IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v89y2015icp982-989.html
   My bibliography  Save this article

An investigation on the catalytic capability of the modified white mud after activation in transesterification and kinetic calculation

Author

Listed:
  • Niu, Shengli
  • Zhou, Yan
  • Li, Hui
  • Lu, Chunmei
  • Liu, Li

Abstract

White mud is modified by acetic acid and then activated at 700 °C to catalyze transesterification. After modification and activation, the prepared catalyst (labeled as MWM–700) mainly consists of calcium oxide with a surface area of 7.97 m2 g−1 and basic strength of 9.8 < H_ < 15.0. Under the optimized condition of the catalyst added amount of 6 wt%, molar ratio of methanol to oil of 15, reaction temperature of 64 °C and reaction time of 150 min, the MWM–700 catalyzed transesterification of peanut oil with methanol supplies an efficiency of 97.43%. With the seventh time usage, a catalytic efficiency of 89.33% is still supplied. Meanwhile, the repeated experiments are conducted to confirm the reproducibility and reliability of the experimental results. The chemical structure and physical properties of the produced biodiesel are detected, which are in accordance with ASTM D 6751. Finally, the kinetic parameters of the MWM–700 catalyzed transesterification are calculated, where the activation energy is 66.82 kJ mol−1 and the pre-exponential factor is 1.36 × 109 min−1.

Suggested Citation

  • Niu, Shengli & Zhou, Yan & Li, Hui & Lu, Chunmei & Liu, Li, 2015. "An investigation on the catalytic capability of the modified white mud after activation in transesterification and kinetic calculation," Energy, Elsevier, vol. 89(C), pages 982-989.
    • Handle: RePEc:eee:energy:v:89:y:2015:i:c:p:982-989
    DOI: 10.1016/j.energy.2015.06.034
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215007902
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.06.034?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    2. Eevera, T. & Rajendran, K. & Saradha, S., 2009. "Biodiesel production process optimization and characterization to assess the suitability of the product for varied environmental conditions," Renewable Energy, Elsevier, vol. 34(3), pages 762-765.
    3. Li, Yingjie & Zhao, Changsui & Chen, Huichao & Ren, Qiangqiang & Duan, Lunbo, 2011. "CO2 capture efficiency and energy requirement analysis of power plant using modified calcium-based sorbent looping cycle," Energy, Elsevier, vol. 36(3), pages 1590-1598.
    4. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    5. Teo, Siow Hwa & Islam, Aminul & Yusaf, Talal & Taufiq-Yap, Yun Hin, 2014. "Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst," Energy, Elsevier, vol. 78(C), pages 63-71.
    6. Suryaputra, Wijaya & Winata, Indra & Indraswati, Nani & Ismadji, Suryadi, 2013. "Waste capiz (Amusium cristatum) shell as a new heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 50(C), pages 795-799.
    7. Ramezani, K. & Rowshanzamir, S. & Eikani, M.H., 2010. "Castor oil transesterification reaction: A kinetic study and optimization of parameters," Energy, Elsevier, vol. 35(10), pages 4142-4148.
    8. Hájek, Martin & Skopal, František & Čapek, Libor & Černoch, Michal & Kutálek, Petr, 2012. "Ethanolysis of rapeseed oil by KOH as homogeneous and as heterogeneous catalyst supported on alumina and CaO," Energy, Elsevier, vol. 48(1), pages 392-397.
    9. Singhabhandhu, Ampaitepin & Tezuka, Tetsuo, 2010. "A perspective on incorporation of glycerin purification process in biodiesel plants using waste cooking oil as feedstock," Energy, Elsevier, vol. 35(6), pages 2493-2504.
    10. Portugal-Pereira, Joana & Nakatani, Jun & Kurisu, Kiyo H. & Hanaki, Keisuke, 2015. "Comparative energy and environmental analysis of Jatropha bioelectricity versus biodiesel production in remote areas," Energy, Elsevier, vol. 83(C), pages 284-293.
    11. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
    12. Yun, Huimin & Wang, Meng & Feng, Wei & Tan, Tianwei, 2013. "Process simulation and energy optimization of the enzyme-catalyzed biodiesel production," Energy, Elsevier, vol. 54(C), pages 84-96.
    13. Borges, Karen Araújo & Squissato, André Luiz & Santos, Douglas Queiroz & Neto, Waldomiro Borges & Batista, Antônio Carlos Ferreira & Silva, Tiago Almeida & Vieira, Andressa Tironi & de Oliveira, Marce, 2014. "Homogeneous catalysis of soybean oil transesterification via methylic and ethylic routes: Multivariate comparison," Energy, Elsevier, vol. 67(C), pages 569-574.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Qu, Tongxin & Niu, Shengli & Gong, Zhiqiang & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2020. "Wollastonite decorated with calcium oxide as heterogeneous transesterification catalyst for biodiesel production: Optimized by response surface methodology," Renewable Energy, Elsevier, vol. 159(C), pages 873-884.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liang, Xuezheng, 2013. "Synthesis of biodiesel from waste oil under mild conditions using novel acidic ionic liquid immobilization on poly divinylbenzene," Energy, Elsevier, vol. 63(C), pages 103-108.
    2. Singh, Bhaskar & Guldhe, Abhishek & Rawat, Ismail & Bux, Faizal, 2014. "Towards a sustainable approach for development of biodiesel from plant and microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 216-245.
    3. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
    4. Ding, Hui & Ye, Wei & Wang, Yongqiang & Wang, Xianqin & Li, Lujun & Liu, Dan & Gui, Jianzhou & Song, Chunfeng & Ji, Na, 2018. "Process intensification of transesterification for biodiesel production from palm oil: Microwave irradiation on transesterification reaction catalyzed by acidic imidazolium ionic liquids," Energy, Elsevier, vol. 144(C), pages 957-967.
    5. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    6. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    7. Sánchez, Marcos & Navas, Marisa & Ruggera, José F. & Casella, Mónica L. & Aracil, José & Martínez, Mercedes, 2014. "Biodiesel production optimization using γAl2O3 based catalysts," Energy, Elsevier, vol. 73(C), pages 661-669.
    8. Hwei Voon Lee & Joon Ching Juan & Taufiq-Yap Yun Hin & Hwai Chyuan Ong, 2016. "Environment-Friendly Heterogeneous Alkaline-Based Mixed Metal Oxide Catalysts for Biodiesel Production," Energies, MDPI, vol. 9(8), pages 1-12, August.
    9. Ng, Wendy Pei Qin & Lam, Hon Loong & Yusup, Suzana, 2013. "Supply network synthesis on rubber seed oil utilisation as potential biofuel feedstock," Energy, Elsevier, vol. 55(C), pages 82-88.
    10. Qian, Kun & Shen, Xiang & Wang, Yanxin & Gao, Qiang & Ding, Hongwei, 2015. "In-situ transesterification of Jatropha oil over an efficient solid alkali using low leaching component supported on industrial silica gel," Energy, Elsevier, vol. 93(P2), pages 2251-2257.
    11. Satyanarayana, M. & Muraleedharan, C., 2011. "A comparative study of vegetable oil methyl esters (biodiesels)," Energy, Elsevier, vol. 36(4), pages 2129-2137.
    12. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    13. Han Jin & Praveen Kolar & Steven W. Peretti & Jason A. Osborne & Jay J. Cheng, 2017. "Kinetics and Mechanism of NaOH-Impregnated Calcined Oyster Shell-Catalyzed Transesterification of Soybean Oil," Energies, MDPI, vol. 10(11), pages 1-18, November.
    14. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Yang, Yajuan & Wang, Nan & Ma, Hongzhi, 2015. "Biodiesel production using unrefined methanol as transesterification agent and the research of individual effect of impurities," Energy, Elsevier, vol. 82(C), pages 361-369.
    15. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    16. Pereira, Caio & Wang, Gongliang & Costa, Mário, 2014. "Combustion of biodiesel in a large-scale laboratory furnace," Energy, Elsevier, vol. 74(C), pages 950-955.
    17. Akhabue, Christopher Ehiaguina & Osa-Benedict, Evidence Osayi & Oyedoh, Eghe Amenze & Otoikhian, Shegun Kevin, 2020. "Development of a bio-based bifunctional catalyst for simultaneous esterification and transesterification of neem seed oil: Modeling and optimization studies," Renewable Energy, Elsevier, vol. 152(C), pages 724-735.
    18. Mukhtar, Ahmad & Saqib, Sidra & Mubashir, Muhammad & Ullah, Sami & Inayat, Abrar & Mahmood, Abid & Ibrahim, Muhammad & Show, Pau Loke, 2021. "Mitigation of CO2 emissions by transforming to biofuels: Optimization of biofuels production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    19. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.
    20. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:89:y:2015:i:c:p:982-989. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.