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Thermodynamic analysis of small-scale dimethyl ether (DME) and methanol plants based on the efficient two-stage gasifier

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  • Clausen, Lasse R.
  • Elmegaard, Brian
  • Ahrenfeldt, Jesper
  • Henriksen, Ulrik

Abstract

Models of dimethyl ether (DME) and methanol synthesis plants have been designed by combining the features of the simulation tools DNA and Aspen Plus. The plants produce DME or methanol by catalytic conversion of a syngas generated by gasification of woody biomass. Electricity is co-produced in the plants by a gas engine utilizing the unconverted syngas. A two-stage gasifier with a cold gas efficiency of 93% is used, but because of the design of this type of gasifier, the plants have to be of small-scale (5 MWth biomass input). The plant models show energy efficiencies from biomass to DME/methanol + electricity of 51–58% (LHV), which shows to be 6-8%-points lower than efficiencies achievable on large-scale plants based on torrefied biomass pellets. By using waste heat from the plants for district heating, the total energy efficiencies become 87–88%.

Suggested Citation

  • Clausen, Lasse R. & Elmegaard, Brian & Ahrenfeldt, Jesper & Henriksen, Ulrik, 2011. "Thermodynamic analysis of small-scale dimethyl ether (DME) and methanol plants based on the efficient two-stage gasifier," Energy, Elsevier, vol. 36(10), pages 5805-5814.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:10:p:5805-5814
    DOI: 10.1016/j.energy.2011.08.047
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    Cited by:

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    5. Bang-Møller, C. & Rokni, M. & Elmegaard, B. & Ahrenfeldt, J. & Henriksen, U.B., 2013. "Decentralized combined heat and power production by two-stage biomass gasification and solid oxide fuel cells," Energy, Elsevier, vol. 58(C), pages 527-537.
    6. Wang, Shucheng & Chen, Xiaoxu & Wei, Bing & Fu, Zhongguang & Li, Hongwei & Qin, Mei, 2023. "Thermodynamic analysis of a net zero emission system with CCHP and green DME production by integrating biomass gasification," Energy, Elsevier, vol. 273(C).
    7. Sanaei, Sayyed Mohammad & Nakata, Toshihiko, 2012. "Optimum design of district heating: Application of a novel methodology for improved design of community scale integrated energy systems," Energy, Elsevier, vol. 38(1), pages 190-204.
    8. Clausen, Lasse R., 2017. "Energy efficient thermochemical conversion of very wet biomass to biofuels by integration of steam drying, steam electrolysis and gasification," Energy, Elsevier, vol. 125(C), pages 327-336.
    9. Salman, Chaudhary Awais & Naqvi, Muhammad & Thorin, Eva & Yan, Jinyue, 2018. "Gasification process integration with existing combined heat and power plants for polygeneration of dimethyl ether or methanol: A detailed profitability analysis," Applied Energy, Elsevier, vol. 226(C), pages 116-128.
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    11. Clausen, Lasse R., 2014. "Integrated torrefaction vs. external torrefaction – A thermodynamic analysis for the case of a thermochemical biorefinery," Energy, Elsevier, vol. 77(C), pages 597-607.
    12. Runge, Philipp & Sölch, Christian & Albert, Jakob & Wasserscheid, Peter & Zöttl, Gregor & Grimm, Veronika, 2019. "Economic comparison of different electric fuels for energy scenarios in 2035," Applied Energy, Elsevier, vol. 233, pages 1078-1093.
    13. Yao, Dong & Xu, Zaifeng & Qi, Huaqing & Zhu, Zhaoyou & Gao, Jun & Wang, Yinglong & Cui, Peizhe, 2022. "Carbon footprint and water footprint analysis of generating synthetic natural gas from biomass," Renewable Energy, Elsevier, vol. 186(C), pages 780-789.
    14. Clausen, Lasse R., 2015. "Maximizing biofuel production in a thermochemical biorefinery by adding electrolytic hydrogen and by integrating torrefaction with entrained flow gasification," Energy, Elsevier, vol. 85(C), pages 94-104.
    15. Kansha, Yasuki & Ishizuka, Masanori & Song, Chunfeng & Tsutsumi, Atsushi, 2015. "Process intensification for dimethyl ether production by self-heat recuperation," Energy, Elsevier, vol. 90(P1), pages 122-127.
    16. Elias Vieren & Toon Demeester & Wim Beyne & Chiara Magni & Hamed Abedini & Cordin Arpagaus & Stefan Bertsch & Alessia Arteconi & Michel De Paepe & Steven Lecompte, 2023. "The Potential of Vapor Compression Heat Pumps Supplying Process Heat between 100 and 200 °C in the Chemical Industry," Energies, MDPI, vol. 16(18), pages 1-28, September.
    17. Sigurjonsson, Hafthor Ægir & Clausen, Lasse R., 2018. "Solution for the future smart energy system: A polygeneration plant based on reversible solid oxide cells and biomass gasification producing either electrofuel or power," Applied Energy, Elsevier, vol. 216(C), pages 323-337.
    18. Ji, Changwei & Liang, Chen & Gao, Binbin & Wei, Baojian & Liu, Xiaolong & Zhu, Yongming, 2013. "The cold start performance of a spark-ignited dimethyl ether engine," Energy, Elsevier, vol. 50(C), pages 187-193.
    19. Wu, Handong & Gao, Lin & Jin, Hongguang & Li, Sheng, 2017. "Low-energy-penalty principles of CO2 capture in polygeneration systems," Applied Energy, Elsevier, vol. 203(C), pages 571-581.
    20. Lythcke-Jørgensen, Christoffer & Clausen, Lasse Røngaard & Algren, Loui & Hansen, Anders Bavnhøj & Münster, Marie & Gadsbøll, Rasmus Østergaard & Haglind, Fredrik, 2017. "Optimization of a flexible multi-generation system based on wood chip gasification and methanol production," Applied Energy, Elsevier, vol. 192(C), pages 337-359.
    21. Chaudhary Awais Salman & Ch Bilal Omer, 2020. "Process Modelling and Simulation of Waste Gasification-Based Flexible Polygeneration Facilities for Power, Heat and Biofuels Production," Energies, MDPI, vol. 13(16), pages 1-22, August.

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