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Influence of metal chloride modified biochar on products characteristics from biomass catalytic pyrolysis

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  • Liu, Zihan
  • Li, Pan
  • Chang, Chun
  • Wang, Xianhua
  • Song, Jiande
  • Fang, Shuqi
  • Pang, Shusheng

Abstract

In this study, the pyrolysis temperature of peanut shells was optimized, and biochar was prepared and modified with HCl to obtain better surface characteristics and pore structure. The incipient wetness impregnation method was used to load one or two of NaCl, MnCl2, FeCl3 on HC, and their influences on the characteristics of the pyrolysis products were studied. The results show phenols have completed the evolution from methoxyphenols to benzenediols to alkylated phenols and aromatics from 440 °C to 660 °C. FeCl3 modified biochar has high phenol selectivity, reaching the maximum value of 46.63% when the loading is 8%. And it also has the highest aromatics selectivity. When the loading is 16%, the aromatic content is 38.33%. The selectivity of phenols and aromatics of MnCl2 is slightly lower than that of FeCl3, but it has the highest decarboxylation activity. The selectivity of NaCl is low, but it has the highest yield of aromatics at low loading. The advantage of bimetal modification is that it can take into account the selectivity of phenol and aromatics. The study indicates peanut shells have the potential to be widely used as raw materials and catalysts for the production of high value-added chemicals.

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  • Liu, Zihan & Li, Pan & Chang, Chun & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2022. "Influence of metal chloride modified biochar on products characteristics from biomass catalytic pyrolysis," Energy, Elsevier, vol. 250(C).
    • Handle: RePEc:eee:energy:v:250:y:2022:i:c:s036054422200679x
    DOI: 10.1016/j.energy.2022.123776
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    1. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    2. Zhang, Li & Yao, Zonglu & Zhao, Lixin & Li, Zhihe & Yi, Weiming & Kang, Kang & Jia, Jixiu, 2021. "Synthesis and characterization of different activated biochar catalysts for removal of biomass pyrolysis tar," Energy, Elsevier, vol. 232(C).
    3. Yang, Haiping & Chen, Zhiqun & Chen, Wei & Chen, Yingquan & Wang, Xianhua & Chen, Hanping, 2020. "Role of porous structure and active O-containing groups of activated biochar catalyst during biomass catalytic pyrolysis," Energy, Elsevier, vol. 210(C).
    4. Chen, Wei & Fang, Yang & Li, Kaixu & Chen, Zhiqun & Xia, Mingwei & Gong, Meng & Chen, Yingquan & Yang, Haiping & Tu, Xin & Chen, Hanping, 2020. "Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products," Applied Energy, Elsevier, vol. 260(C).
    5. Zhao, Na & Li, Bao-Xia, 2016. "The effect of sodium chloride on the pyrolysis of rice husk," Applied Energy, Elsevier, vol. 178(C), pages 346-352.
    6. Hernández, J.J. & Ballesteros, R. & Aranda, G., 2013. "Characterisation of tars from biomass gasification: Effect of the operating conditions," Energy, Elsevier, vol. 50(C), pages 333-342.
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    Cited by:

    1. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    2. Yang, Shi-guan & Zhou, Jia-le & Hu, Zhuang & Zhou, Xin-yue & Cai, Qi & Xie, Jin-heng & Wu, Yang-wen & Lu, Qiang, 2023. "Site selection decision framework for biomass pyrolysis project based on a mixed method under probabilistic linguistic environment and low carbon perspective: A case study in China," Energy, Elsevier, vol. 272(C).
    3. Bartłomiej Igliński & Wojciech Kujawski & Urszula Kiełkowska, 2023. "Pyrolysis of Waste Biomass: Technical and Process Achievements, and Future Development—A Review," Energies, MDPI, vol. 16(4), pages 1-26, February.

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