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Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells

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  • Kim, Jintae
  • Kim, Minjin
  • Kang, Taegon
  • Sohn, Young-Jun
  • Song, Taewon
  • Choi, Kyoung Hwan

Abstract

High-temperature PEMFCs (proton exchange membrane fuel cells) using PA (phosphoric acid)-doped PBI (polybenzimidazole) membranes have received attention as a potential solution to several of the issues with traditional low-temperature PEMFCs. However, the durability of high-temperature PEMFCs deteriorates rapidly with increasing temperature, although its performance improves. This characteristic makes it difficult to select the proper operating temperature to achieve its target lifetime. In this paper, to resolve this problem, models were developed to predict the performance and durability of the high-temperature PEMFC as a function of operating temperature. The optimal operating temperature was then determined for a variety of lifetimes. Theoretical model to estimate cell performance and empirical model to predict the degradation rate of cell performance were constructed, respectively. The prediction results of the developed models agreed well with the experimental data. From the simulation, we could obtain higher average cell performances by optimizing the operating temperature for the given target lifetime compared to the cell performance at some temperatures determined using an existing rule of thumb. It is expected that the proposed methodologies will lead to the more rapid commercialization of this technology in such applications as stationary and automotive fuel cell systems.

Suggested Citation

  • Kim, Jintae & Kim, Minjin & Kang, Taegon & Sohn, Young-Jun & Song, Taewon & Choi, Kyoung Hwan, 2014. "Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells," Energy, Elsevier, vol. 66(C), pages 41-49.
    • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:41-49
    DOI: 10.1016/j.energy.2013.08.053
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    References listed on IDEAS

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    1. Appleby, A.J., 1996. "Fuel cell technology: Status and future prospects," Energy, Elsevier, vol. 21(7), pages 521-653.
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    1. Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    2. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    3. Najafi, Behzad & Haghighat Mamaghani, Alireza & Rinaldi, Fabio & Casalegno, Andrea, 2015. "Long-term performance analysis of an HT-PEM fuel cell based micro-CHP system: Operational strategies," Applied Energy, Elsevier, vol. 147(C), pages 582-592.
    4. Ryu, Sung Kwan & Vinothkannan, Mohanraj & Kim, Ae Rhan & Yoo, Dong Jin, 2022. "Effect of type and stoichiometry of fuels on performance of polybenzimidazole-based proton exchange membrane fuel cells operating at the temperature range of 120–160 °C," Energy, Elsevier, vol. 238(PB).
    5. Roshandel, Ramin & Parhizkar, Tarannom, 2016. "Degradation based optimization framework for long term applications of energy systems, case study: Solid oxide fuel cell stacks," Energy, Elsevier, vol. 107(C), pages 172-181.
    6. Richard Symes & Tchable-Nan Djaname & Michael Deligant & Emilie Sauret, 2021. "Design and Optimization of a Radial Inflow Turbine for Use with a Low Temperature ORC," Energies, MDPI, vol. 14(24), pages 1-16, December.
    7. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    8. Kun He & Dongchen Qin & Jiangyi Chen & Tingting Wang & Hongxia Wu & Peizhuo Wang, 2023. "Adaptive Equivalent Consumption Minimization Strategy for Fuel Cell Buses Based on Driving Style Recognition," Sustainability, MDPI, vol. 15(10), pages 1-17, May.
    9. Víctor Sanz i López & Ramon Costa-Castelló & Carles Batlle, 2022. "Literature Review of Energy Management in Combined Heat and Power Systems Based on High-Temperature Proton Exchange Membrane Fuel Cells for Residential Comfort Applications," Energies, MDPI, vol. 15(17), pages 1-22, September.
    10. Guan, Dong & Pan, Biyu & Chen, Zhen & Li, Jing & Shen, Hui & Pang, Huan, 2023. "Quantitative modeling and bio-inspired optimization the clamping load on the bipolar plate in PEMFC," Energy, Elsevier, vol. 263(PD).
    11. Zhang, Caizhi & Liu, Zhitao & Zhang, Xiongwen & Chan, Siew Hwa & Wang, Youyi, 2016. "Dynamic performance of a high-temperature PEM (proton exchange membrane) fuel cell – Modelling and fuzzy control of purging process," Energy, Elsevier, vol. 95(C), pages 425-432.
    12. Mingzhang Pan & Chengjie Pan & Jinyang Liao & Chao Li & Rong Huang & Qiwei Wang, 2021. "Assessment of Sensitivity to Evaluate the Impact of Operating Parameters on Stability and Performance in Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 14(14), pages 1-23, July.
    13. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    14. Lee, Won-Yong & Kim, Minjin & Sohn, Young-Jun & Kim, Seung-Gon, 2016. "Power optimization of a combined power system consisting of a high-temperature polymer electrolyte fuel cell and an organic Rankine cycle system," Energy, Elsevier, vol. 113(C), pages 1062-1070.
    15. Alizadeh, E. & Ghadimi, M. & Barzegari, M.M. & Momenifar, M. & Saadat, S.H.M., 2017. "Development of contact pressure distribution of PEM fuel cell's MEA using novel clamping mechanism," Energy, Elsevier, vol. 131(C), pages 92-97.
    16. Lee, Won-Yong & Kim, Minjin & Sohn, Young-Jun & Kim, Seung-Gon, 2017. "Performance of a hybrid system consisting of a high-temperature polymer electrolyte fuel cell and an absorption refrigerator," Energy, Elsevier, vol. 141(C), pages 2397-2407.
    17. Zhang, S. & Reimer, U. & Beale, S.B. & Lehnert, W. & Stolten, D., 2019. "Modeling polymer electrolyte fuel cells: A high precision analysis," Applied Energy, Elsevier, vol. 233, pages 1094-1103.
    18. Kim, Eunji & Song, Seunghwan & Choi, Seoeun & Park, Jung Ock & Kim, Junghwan & Kwon, Kyungjung, 2021. "Parameter analysis from the modeling of high temperature proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 301(C).
    19. El-Hay, Enas A. & El-Hameed, Mohamed A. & El-Fergany, Attia A., 2018. "Performance enhancement of autonomous system comprising proton exchange membrane fuel cells and switched reluctance motor," Energy, Elsevier, vol. 163(C), pages 699-711.
    20. Sun, Hong & Xie, Chen & Chen, Hao & Almheiri, Saif, 2015. "A numerical study on the effects of temperature and mass transfer in high temperature PEM fuel cells with ab-PBI membrane," Applied Energy, Elsevier, vol. 160(C), pages 937-944.
    21. Chen, Dongfang & Pei, Pucheng & Meng, Yining & Ren, Peng & Li, Yuehua & Wang, Mingkai & Wang, Xizhong, 2022. "Novel extraction method of working condition spectrum for the lifetime prediction and energy management strategy evaluation of automotive fuel cells," Energy, Elsevier, vol. 255(C).
    22. Wu, Horng-Wen & Ho, Tzu-Yi & Han, Yueh-Jung, 2021. "Parametric optimization of wall-mounted cuboid rows installed in interdigitated flow channel of HT-PEM fuel cells," Energy, Elsevier, vol. 216(C).
    23. Andraž Kravos & Ambrož Kregar & Kurt Mayer & Viktor Hacker & Tomaž Katrašnik, 2021. "Identifiability Analysis of Degradation Model Parameters from Transient CO 2 Release in Low-Temperature PEM Fuel Cell under Various AST Protocols," Energies, MDPI, vol. 14(14), pages 1-16, July.
    24. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2015. "Evaluation of an integrated methane autothermal reforming and high-temperature proton exchange membrane fuel cell system," Energy, Elsevier, vol. 80(C), pages 331-339.

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