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MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction

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  • Raoof, Jahan-Bakhsh
  • Hosseini, Sayed Reza
  • Ojani, Reza
  • Mandegarzad, Sakineh

Abstract

In this work, metal-organic framework Cu3(BTC)2 [BTC = 1,3,5-benzenetricarboxylate] (commonly known as MOF-199 or HKUST-1), is used as porous template for preparation of a Cu/nanoporous carbon composite. The MOF-derived Cu/nanoporous carbon composite (Cu/NPC composite) is synthesized by direct carbonization of the MOF-199 without any carbon precursor additive. The physical characterization of the solid catalyst is achieved by using a variety of different techniques, including XRD (X-ray powder diffraction), scanning electron microscopy, thermo-gravimetric analysis, and nitrogen physisorption measurements. The electrochemical results have shown that the Cu/NPC composite modified glassy carbon electrode (Cu/NPC/GCE) as a non-platinum electrocatalyst exhibited favorable catalytic activity for hydrogen evolution reaction, in spite of high resistance to faradic process. This behavior can be attributed to existence of Cu metal confirmed by XRD and/or high effective pore surface area (1025 m2 g−1) in the Cu/NPC composite. The electron transfer coefficient and exchange current density for the Cu/NPC/GCE is calculated by Tafel plot at about 0.34 and 1.2 × 10−3 mAcm−2, respectively.

Suggested Citation

  • Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:1075-1081
    DOI: 10.1016/j.energy.2015.08.013
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    2. Ensafi, Ali A. & Nabiyan, Afshin & Jafari-Asl, Mehdi & Dinari, Mohammad & Farrokhpour, Hossein & Rezaei, B., 2016. "Galvanic exchange at layered doubled hydroxide/N-doped graphene as an in-situ method to fabricate powerful electrocatalysts for hydrogen evolution reaction," Energy, Elsevier, vol. 116(P1), pages 1087-1096.
    3. Monama, Gobeng R. & Mdluli, Siyabonga B. & Mashao, Gloria & Makhafola, Mogwasha D. & Ramohlola, Kabelo E. & Molapo, Kerileng M. & Hato, Mpitloane J. & Makgopa, Katlego & Iwuoha, Emmanuel I. & Modibane, 2018. "Palladium deposition on copper(II) phthalocyanine/metal organic framework composite and electrocatalytic activity of the modified electrode towards the hydrogen evolution reaction," Renewable Energy, Elsevier, vol. 119(C), pages 62-72.
    4. Ensafi, Ali A. & Jafari-Asl, Mehdi & Nabiyan, Afshin & Rezaei, B., 2016. "Ni3S2/ball-milled silicon flour as a bi-functional electrocatalyst for hydrogen and oxygen evolution reactions," Energy, Elsevier, vol. 116(P1), pages 392-401.

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