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Pyrolysis of furfural residue in a bubbling fluidized bed reactor: Biochar characterization and analysis

Author

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  • Liu, Yang
  • Song, Yongmeng
  • Ran, Chunmei
  • Siyal, Asif Ali
  • Chtaeva, Polina
  • Dai, Jianjun
  • Jiang, Zhihui
  • Deng, Zeyu
  • Zhang, Tianhao
  • Ao, Wenya
  • Fu, Jie

Abstract

The pyrolysis characteristic of furfural residue (FR) was investigated in a fluidized bed reactor. The yield of biochar (BC) decreased whereas non-condensable gas yield increased with increasing temperature from 450 °C to 850 °C. The minimum BC yield (41.67 wt%) was found with addition of kaolin at 650 °C, while the maximum non-condensable gas yield (48.00 wt%) was obtained at 850 °C without additives. Furthermore, the maximum condensate yield (20.63 wt%) was observed at 650 °C with Ca-bentonite addition. Both Ca-bentonite and kaolin decreased the BC yield, while CaO promoted the BC yield. The contents of carbon, nitrogen and sulfur in BC were enriched at different temperatures. Ca-bentonite, kaolin and CaO resulted in more amount of protrusions on the BC surface and improved BC pore structures. Iodine and methylene blue adsorption values of BC were higher than that of FR and the maximum iodine adsorption value (279.6 mg/g) was obtained at 650 °C without additives. CaO remarkably increased methylene blue adsorption value, reaching the maximum value of 168.7 mg/g at 450 °C. A possible formation pathway of BC during FR pyrolysis was also proposed.

Suggested Citation

  • Liu, Yang & Song, Yongmeng & Ran, Chunmei & Siyal, Asif Ali & Chtaeva, Polina & Dai, Jianjun & Jiang, Zhihui & Deng, Zeyu & Zhang, Tianhao & Ao, Wenya & Fu, Jie, 2020. "Pyrolysis of furfural residue in a bubbling fluidized bed reactor: Biochar characterization and analysis," Energy, Elsevier, vol. 211(C).
    • Handle: RePEc:eee:energy:v:211:y:2020:i:c:s0360544220320739
    DOI: 10.1016/j.energy.2020.118966
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