IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v285y2023ics0360544223028062.html
   My bibliography  Save this article

Insight into NOx formation characteristics of ammonia oxidation in N2 and H2O atmospheres

Author

Listed:
  • Shi, Guodong
  • Li, Pengfei
  • Li, Kesheng
  • Hu, Fan
  • Liu, Qian
  • Zhou, Haoyu
  • Liu, Zhaohui

Abstract

For the practical combustion of ammonia (NH3) in air, ammonia jet entrains the combustion product inside the furnace, and the reaction zone is diluted with a significant amount of H2O; thus, the impact of H2O on NH3 oxidation cannot be ignored. In this study, NH3 oxidation was conducted under N2 and H2O atmospheres in a jet-stirred reactor. Experimental and numerical investigations were conducted to analyze the impact of various parameters, including the temperature, equivalence ratio, H2O volume fraction, and residence time. The NO formation is enhanced as T increases, while it is inhibited as Φ or XH2O increases. The N2O and NO concentrations are an order of magnitude when T ≤ 1375 K, and the peak N2O concentration occurs at T ≈ 1375 K and Φ = 0.5. The presence of 20 % H2O reduces NO and N2O concentrations by 61.5 % and 29.5 %, respectively, at Φ = 0.5 and T = 1375 K. To reduce NOx formation with an acceptable concentration of unburned NH3, the recommended operation condition of NH3 oxidation is obtained. This study presents a new underlying understanding of the formation of NOx during NH3 oxidation under N2 and H2O atmospheres.

Suggested Citation

  • Shi, Guodong & Li, Pengfei & Li, Kesheng & Hu, Fan & Liu, Qian & Zhou, Haoyu & Liu, Zhaohui, 2023. "Insight into NOx formation characteristics of ammonia oxidation in N2 and H2O atmospheres," Energy, Elsevier, vol. 285(C).
    • Handle: RePEc:eee:energy:v:285:y:2023:i:c:s0360544223028062
    DOI: 10.1016/j.energy.2023.129412
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223028062
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.129412?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mohammadpour, Mohammadreza & Ashjaee, Mehdi & Houshfar, Ehsan, 2022. "Thermal performance and heat transfer characteristics analyses of oxy-biogas combustion in a swirl stabilized boiler under various oxidizing environments," Energy, Elsevier, vol. 261(PA).
    2. Khasani, & Prasidha, Willie & Widyatama, Arif & Aziz, Muhammad, 2021. "Energy-saving and environmentally-benign integrated ammonia production system," Energy, Elsevier, vol. 235(C).
    3. Liu, Songlin & Fan, Weidong & Guo, Hao & Wu, Xiaofeng & Chen, Jun & Liu, Zhuang & Wang, Xin, 2020. "Relationship between the N2O decomposition and NO formation in H2O/CO2/NH3/NO atmosphere under the conditions of simulated air-staged combustion in the temperature interval of 900–1600 °C," Energy, Elsevier, vol. 211(C).
    4. Ku, J.W. & Ahn, Y.J. & Kim, H.K. & Kim, Y.H. & Kwon, O.C., 2020. "Propagation and emissions of premixed methane-ammonia/air flames," Energy, Elsevier, vol. 201(C).
    5. Rahman, Zia ur & Wang, Xuebin & Zhang, Jiaye & Yang, Zhiwei & Dai, Gaofeng & Verma, Piyush & Mikulcic, Hrvoje & Vujanovic, Milan & Tan, Houzhang & Axelbaum, Richard L., 2022. "Nitrogen evolution, NOX formation and reduction in pressurized oxy coal combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    6. Zhu, Jizhen & Zhou, Dezhi & Yang, Wenming & Qian, Yong & Mao, Yebing & Lu, Xingcai, 2023. "Investigation on the potential of using carbon-free ammonia in large two-stroke marine engines by dual-fuel combustion strategy," Energy, Elsevier, vol. 263(PB).
    7. Wei, Wenwen & Li, Gesheng & Zhang, Zunhua & Long, Yanxiang & Zhang, Hanyuyang & Huang, Yong & Zhou, Mengni & Wei, Yi, 2023. "Effects of ammonia addition on the performance and emissions for a spark-ignition marine natural gas engine," Energy, Elsevier, vol. 272(C).
    8. Cai, Tao & Zhao, Dan & Chan, Siew Hwa & Shahsavari, Mohammad, 2022. "Tailoring reduced mechanisms for predicting flame propagation and ignition characteristics in ammonia and ammonia/hydrogen mixtures," Energy, Elsevier, vol. 260(C).
    9. Chen, Yuhong & Lyu, Yanfeng & Yang, Xiangdong & Zhang, Xiaohong & Pan, Hengyu & Wu, Jun & Lei, Yongjia & Zhang, Yanzong & Wang, Guiyin & Xu, Min & Luo, Hongbin, 2022. "Performance comparison of urea production using one set of integrated indicators considering energy use, economic cost and emissions’ impacts: A case from China," Energy, Elsevier, vol. 254(PC).
    10. Guteša Božo, M. & Vigueras-Zuniga, MO. & Buffi, M. & Seljak, T. & Valera-Medina, A., 2019. "Fuel rich ammonia-hydrogen injection for humidified gas turbines," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    11. Li, Jun & Huang, Hongyu & Kobayashi, Noriyuki & He, Zhaohong & Osaka, Yugo & Zeng, Tao, 2015. "Numerical study on effect of oxygen content in combustion air on ammonia combustion," Energy, Elsevier, vol. 93(P2), pages 2053-2068.
    12. Boulamanti, Aikaterini & Moya, Jose A., 2017. "Production costs of the chemical industry in the EU and other countries: Ammonia, methanol and light olefins," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P2), pages 1205-1212.
    13. Woo, Mino & Choi, Byung Chul, 2021. "Numerical study on fuel-NO formation characteristics of ammonia-added methane fuel in laminar non-premixed flames with oxygen/carbon dioxide oxidizer," Energy, Elsevier, vol. 226(C).
    14. Wu, Fang-Hsien & Chen, Guan-Bang, 2020. "Numerical study of hydrogen peroxide enhancement of ammonia premixed flames," Energy, Elsevier, vol. 209(C).
    15. Issayev, Gani & Giri, Binod Raj & Elbaz, Ayman M. & Shrestha, Krishna P. & Mauss, Fabian & Roberts, William L. & Farooq, Aamir, 2022. "Ignition delay time and laminar flame speed measurements of ammonia blended with dimethyl ether: A promising low carbon fuel blend," Renewable Energy, Elsevier, vol. 181(C), pages 1353-1370.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cai, Tao & Zhao, Dan & Chan, Siew Hwa & Shahsavari, Mohammad, 2022. "Tailoring reduced mechanisms for predicting flame propagation and ignition characteristics in ammonia and ammonia/hydrogen mixtures," Energy, Elsevier, vol. 260(C).
    2. Chai, Wai Siong & Bao, Yulei & Jin, Pengfei & Tang, Guang & Zhou, Lei, 2021. "A review on ammonia, ammonia-hydrogen and ammonia-methane fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    3. Liu, Xing & Wang, Ying & Bai, Yuanqi & Yang, Wenxu, 2023. "Development of reduced and optimized mechanism for ammonia/ hydrogen mixture based on genetic algorithm," Energy, Elsevier, vol. 270(C).
    4. Hookyung Lee & Min-Jung Lee, 2021. "Recent Advances in Ammonia Combustion Technology in Thermal Power Generation System for Carbon Emission Reduction," Energies, MDPI, vol. 14(18), pages 1-29, September.
    5. Rafael Estevez & Francisco J. López-Tenllado & Laura Aguado-Deblas & Felipa M. Bautista & Antonio A. Romero & Diego Luna, 2023. "Current Research on Green Ammonia (NH 3 ) as a Potential Vector Energy for Power Storage and Engine Fuels: A Review," Energies, MDPI, vol. 16(14), pages 1-33, July.
    6. Chen, Danan & Li, Jun & Li, Xing & Deng, Lisheng & He, Zhaohong & Huang, Hongyu & Kobayashi, Noriyuki, 2023. "Study on combustion characteristics of hydrogen addition on ammonia flame at a porous burner," Energy, Elsevier, vol. 263(PA).
    7. Yin, Bingqian & Lu, Zhen & Shi, Lei & Lu, Tianlong & Ye, Jianpeng & Ma, Junqing & Wang, Tianyou, 2024. "Numerical simulation of a spark ignition ammonia marine engine for future ship power applications," Energy, Elsevier, vol. 302(C).
    8. Dai, Gaofeng & Zhang, Jiaye & Wang, Xuebin & Tan, Houzhang & Rahman, Zia ur, 2022. "Calcination and desulfurization characteristics of calcium carbonate in pressurized oxy-combustion," Energy, Elsevier, vol. 261(PA).
    9. Stančin, H. & Mikulčić, H. & Wang, X. & Duić, N., 2020. "A review on alternative fuels in future energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    10. Chen, Yuhong & Lyu, Yanfeng & Yang, Xiangdong & Zhang, Xiaohong & Pan, Hengyu & Wu, Jun & Lei, Yongjia & Zhang, Yanzong & Wang, Guiyin & Xu, Min & Luo, Hongbin, 2022. "Performance comparison of urea production using one set of integrated indicators considering energy use, economic cost and emissions’ impacts: A case from China," Energy, Elsevier, vol. 254(PC).
    11. Wu, Fang-Hsien & Chen, Guan-Bang, 2020. "Numerical study of hydrogen peroxide enhancement of ammonia premixed flames," Energy, Elsevier, vol. 209(C).
    12. Anwar Hamdan Al Assaf & Abdulkarem Amhamed & Odi Fawwaz Alrebei, 2022. "State of the Art in Humidified Gas Turbine Configurations," Energies, MDPI, vol. 15(24), pages 1-32, December.
    13. Wu, Chenxi & Zhu, Qunzhi & Dou, Binlin & Fu, Zaiguo & Wang, Jikai & Mao, Siqi, 2024. "Thermodynamic analysis of a solid oxide electrolysis cell system in thermoneutral mode integrated with industrial waste heat for hydrogen production," Energy, Elsevier, vol. 301(C).
    14. Yadav, Deepak & Banerjee, Rangan, 2020. "Net energy and carbon footprint analysis of solar hydrogen production from the high-temperature electrolysis process," Applied Energy, Elsevier, vol. 262(C).
    15. Oleg Bazaluk & Valerii Havrysh & Vitalii Nitsenko & Tomas Baležentis & Dalia Streimikiene & Elena A. Tarkhanova, 2020. "Assessment of Green Methanol Production Potential and Related Economic and Environmental Benefits: The Case of China," Energies, MDPI, vol. 13(12), pages 1-25, June.
    16. Sun, Xilei & Fu, Jianqin, 2024. "Many-objective optimization of BEV design parameters based on gradient boosting decision tree models and the NSGA-III algorithm considering the ambient temperature," Energy, Elsevier, vol. 288(C).
    17. Zhang, Zhiqing & Dong, Rui & Tan, Dongli & Duan, Lin & Jiang, Feng & Yao, Xiaoxue & Yang, Dixin & Hu, Jingyi & Zhang, Jian & Zhong, Weihuang & Zhao, Ziheng, 2023. "Effect of structural parameters on diesel particulate filter trapping performance of heavy-duty diesel engines based on grey correlation analysis," Energy, Elsevier, vol. 271(C).
    18. Wei, Wenwen & Li, Gesheng & Zhang, Zunhua & Long, Yanxiang & Zhang, Hanyuyang & Huang, Yong & Zhou, Mengni & Wei, Yi, 2023. "Effects of ammonia addition on the performance and emissions for a spark-ignition marine natural gas engine," Energy, Elsevier, vol. 272(C).
    19. Joanna Jójka & Rafał Ślefarski, 2021. "Emission Characteristics for Swirl Methane–Air Premixed Flames with Ammonia Addition," Energies, MDPI, vol. 14(3), pages 1-19, January.
    20. Seong-Jun Yang & Ji-Young Eom & Myung-Jin Lee & Dae-Hwan Hwang & Won-Bin Park & Young-Min Wie & Ki-Gang Lee & Kang-Hoon Lee, 2023. "Comparative Environmental Evaluation of Sewage Sludge Treatment and Aggregate Production Process by Life Cycle Assessment," Sustainability, MDPI, vol. 16(1), pages 1-19, December.

    More about this item

    Keywords

    NOx; Ammonia; H2O atmosphere; Jet-stirred reactor; N2O;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:285:y:2023:i:c:s0360544223028062. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.