IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v250y2022ics036054422200679x.html
   My bibliography  Save this article

Influence of metal chloride modified biochar on products characteristics from biomass catalytic pyrolysis

Author

Listed:
  • Liu, Zihan
  • Li, Pan
  • Chang, Chun
  • Wang, Xianhua
  • Song, Jiande
  • Fang, Shuqi
  • Pang, Shusheng

Abstract

In this study, the pyrolysis temperature of peanut shells was optimized, and biochar was prepared and modified with HCl to obtain better surface characteristics and pore structure. The incipient wetness impregnation method was used to load one or two of NaCl, MnCl2, FeCl3 on HC, and their influences on the characteristics of the pyrolysis products were studied. The results show phenols have completed the evolution from methoxyphenols to benzenediols to alkylated phenols and aromatics from 440 °C to 660 °C. FeCl3 modified biochar has high phenol selectivity, reaching the maximum value of 46.63% when the loading is 8%. And it also has the highest aromatics selectivity. When the loading is 16%, the aromatic content is 38.33%. The selectivity of phenols and aromatics of MnCl2 is slightly lower than that of FeCl3, but it has the highest decarboxylation activity. The selectivity of NaCl is low, but it has the highest yield of aromatics at low loading. The advantage of bimetal modification is that it can take into account the selectivity of phenol and aromatics. The study indicates peanut shells have the potential to be widely used as raw materials and catalysts for the production of high value-added chemicals.

Suggested Citation

  • Liu, Zihan & Li, Pan & Chang, Chun & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2022. "Influence of metal chloride modified biochar on products characteristics from biomass catalytic pyrolysis," Energy, Elsevier, vol. 250(C).
    • Handle: RePEc:eee:energy:v:250:y:2022:i:c:s036054422200679x
    DOI: 10.1016/j.energy.2022.123776
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054422200679X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.123776?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Li & Yao, Zonglu & Zhao, Lixin & Li, Zhihe & Yi, Weiming & Kang, Kang & Jia, Jixiu, 2021. "Synthesis and characterization of different activated biochar catalysts for removal of biomass pyrolysis tar," Energy, Elsevier, vol. 232(C).
    2. Chen, Wei & Fang, Yang & Li, Kaixu & Chen, Zhiqun & Xia, Mingwei & Gong, Meng & Chen, Yingquan & Yang, Haiping & Tu, Xin & Chen, Hanping, 2020. "Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products," Applied Energy, Elsevier, vol. 260(C).
    3. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    4. Yang, Haiping & Chen, Zhiqun & Chen, Wei & Chen, Yingquan & Wang, Xianhua & Chen, Hanping, 2020. "Role of porous structure and active O-containing groups of activated biochar catalyst during biomass catalytic pyrolysis," Energy, Elsevier, vol. 210(C).
    5. Zhao, Na & Li, Bao-Xia, 2016. "The effect of sodium chloride on the pyrolysis of rice husk," Applied Energy, Elsevier, vol. 178(C), pages 346-352.
    6. Hernández, J.J. & Ballesteros, R. & Aranda, G., 2013. "Characterisation of tars from biomass gasification: Effect of the operating conditions," Energy, Elsevier, vol. 50(C), pages 333-342.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    2. Yang, Shi-guan & Zhou, Jia-le & Hu, Zhuang & Zhou, Xin-yue & Cai, Qi & Xie, Jin-heng & Wu, Yang-wen & Lu, Qiang, 2023. "Site selection decision framework for biomass pyrolysis project based on a mixed method under probabilistic linguistic environment and low carbon perspective: A case study in China," Energy, Elsevier, vol. 272(C).
    3. Bartłomiej Igliński & Wojciech Kujawski & Urszula Kiełkowska, 2023. "Pyrolysis of Waste Biomass: Technical and Process Achievements, and Future Development—A Review," Energies, MDPI, vol. 16(4), pages 1-26, February.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    2. Chang, Chun & Liu, Zihan & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2021. "Study on products characteristics from catalytic fast pyrolysis of biomass based on the effects of modified biochars," Energy, Elsevier, vol. 229(C).
    3. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    4. Yang, Haiping & Chen, Zhiqun & Chen, Wei & Chen, Yingquan & Wang, Xianhua & Chen, Hanping, 2020. "Role of porous structure and active O-containing groups of activated biochar catalyst during biomass catalytic pyrolysis," Energy, Elsevier, vol. 210(C).
    5. Asadullah, Mohammad, 2014. "Biomass gasification gas cleaning for downstream applications: A comparative critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 118-132.
    6. Yang, S.I. & Wu, M.S. & Wu, C.Y., 2014. "Application of biomass fast pyrolysis part I: Pyrolysis characteristics and products," Energy, Elsevier, vol. 66(C), pages 162-171.
    7. Liu, Shasha & Wu, Gang & Gao, Yi & Li, Bin & Feng, Yu & Zhou, Jianbin & Hu, Xun & Huang, Yong & Zhang, Shu & Zhang, Hong, 2021. "Understanding the catalytic upgrading of bio-oil from pine pyrolysis over CO2-activated biochar," Renewable Energy, Elsevier, vol. 174(C), pages 538-546.
    8. Yue, Xia & Chen, Dezhen & Luo, Jia & Xin, Qianfan & Huang, Zhen, 2020. "Upgrading of reed pyrolysis oil by using its biochar-based catalytic esterification and the influence of reed sources," Applied Energy, Elsevier, vol. 268(C).
    9. Zhang, Guozhao & Liu, Hao & Wang, Jia & Wu, Baojia, 2018. "Catalytic gasification characteristics of rice husk with calcined dolomite," Energy, Elsevier, vol. 165(PB), pages 1173-1177.
    10. Liu, Haolin & Ye, Chao & Xu, Yousheng & Wang, Qisong, 2022. "Effect of activation conditions and iron loading content on the catalytic cracking of toluene by biochar," Energy, Elsevier, vol. 247(C).
    11. Mendiburu, Andrés Z. & Carvalho, João A. & Coronado, Christian J.R., 2014. "Thermochemical equilibrium modeling of biomass downdraft gasifier: Stoichiometric models," Energy, Elsevier, vol. 66(C), pages 189-201.
    12. Kuo, Hsiu-Po & Hou, Bo-Ren & Huang, An-Ni, 2017. "The influences of the gas fluidization velocity on the properties of bio-oils from fluidized bed pyrolyzer with in-line distillation," Applied Energy, Elsevier, vol. 194(C), pages 279-286.
    13. Sérgio Ferreira & Eliseu Monteiro & Paulo Brito & Cândida Vilarinho, 2019. "A Holistic Review on Biomass Gasification Modified Equilibrium Models," Energies, MDPI, vol. 12(1), pages 1-31, January.
    14. Wan, Wei & Engvall, Klas & Yang, Weihong & Möller, Björn Fredriksson, 2018. "Experimental and modelling studies on condensation of inorganic species during cooling of product gas from pressurized biomass fluidized bed gasification," Energy, Elsevier, vol. 153(C), pages 35-44.
    15. Udomsirichakorn, Jakkapong & Salam, P. Abdul, 2014. "Review of hydrogen-enriched gas production from steam gasification of biomass: The prospect of CaO-based chemical looping gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 565-579.
    16. Gai, Chao & Dong, Yuping & Zhang, Tonghui, 2014. "Downdraft gasification of corn straw as a non-woody biomass: Effects of operating conditions on chlorides distribution," Energy, Elsevier, vol. 71(C), pages 638-644.
    17. Lopes, E.J. & Okamura, L.A. & Maruyama, S.A. & Yamamoto, C.I., 2018. "Evaluation of energy gain from the segregation of organic materials from municipal solid waste in gasification processes," Renewable Energy, Elsevier, vol. 116(PA), pages 623-629.
    18. Lucio Zaccariello & Maria Laura Mastellone, 2023. "Fuel Gas Production from the Co-Gasification of Coal, Plastic Waste, and Wood in a Fluidized Bed Reactor: Effect of Gasifying Agent and Bed Material," Sustainability, MDPI, vol. 15(9), pages 1-19, May.
    19. Ma, Wenchao & Liu, Bin & Zhang, Ruixue & Gu, Tianbao & Ji, Xiang & Zhong, Lei & Chen, Guanyi & Ma, Longlong & Cheng, Zhanjun & Li, Xiangping, 2018. "Co-upgrading of raw bio-oil with kitchen waste oil through fluid catalytic cracking (FCC)," Applied Energy, Elsevier, vol. 217(C), pages 233-240.
    20. Wu, Yujian & Wang, Haoyu & Li, Haoyang & Han, Xue & Zhang, Mingyuan & Sun, Yan & Fan, Xudong & Tu, Ren & Zeng, Yimin & Xu, Chunbao Charles & Xu, Xiwei, 2022. "Applications of catalysts in thermochemical conversion of biomass (pyrolysis, hydrothermal liquefaction and gasification): A critical review," Renewable Energy, Elsevier, vol. 196(C), pages 462-481.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:250:y:2022:i:c:s036054422200679x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.