & Etienne Jambon-Puillet & Freek Ariese & Daniel Bonn & Noushine Shahidzadeh, 2023. "Softness of hydrated salt crystals under deliquescence," Nature Communications, Nature, vol. 14(1), pages 1-7, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    2. Hui Yang & Chengcheng Wang & Lige Tong & Shaowu Yin & Li Wang & Yulong Ding, 2023. "Salt Hydrate Adsorption Material-Based Thermochemical Energy Storage for Space Heating Application: A Review," Energies, MDPI, vol. 16(6), pages 1-54, March.
    3. Bennici, Simona & Dutournié, Patrick & Cathalan, Jérémy & Zbair, Mohamed & Nguyen, Minh Hoang & Scuiller, Elliot & Vaulot, Cyril, 2022. "Heat storage: Hydration investigation of MgSO4/active carbon composites, from material development to domestic applications scenarios," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    4. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2020. "Development and characteristics analysis of salt-hydrate based composite sorbent for low-grade thermochemical energy storage," Renewable Energy, Elsevier, vol. 157(C), pages 920-940.
    5. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    6. Gaeini, M. & Rouws, A.L. & Salari, J.W.O. & Zondag, H.A. & Rindt, C.C.M., 2018. "Characterization of microencapsulated and impregnated porous host materials based on calcium chloride for thermochemical energy storage," Applied Energy, Elsevier, vol. 212(C), pages 1165-1177.
    7. Pujari, Ankush Shankar & Majumdar, Rudrodip & Saha, Sandip K. & Subramaniam, Chandramouli, 2023. "Annular vertical cylindrical thermochemical storage system with innovative flow arrangements for improved heat dispatch towards space heating requirements," Renewable Energy, Elsevier, vol. 217(C).
    8. Mazur, Natalia & Blijlevens, Melian A.R. & Ruliaman, Rick & Fischer, Hartmut & Donkers, Pim & Meekes, Hugo & Vlieg, Elias & Adan, Olaf & Huinink, Henk, 2023. "Revisiting salt hydrate selection for domestic heat storage applications," Renewable Energy, Elsevier, vol. 218(C).
    9. N’Tsoukpoe, Kokouvi Edem & Kuznik, Frédéric, 2021. "A reality check on long-term thermochemical heat storage for household applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    10. Shkatulov, A.I. & Houben, J. & Fischer, H. & Huinink, H.P., 2020. "Stabilization of K2CO3 in vermiculite for thermochemical energy storage," Renewable Energy, Elsevier, vol. 150(C), pages 990-1000.
    11. Salviati, Sergio & Carosio, Federico & Cantamessa, Francesco & Medina, Lilian & Berglund, Lars A. & Saracco, Guido & Fina, Alberto, 2020. "Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites," Renewable Energy, Elsevier, vol. 160(C), pages 698-706.
    12. Zhang, Yong & Hu, Mingke & Chen, Ziwei & Su, Yuehong & Riffat, Saffa, 2024. "Exploring a novel tubular-type modular reactor for solar-driven thermochemical energy storage," Renewable Energy, Elsevier, vol. 221(C).
    13. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2021. "Numerical analysis on the improved thermo-chemical behaviour of hierarchical energy materials as a cascaded thermal accumulator," Energy, Elsevier, vol. 232(C).
    14. Isye Hayatina & Amar Auckaili & Mohammed Farid, 2023. "Review on Salt Hydrate Thermochemical Heat Transformer," Energies, MDPI, vol. 16(12), pages 1-23, June.
    15. Ding, Zhixiong & Wu, Wei & Leung, Michael, 2021. "Advanced/hybrid thermal energy storage technology: material, cycle, system and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    16. Scapino, Luca & Zondag, Herbert A. & Diriken, Jan & Rindt, Camilo C.M. & Van Bael, Johan & Sciacovelli, Adriano, 2019. "Modeling the performance of a sorption thermal energy storage reactor using artificial neural networks," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    17. Mamani, V. & Gutiérrez, A. & Fernández, A.I. & Ushak, S., 2020. "Industrial carnallite-waste for thermochemical energy storage application," Applied Energy, Elsevier, vol. 265(C).
    18. Mukherjee, Ankit & Pujari, Ankush Shankar & Shinde, Shraddha Nitin & Kashyap, Uddip & Kumar, Lalit & Subramaniam, Chandramouli & Saha, Sandip K., 2022. "Performance assessment of open thermochemical energy storage system for seasonal space heating in highly humid environment," Renewable Energy, Elsevier, vol. 201(P1), pages 204-223.
    19. Ait Ousaleh, Hanane & Sair, Said & Zaki, Abdelali & Younes, Abboud & Faik, Abdessamad & El Bouari, Abdeslam, 2020. "Advanced experimental investigation of double hydrated salts and their composite for improved cycling stability and metal compatibility for long-term heat storage technologies," Renewable Energy, Elsevier, vol. 162(C), pages 447-457.
    20. Michel, Benoit & Mazet, Nathalie & Neveu, Pierre, 2016. "Experimental investigation of an open thermochemical process operating with a hydrate salt for thermal storage of solar energy: Local reactive bed evolution," Applied Energy, Elsevier, vol. 180(C), pages 234-244.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:12:p:4339-:d:838307. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.