IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v78y2014icp421-425.html
   My bibliography  Save this article

Combination of preferential CO oxidation and methanation in hybrid MCR (micro-channel reactor) for CO clean-up

Author

Listed:
  • Lee, Chun-Boo
  • Cho, Sung-Ho
  • Lee, Dong-Wook
  • Hwang, Kyung-Ran
  • Park, Jong-Soo
  • Kim, Sung-Hyun

Abstract

CO in the hydrogen stream must be reduced to extremely low levels, under 10 ppm, because the Pt electrode is detrimentally affected by residual CO in the H2 stream. Therefore removal of carbon monoxide from the H2-rich stream during fuel generation from hydrocarbons is a critical challenge, especially for PEMFC (proton exchange membrane fuel cell) applications. Herein, CO an initial concentration of 1.0 vol.% was successfully removed from a H2-rich stream to a residual level below 10 ppm, within the wide operating temperature range from 92 to 235 °C by utilizing a hybrid channel reactor comprising a micro-channel heat exchanger and mini-packed bed reactor. The mini-packed bed reactor contained two kinds of catalysts that promote preferential oxidation and methanation of CO in series. The HMCR (hybrid micro- and mini- channel reactor) offers not only ultimately safe operation but also easy scale-up and is adaptable to mass production of CO clean-up units.

Suggested Citation

  • Lee, Chun-Boo & Cho, Sung-Ho & Lee, Dong-Wook & Hwang, Kyung-Ran & Park, Jong-Soo & Kim, Sung-Hyun, 2014. "Combination of preferential CO oxidation and methanation in hybrid MCR (micro-channel reactor) for CO clean-up," Energy, Elsevier, vol. 78(C), pages 421-425.
  • Handle: RePEc:eee:energy:v:78:y:2014:i:c:p:421-425
    DOI: 10.1016/j.energy.2014.10.029
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214011785
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2014.10.029?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Salemme, Lucia & Menna, Laura & Simeone, Marino, 2013. "Calculation of the energy efficiency of fuel processor – PEM (proton exchange membrane) fuel cell systems from fuel elementar composition and heating value," Energy, Elsevier, vol. 57(C), pages 368-374.
    2. Ouzounidou, Martha & Ipsakis, Dimitris & Voutetakis, Spyros & Papadopoulou, Simira & Seferlis, Panos, 2009. "A combined methanol autothermal steam reforming and PEM fuel cell pilot plant unit: Experimental and simulation studies," Energy, Elsevier, vol. 34(10), pages 1733-1743.
    3. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Hwang, Kyung-Ran & Park, Jin-Woo & Lee, Sung-Wook & Hong, Sungkook & Lee, Chun-Boo & Oh, Duck-Kyu & Jin, Min-Ho & Lee, Dong-Wook & Park, Jong-Soo, 2015. "Catalytic combustion of the retentate gas from a CO2/H2 separation membrane reactor for further CO2 enrichment and energy recovery," Energy, Elsevier, vol. 90(P1), pages 1192-1198.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.
    2. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2015. "Evaluation of an integrated methane autothermal reforming and high-temperature proton exchange membrane fuel cell system," Energy, Elsevier, vol. 80(C), pages 331-339.
    3. Lesmana, Donny & Wu, Ho-Shing, 2014. "Modified oxalic acid co-precipitation method for preparing Cu/ZnO/Al2O3/Cr2O3/CeO2 catalysts for the OR (oxidative reforming) of M (methanol) to produce H2 (hydrogen) gas," Energy, Elsevier, vol. 69(C), pages 769-777.
    4. Abdin, Z. & Webb, C.J. & Gray, E.MacA., 2016. "PEM fuel cell model and simulation in Matlab–Simulink based on physical parameters," Energy, Elsevier, vol. 116(P1), pages 1131-1144.
    5. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    6. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    7. Asadollahi, Arash & Esmaeeli, Asghar, 2018. "Simulation of condensation and liquid break-up on a micro-object with upper and lower movable walls using Lattice Boltzmann Method," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 498(C), pages 33-49.
    8. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    9. Salva, J. Antonio & Iranzo, Alfredo & Rosa, Felipe & Tapia, Elvira, 2016. "Validation of cell voltage and water content in a PEM (polymer electrolyte membrane) fuel cell model using neutron imaging for different operating conditions," Energy, Elsevier, vol. 101(C), pages 100-112.
    10. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    11. Dobersek, Danijela & Goricanec, Darko, 2014. "An experimentally evaluated magnetic device's efficiency for water-scale reduction on electric heaters," Energy, Elsevier, vol. 77(C), pages 271-278.
    12. Jung, Chi-Young & Yi, Jae-You & Yi, Sung-Chul, 2014. "On the role of the silica-containing catalyst layer for proton exchange membrane fuel cells," Energy, Elsevier, vol. 68(C), pages 794-800.
    13. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.
    14. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    15. Yuan, Zhenyu & Zhang, Yufeng & Fu, Wenting & Li, Zipeng & Liu, Xiaowei, 2013. "Investigation of a small-volume direct methanol fuel cell stack for portable applications," Energy, Elsevier, vol. 51(C), pages 462-467.
    16. Xing, Lei & Du, Shangfeng & Chen, Rui & Mamlouk, Mohamed & Scott, Keith, 2016. "Anode partial flooding modelling of proton exchange membrane fuel cells: Model development and validation," Energy, Elsevier, vol. 96(C), pages 80-95.
    17. Xu, Liangfei & Fang, Chuan & Hu, Junming & Cheng, Siliang & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2017. "Parameter extraction of polymer electrolyte membrane fuel cell based on quasi-dynamic model and periphery signals," Energy, Elsevier, vol. 122(C), pages 675-690.
    18. Zhang, Lu & Liu, Jie & Du, Shaojie & Zhao, Chen, 2024. "Multiphase flow dynamics in metal foam proton exchange membrane fuel cell," Renewable Energy, Elsevier, vol. 226(C).
    19. Perng, Shiang-Wuu & Wu, Horng-Wen & Shih, Gin-Jang, 2015. "Effect of prominent gas diffusion layer (GDL) on non-isothermal transport characteristics and cell performance of a proton exchange membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 88(C), pages 126-138.
    20. Salemme, Lucia & Menna, Laura & Simeone, Marino, 2013. "Calculation of the energy efficiency of fuel processor – PEM (proton exchange membrane) fuel cell systems from fuel elementar composition and heating value," Energy, Elsevier, vol. 57(C), pages 368-374.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:78:y:2014:i:c:p:421-425. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.