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Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment

Author

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  • Mohammadreza Beydaghdari

    (Department of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, Ardabil 56199-11367, Iran)

  • Fahimeh Hooriabad Saboor

    (Department of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, Ardabil 56199-11367, Iran)

  • Aziz Babapoor

    (Department of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, Ardabil 56199-11367, Iran)

  • Vikram V. Karve

    (Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1951 Sion, Switzerland)

  • Mehrdad Asgari

    (Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1951 Sion, Switzerland
    Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, UK)

Abstract

The adsorptive removal of dyes from industrial wastewater using commercially available adsorbents is not significantly efficient. Metal–organic frameworks (MOFs) offer outstanding properties which can boost the separation performance over current commercial adsorbents and hence, these materials represent a milestone in improving treatment methods for dye removal from water. Accordingly, in this paper, the recent studies in the modification of MOF structures in dye removal from the aquatic environment have been discussed. This study aims to elaborate on the synthetic strategies applied to improve the adsorption efficiency and to discuss the major adsorption mechanisms as well as the most influential parameters in the adsorptive removal of dyes using MOFs. More particularly, the advanced separation performance of MOF-based adsorbents will be comprehensively explained. The introduction of various functional groups and nanomaterials, such as amine functional groups, magnetic nanoparticles, and carbon-based materials such as graphene oxide and CNT, onto the MOFs can alter the removal efficiency of MOF-based adsorbents through enhancing the water stability, dispersion in water, interactions between the MOF structure and the contaminant, and the adsorption capacity. Finally, we summarize the challenges experienced by MOF-based materials for dye removal from water and propose future research outlooks to be considered.

Suggested Citation

  • Mohammadreza Beydaghdari & Fahimeh Hooriabad Saboor & Aziz Babapoor & Vikram V. Karve & Mehrdad Asgari, 2022. "Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment," Energies, MDPI, vol. 15(6), pages 1-34, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:6:p:2023-:d:768261
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    References listed on IDEAS

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    1. Omar M. Yaghi & Michael O'Keeffe & Nathan W. Ockwig & Hee K. Chae & Mohamed Eddaoudi & Jaheon Kim, 2003. "Reticular synthesis and the design of new materials," Nature, Nature, vol. 423(6941), pages 705-714, June.
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    Cited by:

    1. Tushar Kanti Sen, 2023. "Application of Synthesized Biomass Bamboo Charcoal–Iron Oxide “BC/Fe” Nanocomposite Adsorbents in the Removal of Cationic Methylene Blue Dye Contaminants from Wastewater by Adsorption," Sustainability, MDPI, vol. 15(11), pages 1-18, May.

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