IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v140y2017ip1p426-435.html
   My bibliography  Save this article

Castor oil (Ricinus communis) supercritical methanolysis

Author

Listed:
  • Torrentes-Espinoza, G.
  • Miranda, B.C.
  • Vega-Baudrit, J.
  • Mata-Segreda, Julio F.

Abstract

The catalyst-free transesterification of castor oil under supercritical conditions, using methanol, was studied in this research to determine the molar ratio (methanol:castor oil) and reaction time that produced the biodiesel with the highest conversion by using a 10 L stainless steel batch reactor. The experiments were carried out with 30:1, 40:1, 50:1 and 60:1 molar ratios and reaction times of 5 min, 15 min, 25 min and 35 min under the critical temperature and pressure values according to the molar ratio tested. The reaction conversion was monitored by 1H NMR spectroscopy. The biodiesel was characterized in order to evaluate its accordance to the ASTM D6751 specification and to plot the thermogravimetric and calorimetric profiles of the biodiesel with the highest conversion obtained by TGA and DSC analysis. A regression model was obtained as a reference to calculate the conversion under the studied range of molar ratios and reaction times in future experiments with a coefficient of determination of 95,22% and a standard error of ±1,37% from the observed conversion.

Suggested Citation

  • Torrentes-Espinoza, G. & Miranda, B.C. & Vega-Baudrit, J. & Mata-Segreda, Julio F., 2017. "Castor oil (Ricinus communis) supercritical methanolysis," Energy, Elsevier, vol. 140(P1), pages 426-435.
    • Handle: RePEc:eee:energy:v:140:y:2017:i:p1:p:426-435
    DOI: 10.1016/j.energy.2017.08.122
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217314974
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.08.122?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pramanik, K, 2003. "Properties and use of jatropha curcas oil and diesel fuel blends in compression ignition engine," Renewable Energy, Elsevier, vol. 28(2), pages 239-248.
    2. Knez, Ž. & Markočič, E. & Leitgeb, M. & Primožič, M. & Knez Hrnčič, M. & Škerget, M., 2014. "Industrial applications of supercritical fluids: A review," Energy, Elsevier, vol. 77(C), pages 235-243.
    3. Ramezani, K. & Rowshanzamir, S. & Eikani, M.H., 2010. "Castor oil transesterification reaction: A kinetic study and optimization of parameters," Energy, Elsevier, vol. 35(10), pages 4142-4148.
    4. Román-Figueroa, Celián & Olivares-Carrillo, Pilar & Paneque, Manuel & Palacios-Nereo, Francisco Javier & Quesada-Medina, Joaquín, 2016. "High-yield production of biodiesel by non-catalytic supercritical methanol transesterification of crude castor oil (Ricinus communis)," Energy, Elsevier, vol. 107(C), pages 165-171.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tavseef Mairaj Shah & Anzar Hussain Khan & Cherisa Nicholls & Ihsanullah Sohoo & Ralf Otterpohl, 2023. "Using Landfill Sites and Marginal Lands for Socio-Economically Sustainable Biomass Production through Cultivation of Non-Food Energy Crops: An Analysis Focused on South Asia and Europe," Sustainability, MDPI, vol. 15(6), pages 1-21, March.
    2. Omar Aboelazayem & Mamdouh Gadalla & Basudeb Saha, 2022. "Comprehensive Optimisation of Biodiesel Production Conditions via Supercritical Methanolysis of Waste Cooking Oil," Energies, MDPI, vol. 15(10), pages 1-22, May.
    3. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Valorisation of high acid value waste cooking oil into biodiesel using supercritical methanolysis: Experimental assessment and statistical optimisation on typical Egyptian feedstock," Energy, Elsevier, vol. 162(C), pages 408-420.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    2. Kravanja, Gregor & Zajc, Gašper & Knez, Željko & Škerget, Mojca & Marčič, Simon & Knez, Maša H., 2018. "Heat transfer performance of CO2, ethane and their azeotropic mixture under supercritical conditions," Energy, Elsevier, vol. 152(C), pages 190-201.
    3. Jocelyn Alejandra Cortez-Núñez & María Eugenia Gutiérrez-Castillo & Violeta Y. Mena-Cervantes & Ángel Refugio Terán-Cuevas & Luis Raúl Tovar-Gálvez & Juan Velasco, 2020. "A GIS Approach Land Suitability and Availability Analysis of Jatropha Curcas L. Growth in Mexico as a Potential Source for Biodiesel Production," Energies, MDPI, vol. 13(22), pages 1-23, November.
    4. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    5. Charlotte Stead & Zia Wadud & Chris Nash & Hu Li, 2019. "Introduction of Biodiesel to Rail Transport: Lessons from the Road Sector," Sustainability, MDPI, vol. 11(3), pages 1-20, February.
    6. Rajasekar, E. & Murugesan, A. & Subramanian, R. & Nedunchezhian, N., 2010. "Review of NOx reduction technologies in CI engines fuelled with oxygenated biomass fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(7), pages 2113-2121, September.
    7. Talal Yusaf & Mohd Kamal Kamarulzaman & Abdullah Adam & Sakinah Hisham & Devarajan Ramasamy & Kumaran Kadirgama & Mahendran Samykano & Sivaraos Subramaniam, 2022. "Physical-Chemical Properties Modification of Hermetia Illucens Larvae Oil and Diesel Fuel for the Internal Combustion Engines Application," Energies, MDPI, vol. 15(21), pages 1-17, October.
    8. Ramadhas, A.S. & Jayaraj, S. & Muraleedharan, C., 2005. "Characterization and effect of using rubber seed oil as fuel in the compression ignition engines," Renewable Energy, Elsevier, vol. 30(5), pages 795-803.
    9. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    10. Yaliwal, V.S. & Banapurmath, N.R. & Gireesh, N.M. & Tewari, P.G., 2014. "Production and utilization of renewable and sustainable gaseous fuel for power generation applications: A review of literature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 34(C), pages 608-627.
    11. Tatsidjodoung, Parfait & Dabat, Marie-Hélène & Blin, Joël, 2012. "Insights into biofuel development in Burkina Faso: Potential and strategies for sustainable energy policies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5319-5330.
    12. Singh, S.P. & Singh, Dipti, 2010. "Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 200-216, January.
    13. Mustafa, K.F. & Abdullah, S. & Abdullah, M.Z. & Sopian, K. & Ismail, A.K., 2015. "Experimental investigation of the performance of a liquid fuel-fired porous burner operating on kerosene-vegetable cooking oil (VCO) blends for micro-cogeneration of thermoelectric power," Renewable Energy, Elsevier, vol. 74(C), pages 505-516.
    14. Haldar, S.K. & Ghosh, B.B. & Nag, A., 2009. "Utilization of unattended Putranjiva roxburghii non-edible oil as fuel in diesel engine," Renewable Energy, Elsevier, vol. 34(1), pages 343-347.
    15. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    16. Zhang, Xiaogang & Ranjith, P.G. & Ranathunga, A.S., 2019. "Sub- and super-critical carbon dioxide flow variations in large high-rank coal specimen: An experimental study," Energy, Elsevier, vol. 181(C), pages 148-161.
    17. Pandey, Krishan K. & Pragya, Namita & Sahoo, P.K., 2011. "Life cycle assessment of small-scale high-input Jatropha biodiesel production in India," Applied Energy, Elsevier, vol. 88(12), pages 4831-4839.
    18. Banapurmath, N.R. & Tewari, P.G. & Hosmath, R.S., 2008. "Performance and emission characteristics of a DI compression ignition engine operated on Honge, Jatropha and sesame oil methyl esters," Renewable Energy, Elsevier, vol. 33(9), pages 1982-1988.
    19. Rozina, & Asif, Saira & Ahmad, Mushtaq & Zafar, Muhammad & Ali, Nsir, 2017. "Prospects and potential of fatty acid methyl esters of some non-edible seed oils for use as biodiesel in Pakistan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 687-702.
    20. Arridina Susan Silitonga & Teuku Meurah Indra Mahlia & Abd Halim Shamsuddin & Hwai Chyuan Ong & Jassinnee Milano & Fitranto Kusumo & Abdi Hanra Sebayang & Surya Dharma & Husin Ibrahim & Hazlina Husin , 2019. "Optimization of Cerbera manghas Biodiesel Production Using Artificial Neural Networks Integrated with Ant Colony Optimization," Energies, MDPI, vol. 12(20), pages 1-21, October.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:140:y:2017:i:p1:p:426-435. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.