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Preparation of phosphotungstic acid based poly(ionic liquid) and its application to esterification of palmitic acid

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  • Wang, Yongqiang
  • Zhao, Dan
  • Chen, Guanyi
  • Liu, Shejiang
  • Ji, Na
  • Ding, Hui
  • Fu, Jianfeng

Abstract

For biodiesel production from waste cooking oils with high acid values, an inefficient esterification pretreatment is always conducted to convert free fatty acids (FFAs) before alkali-catalysed transesterification process. In this paper, phosphotungstic acid based poly(ionic liquid) was prepared to catalyse the esterification of palmitic acid with methanol while the required catalyst dosage was much lower than commercial Amberlyst-15. And the catalyst was characterized by 31P CP-MAS NMR, FTIR, SEM, XRF and TG. Among the three poly(ionic liquid)s prepared in this paper, phosphotungstic acid based poly(ionic liquid) was selected to be the most suitable catalyst for esterification because the catalyst could be reused for more than 5 times without significant deactivation. According to single factor analyses, the esterification yield could reach 91.6% after 8 h while the reaction temperature, methanol to acid molar ratio and catalyst dosage were 65 °C, 6 and 3% wt, respectively. Afterwards, palmitic acid was proposed to be first adsorbed on the catalyst before reacting with methanol. Finally, a palmitic acid adsorbed Eley-Rideal model was employed to analyse the reaction and the adsorption mechanism was assumed as well.

Suggested Citation

  • Wang, Yongqiang & Zhao, Dan & Chen, Guanyi & Liu, Shejiang & Ji, Na & Ding, Hui & Fu, Jianfeng, 2019. "Preparation of phosphotungstic acid based poly(ionic liquid) and its application to esterification of palmitic acid," Renewable Energy, Elsevier, vol. 133(C), pages 317-324.
    • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:317-324
    DOI: 10.1016/j.renene.2018.10.029
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    2. Guliani, Disha & Sobti, Amit & Toor, Amrit Pal, 2022. "Titania impregnated mesoporous MCM-48 as a solid photo-catalyst for the synthesis of methyl palmitate: Reaction mechanism and kinetics," Renewable Energy, Elsevier, vol. 191(C), pages 405-417.
    3. Han, Xiaoxiang & Jiang, Shengchou & Chen, Ziyi & Zeng, Zhiwei & Chen, Qing & Niu, Fuge & Pan, Weichun & Tang, Xiujuan & Liu, Shang-Bin, 2023. "Highly active sulfonic ionic liquid modified heteropoly acid composite catalysts for efficient production of ethyl palmitate," Renewable Energy, Elsevier, vol. 215(C).
    4. Li, Mantian & Chen, Jinyi & Huang, Youjie & Li, Meichen & Lin, Xiaocheng & Qiu, Ting, 2020. "Reusable and efficient heterogeneous catalysts for biodiesel production from free fatty acids and oils: Self-solidifying hybrid ionic liquids," Energy, Elsevier, vol. 211(C).
    5. Qu, Tongxin & Niu, Shengli & Gong, Zhiqiang & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2020. "Wollastonite decorated with calcium oxide as heterogeneous transesterification catalyst for biodiesel production: Optimized by response surface methodology," Renewable Energy, Elsevier, vol. 159(C), pages 873-884.

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