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Synergistically improving electrocatalytic performance and CO2 tolerance of Fe-based cathode catalysts for solid oxide fuel cells

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  • Gao, Juntao
  • Ma, Dan
  • Zhao, Hui
  • Li, Qiang
  • Lü, Zhe
  • Wei, Bo

Abstract

Fe-based pervoskite oxides Bi0.5Sr0.5Fe1−xZrxO3−δ (BSFZx, x = 0, 0.05, 0.10 and 0.15) were synthesized and developed by doping of cation Zr as possible cathodes for solid oxide fuel cells (SOFCs). Herein, we carefully investigated the effect of Zr-doped on BSFZx physicochemical property. The Bi0.5Sr0.5Fe0.90Zr0.10O3−δ (BSFZ0.10) cathode shows the lowest Rp values ranging from 0.52 to 0.11 Ω cm2 in the temperature range of 600–700 °C and the corresponding activation energy is about 1.135 eV. A single fuel cell with BSFZ0.10 cathode delivers a satisfactory electrocatalytic performance with a peak power density (PPD) as high as 1.2 W cm−2 at 700 °C. The BSFZ0.10 also exhibits unsurpassed stability by less change in Rp values under different CO2concentrations (5, 10 and 15 vol%). The excellent chemical stability and CO2 tolerance of BSFZx electrode material is mainly due to the doping of highly acidic Zr4+ and the increase of average metal bond energy (ABE). The present work highlights that BSFZx oxides are very promising candidate cathode catalysts for oxygen-conducting SOFCs.

Suggested Citation

  • Gao, Juntao & Ma, Dan & Zhao, Hui & Li, Qiang & Lü, Zhe & Wei, Bo, 2022. "Synergistically improving electrocatalytic performance and CO2 tolerance of Fe-based cathode catalysts for solid oxide fuel cells," Energy, Elsevier, vol. 252(C).
    • Handle: RePEc:eee:energy:v:252:y:2022:i:c:s0360544222009537
    DOI: 10.1016/j.energy.2022.124050
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    References listed on IDEAS

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    1. Cai, Weizi & Cao, Dan & Zhou, Mingyang & Yan, Xiaomin & Li, Yuzhi & Wu, Zhen & Lü, Shengping & Mao, Caiyun & Xie, Yongmin & Zhao, Caiwen & Yu, Jialing & Ni, Meng & Liu, Jiang & Wang, Hailin, 2020. "Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells," Energy, Elsevier, vol. 211(C).
    2. Cascos, V. & Troncoso, L. & Alonso, J.A. & Fernández-Díaz, M.T., 2017. "Design of new Ga-doped SrMoO3 perovskites performing as anode materials in SOFC," Renewable Energy, Elsevier, vol. 111(C), pages 476-483.
    3. Yuan Zhang & Bin Chen & Daqin Guan & Meigui Xu & Ran Ran & Meng Ni & Wei Zhou & Ryan O’Hayre & Zongping Shao, 2021. "Thermal-expansion offset for high-performance fuel cell cathodes," Nature, Nature, vol. 591(7849), pages 246-251, March.
    4. Asensio, Antonio Maria & Clematis, Davide & Viviani, Massimo & Carpanese, M. Paola & Presto, Sabrina & Cademartori, Davide & Cabot, Pere L. & Barbucci, Antonio, 2021. "Impregnation of microporous SDC scaffold as stable solid oxide cell BSCF-based air electrode," Energy, Elsevier, vol. 237(C).
    5. Wang, Heng & Zhao, Hongbin & Du, Huicheng & Zhao, Zefeng & Zhang, Taiheng, 2022. "Thermodynamic performance study of a new diesel-fueled CLHG/SOFC/STIG cogeneration system with CO2 recovery," Energy, Elsevier, vol. 246(C).
    6. Zheng, Yifeng & Wang, Shun & Pan, Zehua & Yin, Bo, 2021. "Electrochemical CO2 reduction to CO using solid oxide electrolysis cells with high-performance Ta-doped bismuth strontium ferrite air electrode," Energy, Elsevier, vol. 228(C).
    7. Chen, Guihua & Wang, Yong & Sunarso, Jaka & Liang, Fengli & Wang, Huanping, 2016. "A new scandium and niobium co-doped cobalt-free perovskite cathode for intermediate-temperature solid oxide fuel cells," Energy, Elsevier, vol. 95(C), pages 137-143.
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    1. Hanif, Muhammad Bilal & Rauf, Sajid & Sultan, Amir & Tayyab, Zuhra & Zheng, Kun & Makarov, Hryhorii & Madej, Dominika & Łasocha, Wiesław & Roch, Tomas & Mosiałek, Michał & Baker, Richard T. & Li, Chen, 2024. "Boosting the electrochemical performance of oxygen electrodes via the formation of LSCF-BaCe0.9–xMoxY0.1O3–δ triple conducting composite for solid oxide fuel cells: Part II," Energy, Elsevier, vol. 289(C).
    2. Ao, Ran & Ma, Liping & Guo, Zhiying & Dai, Quxiu & Xie, Longgui & Yang, Jie, 2024. "Positive effects of the Sr doping on LaCoO3 perovskites for simultaneous catalytic oxidation performances of NO and Hg0," Energy, Elsevier, vol. 290(C).

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