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Evaluation of an integrated methane autothermal reforming and high-temperature proton exchange membrane fuel cell system

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  • Authayanun, Suthida
  • Saebea, Dang
  • Patcharavorachot, Yaneeporn
  • Arpornwichanop, Amornchai

Abstract

The aim of this study was to investigate the performance and efficiency of an integrated autothermal reforming and HT-PEMFC (high-temperature proton exchange membrane fuel cell) system fueled by methane. Effect of the inclusion of a CO (carbon monoxide) removal process on the integrated HT-PEMFC system was considered. An increase in the S/C (steam-to-carbon) ratio and the reformer temperature can enhance the hydrogen fraction while the CO formation reduces with increasing S/C ratio. The fuel processor efficiency of the methane autothermal reformer with a WGS (water gas shift reactor) reactor, as the CO removal process, is higher than that without a WGS reactor. A higher fuel processor efficiency can be obtained when the feed of the autothermal reformer is preheated to the reformer temperature. Regarding the cell performance, the reformate gas from the methane reformer operated at Tin = TR and with a high S/C ratio is suitable for the HT-PEMFC system without a WGS reactor. When considering the HT-PEMFC system with a WGS reactor, the CO poisoning has less significant impact on the cell performance and the system can be operated over a broader range to minimize the required total active area. A WGS reactor is necessary for the methane autothermal reforming and HT-PEMFC integrated system with regard to the system efficiency.

Suggested Citation

  • Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2015. "Evaluation of an integrated methane autothermal reforming and high-temperature proton exchange membrane fuel cell system," Energy, Elsevier, vol. 80(C), pages 331-339.
    • Handle: RePEc:eee:energy:v:80:y:2015:i:c:p:331-339
    DOI: 10.1016/j.energy.2014.11.075
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    1. Ipsakis, Dimitris & Ouzounidou, Martha & Papadopoulou, Simira & Seferlis, Panos & Voutetakis, Spyros, 2017. "Dynamic modeling and control analysis of a methanol autothermal reforming and PEM fuel cell power system," Applied Energy, Elsevier, vol. 208(C), pages 703-718.
    2. Mohamed, Ziyaad & Dasireddy, Venkata D.B.C. & Singh, Sooboo & Friedrich, Holger B., 2020. "Comparative studies for CO oxidation and hydrogenation over supported Pt catalysts prepared by different synthesis methods," Renewable Energy, Elsevier, vol. 148(C), pages 1041-1053.
    3. Guo, Xinru & Zhang, Houcheng, 2020. "Performance analyses of a combined system consisting of high-temperature polymer electrolyte membrane fuel cells and thermally regenerative electrochemical cycles," Energy, Elsevier, vol. 193(C).
    4. Cho, Mingyu & Kim, Yongtae & Ho Song, Han, 2022. "Solid oxide fuel cell–internal combustion engine hybrid system utilizing an internal combustion engine for anode off-gas recirculation, external reforming, and additional power generation," Applied Energy, Elsevier, vol. 328(C).
    5. Zhang, Caizhi & Liu, Zhitao & Zhou, Weijiang & Chan, Siew Hwa & Wang, Youyi, 2015. "Dynamic performance of a high-temperature PEM fuel cell – An experimental study," Energy, Elsevier, vol. 90(P2), pages 1949-1955.
    6. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.

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