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Process simulation and energy optimization of the enzyme-catalyzed biodiesel production

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  • Yun, Huimin
  • Wang, Meng
  • Feng, Wei
  • Tan, Tianwei

Abstract

Biodiesel, as an alternative and renewable fuel, has been studied and developed in recent years. In the present paper, a continuous enzyme-catalyzed biodiesel pilot plant using waste cooking oil, with production capacity of 6482 ton/yr, was simulated by Aspen Plus. Detailed operating conditions and equipment designs were obtained. Five reactions were applied to represent the transesterification of the biodiesel production. The simulation results were in good agreement with the real data. Based on the simulation of the original process, five optimization processes, were proposed focusing on energy saving and methanol recovery. Pinch technology was also used to develop heat exchange networks. Throughout the different optimizations, the quality of biodiesel was still kept at a high purity (>98.5%).

Suggested Citation

  • Yun, Huimin & Wang, Meng & Feng, Wei & Tan, Tianwei, 2013. "Process simulation and energy optimization of the enzyme-catalyzed biodiesel production," Energy, Elsevier, vol. 54(C), pages 84-96.
    • Handle: RePEc:eee:energy:v:54:y:2013:i:c:p:84-96
    DOI: 10.1016/j.energy.2013.01.002
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    5. Mamtani, Kapil & Shahbaz, Kaveh & Farid, Mohammed M., 2021. "Glycerolysis of free fatty acids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    6. Janbarari, Seyed Reza & Ahmadian Behrooz, Hesam, 2020. "Optimal and robust synthesis of the biodiesel production process using waste cooking oil from different feedstocks," Energy, Elsevier, vol. 198(C).
    7. Sun, Dayu & Gao, Lijing & Wei, Ruiping & Pan, Xiaomei & Xiao, Guomin, 2023. "Mechanical vapor recompression coupling organic rankine cycle process for purification of crude biodiesel obtained by solid base-catalyzed transesterification," Energy, Elsevier, vol. 266(C).
    8. Kumar, Ashok & Gudiukaite, Renata & Gricajeva, Alisa & Sadauskas, Mikas & Malunavicius, Vilius & Kamyab, Hesam & Sharma, Swati & Sharma, Tanvi & Pant, Deepak, 2020. "Microbial lipolytic enzymes – promising energy-efficient biocatalysts in bioremediation," Energy, Elsevier, vol. 192(C).
    9. Alvarães, Adan de Oliveira & Prata, Diego Martinez & Santos, Lizandro de Sousa, 2019. "Simulation and optimization of a continuous biodiesel plant using nonlinear programming," Energy, Elsevier, vol. 189(C).
    10. Vadery, Vinu & Narayanan, Binitha N. & Ramakrishnan, Resmi M. & Cherikkallinmel, Sudha Kochiyil & Sugunan, Sankaran & Narayanan, Divya P. & Sasidharan, Sreenikesh, 2014. "Room temperature production of jatropha biodiesel over coconut husk ash," Energy, Elsevier, vol. 70(C), pages 588-594.
    11. Niu, Shengli & Zhou, Yan & Li, Hui & Lu, Chunmei & Liu, Li, 2015. "An investigation on the catalytic capability of the modified white mud after activation in transesterification and kinetic calculation," Energy, Elsevier, vol. 89(C), pages 982-989.
    12. Noraini, M.Y. & Ong, Hwai Chyuan & Badrul, Mohamed Jan & Chong, W.T., 2014. "A review on potential enzymatic reaction for biofuel production from algae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 24-34.
    13. Wang, Kai & Da, Yangyang & Bi, Haoran & Liu, Yanhui & Chen, Biqiang & Wang, Meng & Liu, Zihe & Nielsen, Jens & Tan, Tianwei, 2023. "A one-carbon chemicals conversion strategy to produce precursor of biofuels with Saccharomyces cerevisiae," Renewable Energy, Elsevier, vol. 208(C), pages 331-340.
    14. Liang, Xuezheng, 2013. "Synthesis of biodiesel from waste oil under mild conditions using novel acidic ionic liquid immobilization on poly divinylbenzene," Energy, Elsevier, vol. 63(C), pages 103-108.
    15. Ding, Hui & Ye, Wei & Wang, Yongqiang & Wang, Xianqin & Li, Lujun & Liu, Dan & Gui, Jianzhou & Song, Chunfeng & Ji, Na, 2018. "Process intensification of transesterification for biodiesel production from palm oil: Microwave irradiation on transesterification reaction catalyzed by acidic imidazolium ionic liquids," Energy, Elsevier, vol. 144(C), pages 957-967.
    16. Borges, Karen Araújo & Squissato, André Luiz & Santos, Douglas Queiroz & Neto, Waldomiro Borges & Batista, Antônio Carlos Ferreira & Silva, Tiago Almeida & Vieira, Andressa Tironi & de Oliveira, Marce, 2014. "Homogeneous catalysis of soybean oil transesterification via methylic and ethylic routes: Multivariate comparison," Energy, Elsevier, vol. 67(C), pages 569-574.
    17. Durdu Hakan Utku, 2023. "The Evaluation and Improvement of the Production Processes of an Automotive Industry Company via Simulation and Optimization," Sustainability, MDPI, vol. 15(3), pages 1-17, January.

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