IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v239y2022ipas0360544221021733.html
   My bibliography  Save this article

Paper mill sludge biochar to enhance energy recovery from pyrolysis: A comprehensive evaluation and comparison

Author

Listed:
  • Liu, Zhongzhe
  • Hughes, Matthew
  • Tong, Yiran
  • Zhou, Jizhi
  • Kreutter, William
  • Lopez, Hugo Cortes
  • Singer, Simcha
  • Zitomer, Daniel
  • McNamara, Patrick

Abstract

Bio-oil and pyrolysis gas (py-gas) are two pyrolysis products available for potential energy recovery. Crude bio-oil, however, is typically corrosive and unstable, requiring special combustion equipment or catalytic upgrading to produce drop-in-grade fuel. In contrast, py-gas is readily useable in standard equipment for energy recovery. Previous research revealed that Ca-impregnated biochar catalyst improved bio-oil to py-gas conversion. Biochar produced from paper mill sludge (p-sludge) has very high Ca content. In this study, the catalytic ability of p-sludge biochar was systematically evaluated for the first time in pyrolysis. P-sludge biochar resulted in higher py-gas yield (40 wt% of total pyrolysis products) and py-gas energy (8400 kJ of py-gas per biosolids pyrolyzed) than other biochar catalysts (e.g. wood and corn stover biochars) and mineral catalysts (e.g. calcined dolomite). Under some conditions (e.g. high temperature and catalyst loading), catalysis completely eliminated the nonaqueous phase condensate. A lower catalyst-to-feedstock ratio was required using p-sludge biochar compared to other biochars for similar performance. P-sludge biochar also had a longer catalyst lifetime based on the effectiveness over five reuse cycles. Bio-oil catalyzed by p-sludge biochar contained fewer organic constituents based on GC-MS and GC-FID analyses (e.g. toluene, ethylbenzene, styrene, phenol, cresol, and indole were not identified after catalysis).

Suggested Citation

  • Liu, Zhongzhe & Hughes, Matthew & Tong, Yiran & Zhou, Jizhi & Kreutter, William & Lopez, Hugo Cortes & Singer, Simcha & Zitomer, Daniel & McNamara, Patrick, 2022. "Paper mill sludge biochar to enhance energy recovery from pyrolysis: A comprehensive evaluation and comparison," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021733
    DOI: 10.1016/j.energy.2021.121925
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221021733
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.121925?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fonts, Isabel & Gea, Gloria & Azuara, Manuel & Ábrego, Javier & Arauzo, Jesús, 2012. "Sewage sludge pyrolysis for liquid production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2781-2805.
    2. Devi, Lopamudra & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G. & van Paasen, Sander V.B. & Bergman, Patrick C.A. & Kiel, Jacob H.A., 2005. "Catalytic decomposition of biomass tars: use of dolomite and untreated olivine," Renewable Energy, Elsevier, vol. 30(4), pages 565-587.
    3. Shen, Yafei & Yoshikawa, Kunio, 2013. "Recent progresses in catalytic tar elimination during biomass gasification or pyrolysis—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 371-392.
    4. Liu, Zhongzhe & Singer, Simcha & Tong, Yiran & Kimbell, Lee & Anderson, Erik & Hughes, Matthew & Zitomer, Daniel & McNamara, Patrick, 2018. "Characteristics and applications of biochars derived from wastewater solids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 650-664.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yifan Shen & Qi Li & Xiangjun Pei & Renjie Wei & Bingmei Yang & Ningfei Lei & Xiaochao Zhang & Daqiu Yin & Shijun Wang & Qizhong Tao, 2023. "Ecological Restoration of Engineering Slopes in China—A Review," Sustainability, MDPI, vol. 15(6), pages 1-17, March.
    2. Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).
    3. Tharaka Rama Krishna C. Doddapaneni & Linnar Pärn & Timo Kikas, 2022. "Torrefaction of Pulp Industry Sludge to Enhance Its Fuel Characteristics," Energies, MDPI, vol. 15(17), pages 1-15, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Syed-Hassan, Syed Shatir A. & Wang, Yi & Hu, Song & Su, Sheng & Xiang, Jun, 2017. "Thermochemical processing of sewage sludge to energy and fuel: Fundamentals, challenges and considerations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 888-913.
    2. Ud Din, Zia & Zainal, Z.A., 2016. "Biomass integrated gasification–SOFC systems: Technology overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1356-1376.
    3. Saba Seyedi & Kaushik Venkiteshwaran & Nicholas Benn & Daniel Zitomer, 2020. "Inhibition during Anaerobic Co-Digestion of Aqueous Pyrolysis Liquid from Wastewater Solids and Synthetic Primary Sludge," Sustainability, MDPI, vol. 12(8), pages 1-15, April.
    4. Bendoni, R. & Miccio, F. & Medri, V. & Benito, P. & Vaccari, A. & Landi, E., 2019. "Geopolymer composites for the catalytic cleaning of tar in biomass-derived gas," Renewable Energy, Elsevier, vol. 131(C), pages 1107-1116.
    5. Se-Won Park & Sang-Yeop Lee & Yean-Ouk Jeong & Gun-Ho Han & Yong-Chil Seo, 2018. "Effects of Oxygen Enrichment in Air Oxidants on Biomass Gasification Efficiency and the Reduction of Tar Emissions," Energies, MDPI, vol. 11(10), pages 1-13, October.
    6. Liu, Zhongzhe & Hughes, Matthew & Tong, Yiran & Zhou, Jizhi & Kreutter, William & Valtierra, Danny & Singer, Simcha & Zitomer, Daniel & McNamara, Patrick, 2021. "Enhanced energy and resource recovery via synergistic catalytic pyrolysis of byproducts from thermal processing of wastewater solids," Renewable Energy, Elsevier, vol. 177(C), pages 475-481.
    7. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    8. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    9. Prashanth Reddy Buchireddy & Devin Peck & Mark Zappi & Ray Mark Bricka, 2021. "Catalytic Hot Gas Cleanup of Biomass Gasification Producer Gas via Steam Reforming Using Nickel-Supported Clay Minerals," Energies, MDPI, vol. 14(7), pages 1-21, March.
    10. Shahbaz, Muhammad & yusup, Suzana & Inayat, Abrar & Patrick, David Onoja & Ammar, Muhammad, 2017. "The influence of catalysts in biomass steam gasification and catalytic potential of coal bottom ash in biomass steam gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 468-476.
    11. Ud Din, Zia & Zainal, Z.A., 2017. "The fate of SOFC anodes under biomass producer gas contaminants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 1050-1066.
    12. Liu, Yang & Ran, Chunmei & Siddiqui, Azka R. & Mao, Xiao & Kang, Qinhao & Fu, Jie & Deng, Zeyu & Song, Yongmeng & Jiang, Zhihui & Zhang, Tianhao & Ao, Wenya & Dai, Jianjun, 2018. "Pyrolysis of textile dyeing sludge in fluidized bed: Characterization and analysis of pyrolysis products," Energy, Elsevier, vol. 165(PA), pages 720-730.
    13. Jumoke Oladejo & Kaiqi Shi & Xiang Luo & Gang Yang & Tao Wu, 2018. "A Review of Sludge-to-Energy Recovery Methods," Energies, MDPI, vol. 12(1), pages 1-38, December.
    14. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
    15. Hu, Fu-Xiang & Yang, Guo-Hua & Ding, Guo-Zhu & Li, Zhen & Du, Ka-Shuai & Hu, Zhi-Fa & Tian, Su-Rui, 2016. "Experimental study on catalytic cracking of model tar compounds in a dual layer granular bed filter," Applied Energy, Elsevier, vol. 170(C), pages 47-57.
    16. Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    17. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    18. Patrik Šuhaj & Jakub Husár & Juma Haydary, 2020. "Gasification of RDF and Its Components with Tire Pyrolysis Char as Tar-Cracking Catalyst," Sustainability, MDPI, vol. 12(16), pages 1-14, August.
    19. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    20. Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021733. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.