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Synthesis of biodiesel from waste oil under mild conditions using novel acidic ionic liquid immobilization on poly divinylbenzene

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  • Liang, Xuezheng

Abstract

The one-step synthesis of biodiesel from waste oil with high FFAs (free fatty acids) content was developed under mild condition (70 °C, 1 atm) using novel acidic ionic liquid immobilization on PDVB (poly divinylbenzene) as catalyst. The solid acid owns high activities for both the esterification of FFAs and transesterification of triglyceride with total yield over 99.0%. The novel solid acid combined the high activities of acidic ionic liquids and the easy separation of solid catalysts. The mild reaction conditions, high catalytic activities, high total yield, reusability and high stability were the key properties of the novel methodology, which would greatly reduce the production cost for the industrial application.

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  • Liang, Xuezheng, 2013. "Synthesis of biodiesel from waste oil under mild conditions using novel acidic ionic liquid immobilization on poly divinylbenzene," Energy, Elsevier, vol. 63(C), pages 103-108.
    • Handle: RePEc:eee:energy:v:63:y:2013:i:c:p:103-108
    DOI: 10.1016/j.energy.2013.10.043
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    2. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    3. Ullah, Zahoor & Bustam, M. Azmi & Man, Zakaria & Khan, Amir Sada & Muhammad, Nawshad & Sarwono, Ariyanti, 2017. "Preparation and kinetics study of biodiesel production from waste cooking oil using new functionalized ionic liquids as catalysts," Renewable Energy, Elsevier, vol. 114(PB), pages 755-765.
    4. Go, Alchris Woo & Tran Nguyen, Phuong Lan & Huynh, Lien Huong & Liu, Ying-Tsung & Sutanto, Sylviana & Ju, Yi-Hsu, 2014. "Catalyst free esterification of fatty acids with methanol under subcritical condition," Energy, Elsevier, vol. 70(C), pages 393-400.
    5. Wang, Yongqiang & Zhao, Dan & Chen, Guanyi & Liu, Shejiang & Ji, Na & Ding, Hui & Fu, Jianfeng, 2019. "Preparation of phosphotungstic acid based poly(ionic liquid) and its application to esterification of palmitic acid," Renewable Energy, Elsevier, vol. 133(C), pages 317-324.
    6. Mehrasbi, Mohammad Reza & Mohammadi, Javad & Peyda, Mazyar & Mohammadi, Mehdi, 2017. "Covalent immobilization of Candida antarctica lipase on core-shell magnetic nanoparticles for production of biodiesel from waste cooking oil," Renewable Energy, Elsevier, vol. 101(C), pages 593-602.
    7. Troter, Dragan Z. & Todorović, Zoran B. & Đokić-Stojanović, Dušica R. & Stamenković, Olivera S. & Veljković, Vlada B., 2016. "Application of ionic liquids and deep eutectic solvents in biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 473-500.
    8. Pleşu, Valentin & Subirana Puigcasas, Joan & Benet Surroca, Guillem & Bonet, Jordi & Bonet Ruiz, Alexandra E. & Tuluc, Alexandru & Llorens, Joan, 2015. "Process intensification in biodiesel production with energy reduction by pinch analysis," Energy, Elsevier, vol. 79(C), pages 273-287.
    9. Ding, Hui & Ye, Wei & Wang, Yongqiang & Wang, Xianqin & Li, Lujun & Liu, Dan & Gui, Jianzhou & Song, Chunfeng & Ji, Na, 2018. "Process intensification of transesterification for biodiesel production from palm oil: Microwave irradiation on transesterification reaction catalyzed by acidic imidazolium ionic liquids," Energy, Elsevier, vol. 144(C), pages 957-967.

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