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Cocoa pod husk-plantain peel blend as a novel green heterogeneous catalyst for renewable and sustainable honne oil biodiesel synthesis: A case of biowastes-to-wealth

Author

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  • Olatundun, Esther Adedayo
  • Borokini, Omowumi Oluwatumininu
  • Betiku, Eriola

Abstract

The present study investigated honne oil methyl esters (HOME) production from crude honne seed oil (HSO) using a novel catalyst synthesized from a blend of cocoa pod husk and plantain peel. A two-step esterification-transesterification method was used for the HOME production. For the esterification, the crude HSO was pretreated with H2SO4 to reduce its very high acid value to an acceptable level prior to transesterification to biodiesel. Characterization of the calcined cocoa pod husk-plantain peel ash (CCPA) showed that K (50.95%), Mg (2.49%) and Ca (2.30%) were the major metals present, thereby confirming its heterogeneity. Physisorption isotherms obtained for the CCPA indicate it is composed of nanoparticles that are mesoporous in nature. The initial high acid value of the oil (35.5 g KOH/g oil) was reduced to 1.68 ± 0.57 g KOH/g oil via esterification at a temperature of 65 °C, MeOH:HSO molar ratio of 50:1 and H2SO4 of 2 vol% after 2.5 h. The best operating condition that gave maximum HOME yield (98.98 ± 0.04 wt%) was CCPA amount of 4.5 wt%, reaction temperature of 65 °C, time of 2.5 h and MeOH:pretreated HSO molar ratio of 15:1. The HOME produced satisfied standard limits set for biodiesel.

Suggested Citation

  • Olatundun, Esther Adedayo & Borokini, Omowumi Oluwatumininu & Betiku, Eriola, 2020. "Cocoa pod husk-plantain peel blend as a novel green heterogeneous catalyst for renewable and sustainable honne oil biodiesel synthesis: A case of biowastes-to-wealth," Renewable Energy, Elsevier, vol. 166(C), pages 163-175.
    • Handle: RePEc:eee:renene:v:166:y:2020:i:c:p:163-175
    DOI: 10.1016/j.renene.2020.11.131
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    1. Gohain, Minakshi & Laskar, Khairujjaman & Paul, Atanu Kumar & Daimary, Niran & Maharana, Mrutyunjay & Goswami, Imon Kalyan & Hazarika, Anil & Bora, Utpal & Deka, Dhanapati, 2020. "Carica papaya stem: A source of versatile heterogeneous catalyst for biodiesel production and C–C bond formation," Renewable Energy, Elsevier, vol. 147(P1), pages 541-555.
    2. Yesilyurt, Murat Kadir & Cesur, Cüneyt & Aslan, Volkan & Yilbasi, Zeki, 2020. "The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potential feedstock and its usage in compression ignition engine: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    3. Anietie O. Etim & Eriola Betiku & Sheriff O. Ajala & Peter J. Olaniyi & Tunde V. Ojumu, 2018. "Potential of Ripe Plantain Fruit Peels as an Ecofriendly Catalyst for Biodiesel Synthesis: Optimization by Artificial Neural Network Integrated with Genetic Algorithm," Sustainability, MDPI, vol. 10(3), pages 1-15, March.
    4. Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Yussof, Hafizuddin Wan & Chong, W.T. & Lee, Keat Teong, 2013. "A comparative evaluation of physical and chemical properties of biodiesel synthesized from edible and non-edible oils and study on the effect of biodiesel blending," Energy, Elsevier, vol. 58(C), pages 296-304.
    5. Vadery, Vinu & Narayanan, Binitha N. & Ramakrishnan, Resmi M. & Cherikkallinmel, Sudha Kochiyil & Sugunan, Sankaran & Narayanan, Divya P. & Sasidharan, Sreenikesh, 2014. "Room temperature production of jatropha biodiesel over coconut husk ash," Energy, Elsevier, vol. 70(C), pages 588-594.
    6. Mohammad I. Jahirul & Wenyong Koh & Richard J. Brown & Wijitha Senadeera & Ian O'Hara & Lalehvash Moghaddam, 2014. "Biodiesel Production from Non-Edible Beauty Leaf ( Calophyllum inophyllum ) Oil: Process Optimization Using Response Surface Methodology (RSM)," Energies, MDPI, vol. 7(8), pages 1-15, August.
    7. Arumugam, A. & Ponnusami, V., 2014. "Biodiesel production from Calophyllum inophyllum oil using lipase producing Rhizopus oryzae cells immobilized within reticulated foams," Renewable Energy, Elsevier, vol. 64(C), pages 276-282.
    8. Balajii, Muthusamy & Niju, Subramaniapillai, 2020. "Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil," Renewable Energy, Elsevier, vol. 146(C), pages 2255-2269.
    9. Betiku, Eriola & Akintunde, Aramide Mistura & Ojumu, Tunde Victor, 2016. "Banana peels as a biobase catalyst for fatty acid methyl esters production using Napoleon's plume (Bauhinia monandra) seed oil: A process parameters optimization study," Energy, Elsevier, vol. 103(C), pages 797-806.
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