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Numerical study on effect of oxygen content in combustion air on ammonia combustion

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  • Li, Jun
  • Huang, Hongyu
  • Kobayashi, Noriyuki
  • He, Zhaohong
  • Osaka, Yugo
  • Zeng, Tao

Abstract

As a key parameter for a fuel in real combustion development, burning velocity of NH3 which is usually low limits its application in the energy device. In this study, the combustion of NH3 at oxygen enriched condition has been proposed as a novel method for improving NH3 combustion. The oxygen concentration in the combustion air was varied from 21% to 30%. The results show that O2-enriched combustion has positive effects on both laminar burning velocity and adiabatic flame temperature of NH3. The maximum burning velocity of NH3 is 38.6 cm/s at O2 content of 30%, which is approximately 2.6 times the value obtained at an O2 content of 21%, mainly due to the increased reaction rates of OH, H, O, and NH2 radicals in the reaction zone at higher O2 contents. NO emissions increase with an increase in the O2 content of the combustion air. Whereas, the reactions between NO and surplus NH2, NH and N radicals cause more NO consumption especially at fuel-rich conditions, showing the potential in reducing NO emission in NH3-air combustion. Therefore, O2-enriched combustion is a suitable method for improving NH3 combustion when NH3 is utilized as fuel.

Suggested Citation

  • Li, Jun & Huang, Hongyu & Kobayashi, Noriyuki & He, Zhaohong & Osaka, Yugo & Zeng, Tao, 2015. "Numerical study on effect of oxygen content in combustion air on ammonia combustion," Energy, Elsevier, vol. 93(P2), pages 2053-2068.
    • Handle: RePEc:eee:energy:v:93:y:2015:i:p2:p:2053-2068
    DOI: 10.1016/j.energy.2015.10.060
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    References listed on IDEAS

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    14. Joanna Jójka & Rafał Ślefarski, 2021. "Emission Characteristics for Swirl Methane–Air Premixed Flames with Ammonia Addition," Energies, MDPI, vol. 14(3), pages 1-19, January.
    15. Chen, Danan & Li, Jun & Li, Xing & Deng, Lisheng & He, Zhaohong & Huang, Hongyu & Kobayashi, Noriyuki, 2023. "Study on combustion characteristics of hydrogen addition on ammonia flame at a porous burner," Energy, Elsevier, vol. 263(PA).
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    18. Li, Yanchao & Bi, Mingshu & Li, Bei & Zhou, Yonghao & Huang, Lei & Gao, Wei, 2018. "Explosion hazard evaluation of renewable hydrogen/ammonia/air fuels," Energy, Elsevier, vol. 159(C), pages 252-263.
    19. Ahmed T. Khalil & Dimitris M. Manias & Efstathios-Al. Tingas & Dimitrios C. Kyritsis & Dimitris A. Goussis, 2019. "Algorithmic Analysis of Chemical Dynamics of the Autoignition of NH 3 –H 2 O 2 /Air Mixtures," Energies, MDPI, vol. 12(23), pages 1-14, November.
    20. Chai, Wai Siong & Bao, Yulei & Jin, Pengfei & Tang, Guang & Zhou, Lei, 2021. "A review on ammonia, ammonia-hydrogen and ammonia-methane fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    21. Ali, Asif & Nemitallah, Medhat A. & Abdelhafez, Ahmed & Hussain, Muzafar & Kamal, M. Mustafa & Habib, Mohamed A., 2021. "Comparative analysis of the stability and structure of premixed C3H8/O2/CO2 and C3H8/O2/N2 flames for clean flexible energy production," Energy, Elsevier, vol. 214(C).
    22. Pan, Suyang & Ma, Jiliang & Chen, Xiaoping & Liu, Daoyin & Liang, Cai, 2023. "NH3/O2 premixed combustion in a single bubble of fluidized bed," Applied Energy, Elsevier, vol. 349(C).

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