IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v77y2014icp235-243.html
   My bibliography  Save this article

Industrial applications of supercritical fluids: A review

Author

Listed:
  • Knez, Ž.
  • Markočič, E.
  • Leitgeb, M.
  • Primožič, M.
  • Knez Hrnčič, M.
  • Škerget, M.

Abstract

High pressure technologies involving sub and supercritical fluids offer the possibility to obtain new products with special characteristics or to design new processes, which are environmentally friendly and sustainable. By using high pressure as a processing tool one can also avoid the legal limitations for solvent residues and restrictions on use of conventional solvents in chemical processes. Supercritical fluids are already applied in several processes developed to commercial scale in pharmaceutical, food and textile industries. Extraction of valuable compounds from plant materials and their “in situ” formulation in products with specific properties is one of the very promising applications of high pressure technology. Particle formation using supercritical fluids may overcome the drawbacks of conventional particle size reduction processes. Because of their unique thermo-dynamic and fluid-dynamic properties, dense gases can also be used for impregnation of solid particles, particle coating, foaming etc. Some biochemical and chemical reactions performed in supercritical fluids have already been implemented at industrial scale to obtain products with high added value, while the use of supercritical fluids as heat carriers is a newly emerging field. In our short overview we present some applications and future expected development in the field of sub and supercritical fluids.

Suggested Citation

  • Knez, Ž. & Markočič, E. & Leitgeb, M. & Primožič, M. & Knez Hrnčič, M. & Škerget, M., 2014. "Industrial applications of supercritical fluids: A review," Energy, Elsevier, vol. 77(C), pages 235-243.
  • Handle: RePEc:eee:energy:v:77:y:2014:i:c:p:235-243
    DOI: 10.1016/j.energy.2014.07.044
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214008664
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2014.07.044?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lim, Steven & Lee, Keat Teong, 2014. "Investigation of impurity tolerance and thermal stability for biodiesel production from Jatropha curcas L. seeds using supercritical reactive extraction," Energy, Elsevier, vol. 68(C), pages 71-79.
    2. Rönnlund, I. & Myréen, L. & Lundqvist, K. & Ahlbeck, J. & Westerlund, T., 2011. "Waste to energy by industrially integrated supercritical water gasification – Effects of alkali salts in residual by-products from the pulp and paper industry," Energy, Elsevier, vol. 36(4), pages 2151-2163.
    3. Xu, Jinliang & Liu, Chao, 2013. "Effect of the critical temperature of organic fluids on supercritical pressure Organic Rankine Cycles," Energy, Elsevier, vol. 63(C), pages 109-122.
    4. Nithyanandam, K. & Pitchumani, R., 2014. "Cost and performance analysis of concentrating solar power systems with integrated latent thermal energy storage," Energy, Elsevier, vol. 64(C), pages 793-810.
    5. Hassan Zaim, E. & Gandjalikhan Nassab, S.A., 2010. "Numerical investigation of laminar forced convection of water upwards in a narrow annulus at supercritical pressure," Energy, Elsevier, vol. 35(10), pages 4172-4177.
    6. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.
    7. Ong, Lu Ki & Effendi, Chintya & Kurniawan, Alfin & Lin, Chun Xiang & Zhao, Xiu Song & Ismadji, Suryadi, 2013. "Optimization of catalyst-free production of biodiesel from Ceiba pentandra (kapok) oil with high free fatty acid contents," Energy, Elsevier, vol. 57(C), pages 615-623.
    8. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    9. Gutiérrez Ortiz, F.J. & Serrera, A. & Galera, S. & Ollero, P., 2013. "Experimental study of the supercritical water reforming of glycerol without the addition of a catalyst," Energy, Elsevier, vol. 56(C), pages 193-206.
    10. Rovira, Antonio & Muñoz-Antón, Javier & Montes, María José & Martínez-Val, José María, 2013. "Optimization of Brayton cycles for low-to-moderate grade thermal energy sources," Energy, Elsevier, vol. 55(C), pages 403-416.
    11. Kim, Y.M. & Kim, C.G. & Favrat, D., 2012. "Transcritical or supercritical CO2 cycles using both low- and high-temperature heat sources," Energy, Elsevier, vol. 43(1), pages 402-415.
    12. Markočič, Elena & Kramberger, Boris & van Bennekom, Joost G. & Jan Heeres, Hero & Vos, John & Knez, Željko, 2013. "Glycerol reforming in supercritical water; a short review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 40-48.
    13. Larsen, Ulrik & Pierobon, Leonardo & Haglind, Fredrik & Gabrielii, Cecilia, 2013. "Design and optimisation of organic Rankine cycles for waste heat recovery in marine applications using the principles of natural selection," Energy, Elsevier, vol. 55(C), pages 803-812.
    14. Zhang, Fengming & Xu, Chunyan & Zhang, Yong & Chen, Shouyan & Chen, Guifang & Ma, Chunyuan, 2014. "Experimental study on the operating characteristics of an inner preheating transpiring wall reactor for supercritical water oxidation: Temperature profiles and product properties," Energy, Elsevier, vol. 66(C), pages 577-587.
    15. Astolfi, Marco & Romano, Matteo C. & Bombarda, Paola & Macchi, Ennio, 2014. "Binary ORC (organic Rankine cycles) power plants for the exploitation of medium–low temperature geothermal sources – Part A: Thermodynamic optimization," Energy, Elsevier, vol. 66(C), pages 423-434.
    16. Ho, Clifford K. & Iverson, Brian D., 2014. "Review of high-temperature central receiver designs for concentrating solar power," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 835-846.
    17. Singh, Rajinesh & Kearney, Michael P. & Manzie, Chris, 2013. "Extremum-seeking control of a supercritical carbon-dioxide closed Brayton cycle in a direct-heated solar thermal power plant," Energy, Elsevier, vol. 60(C), pages 380-387.
    18. Astolfi, Marco & Romano, Matteo C. & Bombarda, Paola & Macchi, Ennio, 2014. "Binary ORC (Organic Rankine Cycles) power plants for the exploitation of medium–low temperature geothermal sources – Part B: Techno-economic optimization," Energy, Elsevier, vol. 66(C), pages 435-446.
    19. Russo, D. & Dassisti, M. & Lawlor, V. & Olabi, A.G., 2012. "State of the art of biofuels from pure plant oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 4056-4070.
    20. Tan, Kok Tat & Lee, Keat Teong, 2011. "A review on supercritical fluids (SCF) technology in sustainable biodiesel production: Potential and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2452-2456, June.
    21. Singh, Rajinesh & Miller, Sarah A. & Rowlands, Andrew S. & Jacobs, Peter A., 2013. "Dynamic characteristics of a direct-heated supercritical carbon-dioxide Brayton cycle in a solar thermal power plant," Energy, Elsevier, vol. 50(C), pages 194-204.
    22. Guo, Y. & Wang, S.Z. & Xu, D.H. & Gong, Y.M. & Ma, H.H. & Tang, X.Y., 2010. "Review of catalytic supercritical water gasification for hydrogen production from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 334-343, January.
    23. Steffen, Michael & Löffler, Michael & Schaber, Karlheinz, 2013. "Efficiency of a new Triangle Cycle with flash evaporation in a piston engine," Energy, Elsevier, vol. 57(C), pages 295-307.
    24. Le, Van Long & Feidt, Michel & Kheiri, Abdelhamid & Pelloux-Prayer, Sandrine, 2014. "Performance optimization of low-temperature power generation by supercritical ORCs (organic Rankine cycles) using low GWP (global warming potential) working fluids," Energy, Elsevier, vol. 67(C), pages 513-526.
    25. Ma, Yitai & Liu, Zhongyan & Tian, Hua, 2013. "A review of transcritical carbon dioxide heat pump and refrigeration cycles," Energy, Elsevier, vol. 55(C), pages 156-172.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xu, Jialing & Rong, Siqi & Sun, Jingli & Peng, Zhiyong & Jin, Hui & Guo, Liejin & Zhang, Xiang & Zhou, Teng, 2022. "Optimal design of non-isothermal supercritical water gasification reactor: From biomass to hydrogen," Energy, Elsevier, vol. 244(PB).
    2. Zhang, Xiaogang & Ranjith, P.G. & Ranathunga, A.S., 2019. "Sub- and super-critical carbon dioxide flow variations in large high-rank coal specimen: An experimental study," Energy, Elsevier, vol. 181(C), pages 148-161.
    3. Liu, Fang-Jing & Gasem, Khaled A.M. & Tang, Mingchen & Xu, Bang & Huang, Zaixing & Zhang, Riguang & Fan, Maohong, 2020. "Enhanced liquid tar production as fuels/chemicals from Powder River Basin coal through CaO catalyzed stepwise degradation in eco-friendly supercritical CO2/ethanol," Energy, Elsevier, vol. 191(C).
    4. Liu, Fang-Jing & Liu, Guang-Hui & Gasem, Khaled A.M. & Xu, Bang & Goroncy, Alexander & Tang, Ming-Chen & Huang, Zai-Xing & Fan, Maohong & Wei, Xian-Yong, 2020. "Green and efficient two-step degradation approach for converting Powder River Basin coal into fuels/chemicals and insights into their chemical compositions," Applied Energy, Elsevier, vol. 264(C).
    5. Löffler, Michael, 2017. "Batch Processes in Heat Engines," Energy, Elsevier, vol. 125(C), pages 788-794.
    6. Yee Ho Chai & Suzana Yusup & Wan Nadiah Amalina Kadir & Chung Yiin Wong & Siti Suhailah Rosli & Muhammad Syafiq Hazwan Ruslan & Bridgid Lai Fui Chin & Chung Loong Yiin, 2020. "Valorization of Tropical Biomass Waste by Supercritical Fluid Extraction Technology," Sustainability, MDPI, vol. 13(1), pages 1-24, December.
    7. Hämäläinen, Henri & Ruusunen, Mika, 2022. "Identification of a supercritical fluid extraction process for modelling the energy consumption," Energy, Elsevier, vol. 252(C).
    8. Sarkar, Jahar, 2015. "Review and future trends of supercritical CO2 Rankine cycle for low-grade heat conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 434-451.
    9. Torrentes-Espinoza, G. & Miranda, B.C. & Vega-Baudrit, J. & Mata-Segreda, Julio F., 2017. "Castor oil (Ricinus communis) supercritical methanolysis," Energy, Elsevier, vol. 140(P1), pages 426-435.
    10. Kravanja, Gregor & Zajc, Gašper & Knez, Željko & Škerget, Mojca & Marčič, Simon & Knez, Maša H., 2018. "Heat transfer performance of CO2, ethane and their azeotropic mixture under supercritical conditions," Energy, Elsevier, vol. 152(C), pages 190-201.
    11. Samuel Santos & Jaime Puna & João Gomes, 2022. "A Brief Review of the Supercritical Antisolvent (SAS) Technique for the Preparation of Nanocatalysts to Be Used in Biodiesel Production," Energies, MDPI, vol. 15(24), pages 1-7, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    2. Rovira, Antonio & Muñoz, Marta & Sánchez, Consuelo & Martínez-Val, José María, 2015. "Proposal and study of a balanced hybrid Rankine–Brayton cycle for low-to-moderate temperature solar power plants," Energy, Elsevier, vol. 89(C), pages 305-317.
    3. Cavazzini, G. & Bari, S. & Pavesi, G. & Ardizzon, G., 2017. "A multi-fluid PSO-based algorithm for the search of the best performance of sub-critical Organic Rankine Cycles," Energy, Elsevier, vol. 129(C), pages 42-58.
    4. Amini, Ali & Mirkhani, Nima & Pakjesm Pourfard, Pedram & Ashjaee, Mehdi & Khodkar, Mohammad Amin, 2015. "Thermo-economic optimization of low-grade waste heat recovery in Yazd combined-cycle power plant (Iran) by a CO2 transcritical Rankine cycle," Energy, Elsevier, vol. 86(C), pages 74-84.
    5. Li, Chengyu & Wang, Huaixin, 2016. "Power cycles for waste heat recovery from medium to high temperature flue gas sources – from a view of thermodynamic optimization," Applied Energy, Elsevier, vol. 180(C), pages 707-721.
    6. Sarkar, Jahar, 2015. "Review and future trends of supercritical CO2 Rankine cycle for low-grade heat conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 434-451.
    7. Lin, Junhao & Sun, Shichang & Cui, Chongwei & Ma, Rui & Fang, Lin & Zhang, Peixin & Quan, Zonggang & Song, Xin & Yan, Jianglong & Luo, Juan, 2019. "Hydrogen-rich bio-gas generation and optimization in relation to heavy metals immobilization during Pd-catalyzed supercritical water gasification of sludge," Energy, Elsevier, vol. 189(C).
    8. S. Mohammad S. Mahmoudi & Ata D. Akbari & Marc A. Rosen, 2016. "Thermoeconomic Analysis and Optimization of a New Combined Supercritical Carbon Dioxide Recompression Brayton/Kalina Cycle," Sustainability, MDPI, vol. 8(10), pages 1-19, October.
    9. Angelo La Seta & Andrea Meroni & Jesper Graa Andreasen & Leonardo Pierobon & Giacomo Persico & Fredrik Haglind, 2016. "Combined Turbine and Cycle Optimization for Organic Rankine Cycle Power Systems—Part B: Application on a Case Study," Energies, MDPI, vol. 9(6), pages 1-17, May.
    10. Al-Sulaiman, Fahad A. & Atif, Maimoon, 2015. "Performance comparison of different supercritical carbon dioxide Brayton cycles integrated with a solar power tower," Energy, Elsevier, vol. 82(C), pages 61-71.
    11. Huang, Dan & Wu, Zan & Sunden, Bengt & Li, Wei, 2016. "A brief review on convection heat transfer of fluids at supercritical pressures in tubes and the recent progress," Applied Energy, Elsevier, vol. 162(C), pages 494-505.
    12. Li, Xiaoya & Shu, Gequn & Tian, Hua & Shi, Lingfeng & Huang, Guangdai & Chen, Tianyu & Liu, Peng, 2017. "Preliminary tests on dynamic characteristics of a CO2 transcritical power cycle using an expansion valve in engine waste heat recovery," Energy, Elsevier, vol. 140(P1), pages 696-707.
    13. Long, R. & Bao, Y.J. & Huang, X.M. & Liu, W., 2014. "Exergy analysis and working fluid selection of organic Rankine cycle for low grade waste heat recovery," Energy, Elsevier, vol. 73(C), pages 475-483.
    14. Moloney, Francesca & Almatrafi, Eydhah & Goswami, D.Y., 2020. "Working fluid parametric analysis for recuperative supercritical organic Rankine cycles for medium geothermal reservoir temperatures," Renewable Energy, Elsevier, vol. 147(P3), pages 2874-2881.
    15. de M. Ventura, Carlos A. & Rowlands, Andrew S., 2015. "Recuperated power cycle analysis model: Investigation and optimisation of low-to-moderate resource temperature Organic Rankine Cycles," Energy, Elsevier, vol. 93(P1), pages 484-494.
    16. Luu, Minh Tri & Milani, Dia & McNaughton, Robbie & Abbas, Ali, 2017. "Analysis for flexible operation of supercritical CO2 Brayton cycle integrated with solar thermal systems," Energy, Elsevier, vol. 124(C), pages 752-771.
    17. Mondejar, M.E. & Andreasen, J.G. & Pierobon, L. & Larsen, U. & Thern, M. & Haglind, F., 2018. "A review of the use of organic Rankine cycle power systems for maritime applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 126-151.
    18. Meroni, Andrea & Andreasen, Jesper Graa & Persico, Giacomo & Haglind, Fredrik, 2018. "Optimization of organic Rankine cycle power systems considering multistage axial turbine design," Applied Energy, Elsevier, vol. 209(C), pages 339-354.
    19. Linares, José Ignacio & Cantizano, Alexis & Arenas, Eva & Moratilla, Beatriz Yolanda & Martín-Palacios, Víctor & Batet, Lluis, 2017. "Recuperated versus single-recuperator re-compressed supercritical CO2 Brayton power cycles for DEMO fusion reactor based on dual coolant lithium lead blanket," Energy, Elsevier, vol. 140(P1), pages 307-317.
    20. Vivian, Jacopo & Manente, Giovanni & Lazzaretto, Andrea, 2015. "A general framework to select working fluid and configuration of ORCs for low-to-medium temperature heat sources," Applied Energy, Elsevier, vol. 156(C), pages 727-746.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:77:y:2014:i:c:p:235-243. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.