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Organic Salt Hydrate as a Novel Paradigm for Thermal Energy Storage

Author

Listed:
  • Emanuela Mastronardo

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Emanuele La Mazza

    (CNR ITAE “Nicola Giordano”, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • Davide Palamara

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Elpida Piperopoulos

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy
    CNR ITAE “Nicola Giordano”, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy
    National Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Florence, Italy)

  • Daniela Iannazzo

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Edoardo Proverbio

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy)

  • Candida Milone

    (Engineering Department, University of Messina, Contrada di Dio, 98166 Messina, Italy
    National Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Florence, Italy)

Abstract

The use of inorganic salt hydrates for thermochemical energy storage (TCS) applications is widely investigated. One of the drawbacks that researchers face when studying this class of materials is their tendency to undergo deliquescence phenomena. We here proposed and investigated, for the first time, the possibility of using organic salt hydrates as a paradigm for novel TCS materials with low water solubility, that is, more resistance to deliquescence, a tendency to coordinate a high number of water molecules and stability under operating conditions. The organic model compound chosen in this study was calcium; 7-[[2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoacetyl]amino]-3-[(2-methyl-5,6-dioxo-1H-1,2,4-triazin-3-yl)sulfanylmethyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate, known as calcium ceftriaxone, hereafter named CaHS (calcium hydrated salt), a water-insoluble organic salt, which can combine up to seven water molecules. The CaHS was prepared by precipitation from the water-soluble disodium triaxone. The thermal behavior of CaHS, in terms of stability and dehydration–hydration cyclability, was assessed. The material can operate in the temperature range of 30–150 °C, suitable for TCS. No deliquescence phenomena occurred upon exposure to a relative humidity (RH) between 10 and 100%. Its heat storage capacity, so far unknown, was measured to be ~595.2 kJ/kg (or ~278.6 kWh/m 3 ). The observed heat storage capacity, thermal stability, and good reversibility after dehydration–hydration cycles highlight the potential of this class of materials, thus opening new research paths for the development and investigation of innovative organic salt hydrates.

Suggested Citation

  • Emanuela Mastronardo & Emanuele La Mazza & Davide Palamara & Elpida Piperopoulos & Daniela Iannazzo & Edoardo Proverbio & Candida Milone, 2022. "Organic Salt Hydrate as a Novel Paradigm for Thermal Energy Storage," Energies, MDPI, vol. 15(12), pages 1-13, June.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:12:p:4339-:d:838307
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    References listed on IDEAS

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    Cited by:

    1. Yihan Wang & Zicheng Zhang & Shuli Liu & Zhihao Wang & Yongliang Shen, 2023. "Development and Characteristics Analysis of Novel Hydrated Salt Composite Adsorbents for Thermochemical Energy Storage," Energies, MDPI, vol. 16(18), pages 1-21, September.
    2. Wojtacha-Rychter, Karolina & Król, Magdalena & Lalik, Erwin & Śliwa, Michał & Kucharski, Piotr & Magdziarczyk, Małgorzata & Smoliński, Adam, 2024. "Experimental study of the new composite materials for thermochemical energy storage," Energy, Elsevier, vol. 296(C).
    3. Rozeline Wijnhorst & Menno Demmenie & Etienne Jambon-Puillet & Freek Ariese & Daniel Bonn & Noushine Shahidzadeh, 2023. "Softness of hydrated salt crystals under deliquescence," Nature Communications, Nature, vol. 14(1), pages 1-7, December.

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