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Combination of preferential CO oxidation and methanation in hybrid MCR (micro-channel reactor) for CO clean-up

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  • Lee, Chun-Boo
  • Cho, Sung-Ho
  • Lee, Dong-Wook
  • Hwang, Kyung-Ran
  • Park, Jong-Soo
  • Kim, Sung-Hyun

Abstract

CO in the hydrogen stream must be reduced to extremely low levels, under 10 ppm, because the Pt electrode is detrimentally affected by residual CO in the H2 stream. Therefore removal of carbon monoxide from the H2-rich stream during fuel generation from hydrocarbons is a critical challenge, especially for PEMFC (proton exchange membrane fuel cell) applications. Herein, CO an initial concentration of 1.0 vol.% was successfully removed from a H2-rich stream to a residual level below 10 ppm, within the wide operating temperature range from 92 to 235 °C by utilizing a hybrid channel reactor comprising a micro-channel heat exchanger and mini-packed bed reactor. The mini-packed bed reactor contained two kinds of catalysts that promote preferential oxidation and methanation of CO in series. The HMCR (hybrid micro- and mini- channel reactor) offers not only ultimately safe operation but also easy scale-up and is adaptable to mass production of CO clean-up units.

Suggested Citation

  • Lee, Chun-Boo & Cho, Sung-Ho & Lee, Dong-Wook & Hwang, Kyung-Ran & Park, Jong-Soo & Kim, Sung-Hyun, 2014. "Combination of preferential CO oxidation and methanation in hybrid MCR (micro-channel reactor) for CO clean-up," Energy, Elsevier, vol. 78(C), pages 421-425.
    • Handle: RePEc:eee:energy:v:78:y:2014:i:c:p:421-425
    DOI: 10.1016/j.energy.2014.10.029
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    References listed on IDEAS

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    1. Salemme, Lucia & Menna, Laura & Simeone, Marino, 2013. "Calculation of the energy efficiency of fuel processor – PEM (proton exchange membrane) fuel cell systems from fuel elementar composition and heating value," Energy, Elsevier, vol. 57(C), pages 368-374.
    2. Ouzounidou, Martha & Ipsakis, Dimitris & Voutetakis, Spyros & Papadopoulou, Simira & Seferlis, Panos, 2009. "A combined methanol autothermal steam reforming and PEM fuel cell pilot plant unit: Experimental and simulation studies," Energy, Elsevier, vol. 34(10), pages 1733-1743.
    3. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
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    Cited by:

    1. Hwang, Kyung-Ran & Park, Jin-Woo & Lee, Sung-Wook & Hong, Sungkook & Lee, Chun-Boo & Oh, Duck-Kyu & Jin, Min-Ho & Lee, Dong-Wook & Park, Jong-Soo, 2015. "Catalytic combustion of the retentate gas from a CO2/H2 separation membrane reactor for further CO2 enrichment and energy recovery," Energy, Elsevier, vol. 90(P1), pages 1192-1198.

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