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Torrefaction of wood and bark from Eucalyptus globulus and Eucalyptus nitens: Focus on volatile evolution vs feasible temperatures

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  • Arteaga-Pérez, Luis E.
  • Segura, Cristina
  • Bustamante-García, Verónica
  • Gómez Cápiro, Oscar
  • Jiménez, Romel

Abstract

Torrefaction is a thermal pretreatment leading to the improvement of most of the fuel properties of biomass, namely energy density, HHV (higher heating value), grindability and hydrophobicity. The aim of this study is to identify the most feasible temperature to carry out torrefaction of Eucalyptus globulus and nitens, based on chemical evidences associated to the release of volatiles during thermal treatment of biomass. With that end: (i) Devolatilization kinetics, (ii) Effects of temperature and residence time and (iii) volatiles composition during torrefaction of both wood and bark were analyzed. In all cases DTG (derivative thermogravimetric curves) exhibited the typical shape of lignocellulosic materials, with three decomposition phases and two reaction zones. Values of activation energies for hemicellulose decomposition, were in agreement with those reported in the literature (121–170 kJ/mol). Carboxylic acids, water and phenolic compounds showed two peaks, which were associated to torrefaction (below 310 °C) and pyrolysis (310–410 °C) respectively. The most feasible temperatures for torrefaction were estimated as a function of these peaks, and it ranged between 295 °C and 310 °C for all samples. Main volatile species at the torrefaction peaks were distributed as Water > Acetic Acid > CO2 > Others, while Levoglucosan formation was marginal, due to the catalytic effect of inorganics.

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  • Arteaga-Pérez, Luis E. & Segura, Cristina & Bustamante-García, Verónica & Gómez Cápiro, Oscar & Jiménez, Romel, 2015. "Torrefaction of wood and bark from Eucalyptus globulus and Eucalyptus nitens: Focus on volatile evolution vs feasible temperatures," Energy, Elsevier, vol. 93(P2), pages 1731-1741.
    • Handle: RePEc:eee:energy:v:93:y:2015:i:p2:p:1731-1741
    DOI: 10.1016/j.energy.2015.10.007
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    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    3. Sermyagina, Ekaterina & Saari, Jussi & Zakeri, Behnam & Kaikko, Juha & Vakkilainen, Esa, 2015. "Effect of heat integration method and torrefaction temperature on the performance of an integrated CHP-torrefaction plant," Applied Energy, Elsevier, vol. 149(C), pages 24-34.
    4. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2006. "More efficient biomass gasification via torrefaction," Energy, Elsevier, vol. 31(15), pages 3458-3470.
    5. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Gasification of lignocellulosic biomass char obtained from pyrolysis: Kinetic and evolved gas analyses," Energy, Elsevier, vol. 71(C), pages 456-467.
    6. Nocquet, Timothée & Dupont, Capucine & Commandre, Jean-Michel & Grateau, Maguelone & Thiery, Sébastien & Salvador, Sylvain, 2014. "Volatile species release during torrefaction of wood and its macromolecular constituents: Part 1 – Experimental study," Energy, Elsevier, vol. 72(C), pages 180-187.
    7. Nocquet, Timothée & Dupont, Capucine & Commandre, Jean-Michel & Grateau, Maguelone & Thiery, Sébastien & Salvador, Sylvain, 2014. "Volatile species release during torrefaction of biomass and its macromolecular constituents: Part 2 – Modeling study," Energy, Elsevier, vol. 72(C), pages 188-194.
    8. Chen, Wei-Hsin & Liu, Shih-Hsien & Juang, Tarng-Tzuen & Tsai, Chi-Ming & Zhuang, Yi-Qing, 2015. "Characterization of solid and liquid products from bamboo torrefaction," Applied Energy, Elsevier, vol. 160(C), pages 829-835.
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    7. Wang, L. & Barta-Rajnai, E. & Skreiberg, Ø. & Khalil, R. & Czégény, Z. & Jakab, E. & Barta, Z. & Grønli, M., 2018. "Effect of torrefaction on physiochemical characteristics and grindability of stem wood, stump and bark," Applied Energy, Elsevier, vol. 227(C), pages 137-148.
    8. Chen, Congjin & Zhu, Jingxian & Jia, Shuang & Mi, Shuai & Tong, Zhangfa & Li, Zhixia & Li, Mingfei & Zhang, Yanjuan & Hu, Yuhua & Huang, Zuqiang, 2018. "Effect of ethanol on Mulberry bark hydrothermal liquefaction and bio-oil chemical compositions," Energy, Elsevier, vol. 162(C), pages 460-475.
    9. Isabel Malico & Ana Cristina Gonçalves, 2021. "Eucalyptus globulus Coppices in Portugal: Influence of Site and Percentage of Residues Collected for Energy," Sustainability, MDPI, vol. 13(11), pages 1-14, May.
    10. Arteaga-Pérez, Luis E. & Gómez Cápiro, Oscar & Romero, Romina & Delgado, Aaron & Olivera, Patricia & Ronsse, Frederik & Jiménez, Romel, 2017. "In situ catalytic fast pyrolysis of crude and torrefied Eucalyptus globulus using carbon aerogel-supported catalysts," Energy, Elsevier, vol. 128(C), pages 701-712.
    11. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    12. Umut Şen & Bruno Esteves & Helena Pereira, 2023. "Pyrolysis and Extraction of Bark in a Biorefineries Context: A Critical Review," Energies, MDPI, vol. 16(13), pages 1-23, June.
    13. Ignacio, Luís Henrique da Silva & Santos, Pedro Eduardo de Almeida & Duarte, Carlos Antonio Ribeiro, 2019. "An experimental assessment of Eucalyptus urosemente energy potential for biomass production in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 103(C), pages 361-369.
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    15. Moya, Roger & Rodríguez-Zúñiga, Ana & Puente-Urbina, Allen & Gaitán-Álvarez, Johanna, 2018. "Study of light, middle and severe torrefaction and effects of extractives and chemical compositions on torrefaction process by thermogravimetric analysis in five fast-growing plantations of Costa Rica," Energy, Elsevier, vol. 149(C), pages 1-10.

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