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Room temperature production of jatropha biodiesel over coconut husk ash

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  • Vadery, Vinu
  • Narayanan, Binitha N.
  • Ramakrishnan, Resmi M.
  • Cherikkallinmel, Sudha Kochiyil
  • Sugunan, Sankaran
  • Narayanan, Divya P.
  • Sasidharan, Sreenikesh

Abstract

A cost effective and efficient method for the preparation of fuel grade biodiesel by the transesterification of jatropha oil at room temperature over a coconut husk derived catalyst under mild reaction conditions without the use of any cosolvent is reported here. Catalyst is prepared by means of controlled heating of coconut husk, without any chemical treatment. The main active component over the catalyst was found to be potassium. When the reaction temperature was increased to 45 °C, the catalyst showed excellent performance on the transesterification of Jatropha oil in a range of methanol/oil molar ratios. The important speciality for the present catalytic systems is the comparatively low reaction temperature requirement for effective reaction. For the optimization of different reaction variables including molar ratio of the reactants, reaction time, the catalyst calcination temperatures and the catalyst/oil weight percentage, a series of transesterification reactions were conducted and the results obtained are presented here.

Suggested Citation

  • Vadery, Vinu & Narayanan, Binitha N. & Ramakrishnan, Resmi M. & Cherikkallinmel, Sudha Kochiyil & Sugunan, Sankaran & Narayanan, Divya P. & Sasidharan, Sreenikesh, 2014. "Room temperature production of jatropha biodiesel over coconut husk ash," Energy, Elsevier, vol. 70(C), pages 588-594.
  • Handle: RePEc:eee:energy:v:70:y:2014:i:c:p:588-594
    DOI: 10.1016/j.energy.2014.04.045
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    10. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    11. Miladinović, Marija R. & Krstić, Jugoslav B. & Zdujić, Miodrag V. & Veselinović, Ljiljana M. & Veljović, Djordje N. & Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2022. "Transesterification of used cooking sunflower oil catalyzed by hazelnut shell ash," Renewable Energy, Elsevier, vol. 183(C), pages 103-113.
    12. Vadery, Vinu & Cherikkallinmel, Sudha Kochiyil & Ramakrishnan, Resmi M. & Sugunan, Sankaran & Narayanan, Binitha N., 2019. "Green production of biodiesel over waste borosilicate glass derived catalyst and the process up-gradation in pilot scale," Renewable Energy, Elsevier, vol. 141(C), pages 1042-1053.
    13. Che Zhao & Hongyuan Chen & Xiao Wu & Rui Shan, 2023. "Exploiting the Waste Biomass of Durian Shell as a Heterogeneous Catalyst for Biodiesel Production at Room Temperature," IJERPH, MDPI, vol. 20(3), pages 1-10, January.
    14. Arumugam, A. & Sankaranarayanan, Pooja, 2020. "Biodiesel production and parameter optimization: An approach to utilize residual ash from sugarcane leaf, a novel heterogeneous catalyst, from Calophyllum inophyllum oil," Renewable Energy, Elsevier, vol. 153(C), pages 1272-1282.
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