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Study on effects of ethylene or acetylene addition on the stability of ammonia laminar diffusion flame by optical diagnostics and chemical kinetics

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  • Guo, Liang
  • Yu, Changyou
  • Sun, Wanchen
  • Zhang, Hao
  • Cheng, Peng
  • Yan, Yuying
  • Lin, Shaodian
  • Zeng, Wenpeng
  • Zhu, Genan
  • Jiang, Mengqi

Abstract

Improvement of ammonia combustion characteristics by carbon-based combustion promoters is currently emphasized, but the impact of carbon‑carbon multi-bond structure on ammonia combustion characteristics and reaction mechanisms has not been sufficiently investigated. In order to investigate the mechanism of molecular structures (C=C and C≡C) of combustion promoters on the stability of ammonia flames, the flame morphology, flame structure, NH3-H2 cracking, and C-N cross-reaction of ammonia/ethylene and ammonia/acetylene laminar diffusion flame are investigated based on a Gu¨lder burner by utilizing high-speed photography, planar laser-induced fluorescence (PLIF) and laser spontaneous Raman scattering (SRS) techniques. The results show that acetylene addition is more effective than ethylene to improve the flame stability. Combined with the flame structure analysis, it is shown that C=C mainly enhances the low-temperature reaction stage intensity of laminar flame, while C≡C can both enhance the intensity of low-temperature and high-temperature reaction stages, thereby enhancing the flame combustion exothermic process. Besides, C=C mainly strengthens the exothermic reactions in the upstream of the flame whereas C≡C can strengthen the exothermic reactions in the upstream and downstream of the flame simultaneously. Investigation of the NH3-H2 cracking reactions reveals that C≡C promotes H2 generation mainly by increasing NH3→H2 cracking, whereas C=C promotes H2 generation mainly by increasing NH2→H2 and NH→H cracking, hence improving the flame stability. Further analysis through the reaction flows revels that C=C acts mainly on H-containing species HCN/HNCO whereas C≡C mainly acts on non-H-containing species CN/NCO to influence the reaction pathways, but C-N cross-reaction does not play an important role in the characteristics of ammonia composite combustion (ACC).

Suggested Citation

  • Guo, Liang & Yu, Changyou & Sun, Wanchen & Zhang, Hao & Cheng, Peng & Yan, Yuying & Lin, Shaodian & Zeng, Wenpeng & Zhu, Genan & Jiang, Mengqi, 2024. "Study on effects of ethylene or acetylene addition on the stability of ammonia laminar diffusion flame by optical diagnostics and chemical kinetics," Applied Energy, Elsevier, vol. 362(C).
    • Handle: RePEc:eee:appene:v:362:y:2024:i:c:s030626192400415x
    DOI: 10.1016/j.apenergy.2024.123032
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    1. Wu, Binyang & Wang, Yusong & Wang, Decheng & Feng, Yongming & Jin, Shouying, 2023. "Generation mechanism and emission characteristics of N2O and NOx in ammonia-diesel dual-fuel engine," Energy, Elsevier, vol. 284(C).
    2. Bharath, G. & Karthikeyan, G. & Kumar, Anuj & Prakash, J. & Venkatasubbu, Devanand & Kumar Nadda, Ashok & Kumar Gupta, Vijai & Abu Haija, Mohammad & Banat, Fawzi, 2022. "Surface engineering of Au nanostructures for plasmon-enhanced electrochemical reduction of N2 and CO2 into urea in the visible-NIR region," Applied Energy, Elsevier, vol. 318(C).
    3. Xu, Leilei & Xu, Shijie & Bai, Xue-Song & Repo, Juho Aleksi & Hautala, Saana & Hyvönen, Jari, 2023. "Performance and emission characteristics of an ammonia/diesel dual-fuel marine engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).
    4. Askari, Omid & Vien, Kevin & Wang, Ziyu & Sirio, Matteo & Metghalchi, Hameed, 2016. "Exhaust gas recirculation effects on flame structure and laminar burning speeds of H2/CO/air flames at high pressures and temperatures," Applied Energy, Elsevier, vol. 179(C), pages 451-462.
    5. Ryu, Kyunghyun & Zacharakis-Jutz, George E. & Kong, Song-Charng, 2014. "Performance characteristics of compression-ignition engine using high concentration of ammonia mixed with dimethyl ether," Applied Energy, Elsevier, vol. 113(C), pages 488-499.
    6. Wang, Ziyu & Lu, Zhenyu & Yelishala, Sai C. & Metghalchi, Hameed & Levendis, Yiannis A., 2021. "Flame characteristics of propane-air-carbon dioxide blends at elevated temperatures and pressures," Energy, Elsevier, vol. 228(C).
    7. Nadimi, Ebrahim & Przybyła, Grzegorz & Løvås, Terese & Peczkis, Grzegorz & Adamczyk, Wojciech, 2023. "Experimental and numerical study on direct injection of liquid ammonia and its injection timing in an ammonia-biodiesel dual injection engine," Energy, Elsevier, vol. 284(C).
    8. Tay, Kun Lin & Yang, Wenming & Li, Jing & Zhou, Dezhi & Yu, Wenbin & Zhao, Feiyang & Chou, Siaw Kiang & Mohan, Balaji, 2017. "Numerical investigation on the combustion and emissions of a kerosene-diesel fueled compression ignition engine assisted by ammonia fumigation," Applied Energy, Elsevier, vol. 204(C), pages 1476-1488.
    9. Shen, Xiaobo & Zhang, Zhenwu & Dou, Zengguo & Cong, Beihua & Xiao, Qiuping & Liu, Haifeng, 2022. "Premixed syngas/air combustion in closed ducts with varied aspect ratios and initial pressures," Energy, Elsevier, vol. 254(PC).
    10. Tu, Yaojie & Xu, Mingchen & Zhou, Dezhi & Wang, Qingxiang & Yang, Wenming & Liu, Hao, 2019. "CFD and kinetic modelling study of methane MILD combustion in O2/N2, O2/CO2 and O2/H2O atmospheres," Applied Energy, Elsevier, vol. 240(C), pages 1003-1013.
    11. Shen, Xiaobo & Zhang, Zhenwu & Dou, Zengguo & Zhang, Chao, 2021. "Premixed CO/air combustion in a closed duct with inhibition," Energy, Elsevier, vol. 230(C).
    12. Zhong, Kengqiang & Li, Meng & Yang, Yue & Zhang, Hongguo & Zhang, Bopeng & Tang, Jinfeng & Yan, Jia & Su, Minhua & Yang, Zhiquan, 2019. "Nitrogen-doped biochar derived from watermelon rind as oxygen reduction catalyst in air cathode microbial fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 516-525.
    13. Pan, Suyang & Ma, Jiliang & Chen, Xiaoping & Liu, Daoyin & Liang, Cai, 2023. "NH3/O2 premixed combustion in a single bubble of fluidized bed," Applied Energy, Elsevier, vol. 349(C).
    14. Najjaran, Ahmad & Freeman, James & Ramos, Alba & Markides, Christos N., 2019. "Experimental investigation of an ammonia-water-hydrogen diffusion absorption refrigerator," Applied Energy, Elsevier, vol. 256(C).
    15. Ryu, Kyunghyun & Zacharakis-Jutz, George E. & Kong, Song-Charng, 2014. "Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine," Applied Energy, Elsevier, vol. 116(C), pages 206-215.
    16. Issayev, Gani & Giri, Binod Raj & Elbaz, Ayman M. & Shrestha, Krishna P. & Mauss, Fabian & Roberts, William L. & Farooq, Aamir, 2022. "Ignition delay time and laminar flame speed measurements of ammonia blended with dimethyl ether: A promising low carbon fuel blend," Renewable Energy, Elsevier, vol. 181(C), pages 1353-1370.
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