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Biodiesel production from soybean and Jatropha oils using cesium impregnated sodium zirconate as a heterogeneous base catalyst

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  • Torres-Rodríguez, Daniela A.
  • Romero-Ibarra, Issis C.
  • Ibarra, Ilich A.
  • Pfeiffer, Heriberto

Abstract

Cesium modified sodium zirconate (Cs-Na2ZrO3) was prepared by ionic exchange from sodium zirconate (Na2ZrO3), which was synthesized via a solid state reaction. Both ceramics, i.e., pristine Na2ZrO3 and the Cs-Na2ZrO3, were used as basic heterogeneous catalysts in biodiesel production. Soybean and Jatropha oils were used as triglyceride sources for transesterification reactions. Parameters, such as catalyst concentration (between 0.5 and 3 wt%), reaction time, different methanol/vegetable oil molar ratios, and temperature of the reaction, were evaluated. The cesium cation influence was evaluated from the basic transesterification reactivity. The results showed that the introduction of cesium significantly modified the catalytic activity in biodiesel production. Cs enhanced the reaction kinetics in obtaining biodiesel and reduced the reaction time in comparison with pristine Na2ZrO3. The results showed that Cs-Na2ZrO3 as a basic heterogeneous catalyst exhibited the best fatty acid methyl esters (FAME) conversion for soybean oil (98.8%) at 1 wt%, 30:1 methanol/oil ratio, 65 °C, and 15 min. The best conditions for Jatropha oil (90.8%) were 3 wt%, 15:1 methanol/oil ratio, 65 °C, and 1 h. The impregnation of Na2ZrO3 with cesium represents a very exciting alternative heterogeneous base catalyst for biodiesel production.

Suggested Citation

  • Torres-Rodríguez, Daniela A. & Romero-Ibarra, Issis C. & Ibarra, Ilich A. & Pfeiffer, Heriberto, 2016. "Biodiesel production from soybean and Jatropha oils using cesium impregnated sodium zirconate as a heterogeneous base catalyst," Renewable Energy, Elsevier, vol. 93(C), pages 323-331.
    • Handle: RePEc:eee:renene:v:93:y:2016:i:c:p:323-331
    DOI: 10.1016/j.renene.2016.02.061
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    1. Lee, H.V. & Juan, J.C. & Taufiq-Yap, Y.H., 2015. "Preparation and application of binary acid–base CaO–La2O3 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 74(C), pages 124-132.
    2. De Meyer, Annelies & Cattrysse, Dirk & Rasinmäki, Jussi & Van Orshoven, Jos, 2014. "Methods to optimise the design and management of biomass-for-bioenergy supply chains: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 657-670.
    3. Chouhan, A.P. Singh & Sarma, A.K., 2011. "Modern heterogeneous catalysts for biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4378-4399.
    4. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    5. Guo, Pingmei & Zheng, Chang & Zheng, Mingming & Huang, Fenghong & Li, Wenlin & Huang, Qingde, 2013. "Solid base catalysts for production of fatty acid methyl esters," Renewable Energy, Elsevier, vol. 53(C), pages 377-383.
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