IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v172y2016icp23-33.html
   My bibliography  Save this article

A low cost one pot synthesis of biodiesel from waste frying oil (WFO) using a novel material, β-potassium dizirconate (β-K2Zr2O5)

Author

Listed:
  • Singh, Veena
  • Bux, Faizal
  • Sharma, Yogesh Chandra

Abstract

Biodiesel was synthesized from waste frying oil (WFO) using β-potassium dizirconate (β-K2Zr2O5) as a novel heterogeneous catalyst. Synthesized catalyst was characterized by X-ray diffractometry (XRD), thermogravimetric analysis (TGA), attenuated total reflectance fourier transform infrared spectroscopy (ATR-FTIR), particle size analyser, scanning electron microscopy (SEM), BET surface area and basicity. Various reaction conditions such as molar ratio of methanol: oil, catalyst amount (wt%), reaction temperature, time and reusability of catalyst were studied for transesterification reaction with the catalyst, β-K2Zr2O5. High biodiesel conversion of 96.85% was observed at a 10:1M ratio (alcohol: oil), 4wt% catalyst at 65°C for 2h. WFO was characterized by GCMS and biodiesel conversion was ascertained by Fourier transform nuclear magnetic resonance (1H and 13C FTNMR) spectroscopy. It was first time that β-potassium dizirconate was used as a catalyst for biodiesel synthesis. The catalyst was reused up to five times without significant loss in its activity. Physical and chemical properties of FAME such as flash point, fire point, cloud point, density, and kinematic viscosity were deliberated.

Suggested Citation

  • Singh, Veena & Bux, Faizal & Sharma, Yogesh Chandra, 2016. "A low cost one pot synthesis of biodiesel from waste frying oil (WFO) using a novel material, β-potassium dizirconate (β-K2Zr2O5)," Applied Energy, Elsevier, vol. 172(C), pages 23-33.
    • Handle: RePEc:eee:appene:v:172:y:2016:i:c:p:23-33
    DOI: 10.1016/j.apenergy.2016.02.135
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916302914
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.02.135?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sharma, Y.C. & Singh, B., 2009. "Development of biodiesel: Current scenario," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1646-1651, August.
    2. Balat, Mustafa & Balat, Havva, 2010. "Progress in biodiesel processing," Applied Energy, Elsevier, vol. 87(6), pages 1815-1835, June.
    3. Chattopadhyay, Soham & Sen, Ramkrishna, 2013. "Fuel properties, engine performance and environmental benefits of biodiesel produced by a green process," Applied Energy, Elsevier, vol. 105(C), pages 319-326.
    4. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
    5. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    6. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
    7. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    8. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    9. An, H. & Yang, W.M. & Maghbouli, A. & Li, J. & Chou, S.K. & Chua, K.J., 2013. "Performance, combustion and emission characteristics of biodiesel derived from waste cooking oils," Applied Energy, Elsevier, vol. 112(C), pages 493-499.
    10. Bari, S., 2014. "Performance, combustion and emission tests of a metro-bus running on biodiesel-ULSD blended (B20) fuel," Applied Energy, Elsevier, vol. 124(C), pages 35-43.
    11. Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2014. "Potassium impregnated nanocrystalline mixed oxides of La and Mg as heterogeneous catalysts for transesterification," Renewable Energy, Elsevier, vol. 62(C), pages 226-233.
    12. Jincheng Ding & Benqiao He & Jianxin Li, 2011. "Biodiesel Production from Acidified Oils via Supercritical Methanol," Energies, MDPI, vol. 4(12), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Renas Hasan Saeed Saeed & Youssef Kassem & Hüseyin Çamur, 2019. "Effect of Biodiesel Mixture Derived from Waste Frying-Corn, Frying-Canola-Corn and Canola-Corn Cooking Oils with Various ‎Ages on Physicochemical Properties," Energies, MDPI, vol. 12(19), pages 1-26, September.
    2. Ambat, Indu & Srivastava, Varsha & Haapaniemi, Esa & Sillanpää, Mika, 2019. "Nano-magnetic potassium impregnated ceria as catalyst for the biodiesel production," Renewable Energy, Elsevier, vol. 139(C), pages 1428-1436.
    3. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    4. Ambat, Indu & Srivastava, Varsha & Iftekhar, Sidra & Haapaniemi, Esa & Sillanpää, Mika, 2020. "Effect of different co-solvents on biodiesel production from various low-cost feedstocks using Sr–Al double oxides," Renewable Energy, Elsevier, vol. 146(C), pages 2158-2169.
    5. AlSharifi, Mariam & Znad, Hussein, 2020. "Transesterification of waste canola oil by lithium/zinc composite supported on waste chicken bone as an effective catalyst," Renewable Energy, Elsevier, vol. 151(C), pages 740-749.
    6. Ambat, Indu & Srivastava, Varsha & Sillanpää, Mika, 2018. "Recent advancement in biodiesel production methodologies using various feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 356-369.
    7. Chiatti, Giancarlo & Chiavola, Ornella & Palmieri, Fulvio, 2017. "Vibration and acoustic characteristics of a city-car engine fueled with biodiesel blends," Applied Energy, Elsevier, vol. 185(P1), pages 664-670.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    2. Su, Chia-Hung, 2013. "Recoverable and reusable hydrochloric acid used as a homogeneous catalyst for biodiesel production," Applied Energy, Elsevier, vol. 104(C), pages 503-509.
    3. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    4. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    5. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    6. Boonyongmaneerat, Yuttanant & Sukjamsri, Chamaiporn & Sahapatsombut, Ukrit & Saenapitak, Sawalee & Sukkasi, Sittha, 2011. "Investigation of electrodeposited Ni-based coatings for biodiesel storage," Applied Energy, Elsevier, vol. 88(3), pages 909-913, March.
    7. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    8. Gong, Shu-wen & Lu, Jing & Wang, Hong-hong & Liu, Li-jun & Zhang, Qian, 2014. "Biodiesel production via esterification of oleic acid catalyzed by picolinic acid modified 12-tungstophosphoric acid," Applied Energy, Elsevier, vol. 134(C), pages 283-289.
    9. Wang, Jiayan & Xing, Shiyou & Huang, Yanqin & Fan, Pei & Fu, Junying & Yang, Gaixiu & Yang, Lingmei & Lv, Pengmei, 2017. "Highly stable gasified straw slag as a novel solid base catalyst for the effective synthesis of biodiesel: Characteristics and performance," Applied Energy, Elsevier, vol. 190(C), pages 703-712.
    10. Gude, Veera Gnaneswar & Grant, Georgene Elizabeth, 2013. "Biodiesel from waste cooking oils via direct sonication," Applied Energy, Elsevier, vol. 109(C), pages 135-144.
    11. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    12. Bora, Plaban & Konwar, Lakhya Jyoti & Boro, Jutika & Phukan, Mayur Mausoom & Deka, Dhanapati & Konwar, Bolin Kumar, 2014. "Hybrid biofuels from non-edible oils: A comparative standpoint with corresponding biodiesel," Applied Energy, Elsevier, vol. 135(C), pages 450-460.
    13. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    14. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "Production of biodiesel using high free fatty acid feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3275-3285.
    15. Singh, Bhaskar & Guldhe, Abhishek & Rawat, Ismail & Bux, Faizal, 2014. "Towards a sustainable approach for development of biodiesel from plant and microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 216-245.
    16. Sharma, Yogesh Chandra & Singh, Veena, 2017. "Microalgal biodiesel: A possible solution for India’s energy security," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 72-88.
    17. Ding, Hui & Ye, Wei & Wang, Yongqiang & Wang, Xianqin & Li, Lujun & Liu, Dan & Gui, Jianzhou & Song, Chunfeng & Ji, Na, 2018. "Process intensification of transesterification for biodiesel production from palm oil: Microwave irradiation on transesterification reaction catalyzed by acidic imidazolium ionic liquids," Energy, Elsevier, vol. 144(C), pages 957-967.
    18. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    19. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.
    20. S. M. Ashrafur Rahman & I. M. Rizwanul Fattah & Hwai Chyuan Ong & M. F. M. A. Zamri, 2021. "State-of-the-Art of Strategies to Reduce Exhaust Emissions from Diesel Engine Vehicles," Energies, MDPI, vol. 14(6), pages 1-24, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:172:y:2016:i:c:p:23-33. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.