IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v150y2018icp377-395.html
   My bibliography  Save this article

Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation

Author

Listed:
  • Wang, Yiwei
  • Deng, Ye
  • Guo, Xuqiang
  • Sun, Qiang
  • Liu, Aixian
  • Zhang, Guangqing
  • Yue, Gang
  • Yang, Lanying

Abstract

The effects of temperature, pressure, initial promoter concentration and coal seam gas/liquid ratio on the separation of methane from coal seam gas were experimentally investigated. Low temperature, high pressure and high promoter concentration lead to high separation efficiency and high recovery rate of CH4, but reduce the CH4 capture selectivity in hydrate. Experimental simulation of a three-stage separation shows that CH4 can be concentrated from 34.6 to 81.3 mol% in the dissociated gas, while its content is only 7.2 mol% in the residual gas. An innovative model was established to predict the separation performance. The modeling results reasonably match the experimental data in predicting the effects of different influential factors, with an average relative deviation of 2.83%, the maximum relative deviation 11.2%, and the average relative variance 0.1044. The modeling results of a three-stage separation process include 81.0 mol% of CH4 in the final dissociated gas and 5.5 mol% of CH4 in the final residual gas. The recovery rate of CH4 was 90.1 mol% and the separation factor was 73.0.

Suggested Citation

  • Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    • Handle: RePEc:eee:energy:v:150:y:2018:i:c:p:377-395
    DOI: 10.1016/j.energy.2018.01.171
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218301993
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.01.171?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    2. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    3. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    4. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    5. Cai, Jing & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2017. "Hydrate-based methane separation from coal mine methane gas mixture by bubbling using the scale-up equipment," Applied Energy, Elsevier, vol. 204(C), pages 1526-1534.
    6. Pivezhani, Farzane & Roosta, Hadi & Dashti, Ali & Mazloumi, S. Hossein, 2016. "Investigation of CO2 hydrate formation conditions for determining the optimum CO2 storage rate and energy: Modeling and experimental study," Energy, Elsevier, vol. 113(C), pages 215-226.
    7. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2017. "Entropy generation analysis of hydrate dissociation by depressurization with horizontal well in different scales of hydrate reservoirs," Energy, Elsevier, vol. 125(C), pages 62-71.
    8. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2016. "Energy and entropy analyses of hydrate dissociation in different scales of hydrate simulator," Energy, Elsevier, vol. 102(C), pages 176-186.
    9. Huen Lee & Jong-won Lee & Do Youn Kim & Jeasung Park & Yu-Taek Seo & Huang Zeng & Igor L. Moudrakovski & Christopher I. Ratcliffe & John A. Ripmeester, 2005. "Tuning clathrate hydrates for hydrogen storage," Nature, Nature, vol. 434(7034), pages 743-746, April.
    10. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    11. Wang, Fei & Fu, Shanfei & Guo, Gang & Jia, Zhen-Zhen & Luo, Sheng-Jun & Guo, Rong-Bo, 2016. "Experimental study on hydrate-based CO2 removal from CH4/CO2 mixture," Energy, Elsevier, vol. 104(C), pages 76-84.
    12. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    13. Wang, Yiwei & Du, Mei & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Chen, Bo & Chen, Guangjin & Sun, Changyu & Yang, Lanying, 2017. "Experiments and simulations for continuous recovery of methane from coal seam gas (CSG) utilizing hydrate formation," Energy, Elsevier, vol. 129(C), pages 28-41.
    14. Zhou, H. & de Sera, I.E.E. & Infante Ferreira, C.A., 2015. "Modelling and experimental validation of a fluidized bed based CO2 hydrate cold storage system," Applied Energy, Elsevier, vol. 158(C), pages 433-445.
    15. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    16. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    17. Renault-Crispo, Jean-Sébastien & Coulombe, Sylvain & Servio, Phillip, 2017. "Kinetics of carbon dioxide gas hydrates with tetrabutylammonium bromide and functionalized multi-walled carbon nanotubes," Energy, Elsevier, vol. 128(C), pages 414-420.
    18. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2017. "An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application," Applied Energy, Elsevier, vol. 188(C), pages 190-199.
    19. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    20. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    21. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    22. Kim, Shol & Lee, Seong Hyuk & Kang, Yong Tae, 2017. "Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application," Energy, Elsevier, vol. 120(C), pages 362-373.
    23. Yang, Ming, 2009. "Climate change and energy policies, coal and coalmine methane in China," Energy Policy, Elsevier, vol. 37(8), pages 2858-2869, August.
    24. Huang, Yuping & Zheng, Qipeng P. & Fan, Neng & Aminian, Kashy, 2014. "Optimal scheduling for enhanced coal bed methane production through CO2 injection," Applied Energy, Elsevier, vol. 113(C), pages 1475-1483.
    25. Xia, Zhi-Ming & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Yan, Ke-Feng & Xu, Chun-Gang & Lv, Qiu-Nan & Cai, Jing, 2016. "Hydrate-based CO2 capture and CH4 purification from simulated biogas with synergic additives based on gas solvent," Applied Energy, Elsevier, vol. 162(C), pages 1153-1159.
    26. Hashimoto, Hidenori & Yamaguchi, Tsutomu & Kinoshita, Takahiro & Muromachi, Sanehiro, 2017. "Gas separation of flue gas by tetra-n-butylammonium bromide hydrates under moderate pressure conditions," Energy, Elsevier, vol. 129(C), pages 292-298.
    27. Bi, Yuehong & Chen, Jie & Miao, Zhen, 2016. "Thermodynamic optimization for dissociation process of gas hydrates," Energy, Elsevier, vol. 106(C), pages 270-276.
    28. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    29. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    30. Cai, Jing & Xu, Chun-Gang & Lin, Fu-Hua & Yu, Hai-Zhu & Li, Xiao-Sen, 2016. "A novel method for evaluating effects of promoters on hydrate formation," Energy, Elsevier, vol. 102(C), pages 567-575.
    31. Sarhosis, V. & Jaya, A.A. & Thomas, H.R., 2016. "Economic modelling for coal bed methane production and electricity generation from deep virgin coal seams," Energy, Elsevier, vol. 107(C), pages 580-594.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2021. "Coal mine gas separation of methane via clathrate hydrate process aided by tetrahydrofuran and amino acids," Applied Energy, Elsevier, vol. 287(C).
    2. Lai, Xi & Zhao, Li & Nie, Xianhua & Zhang, Yue & Zhang, Qi, 2023. "Hydrate-based composition separation of R32/R1234yf mixed working fluids applied in composition-adjustable organic Rankine cycle," Energy, Elsevier, vol. 284(C).
    3. Yiwei Wang & Lin Wang & Zhen Hu & Youli Li & Qiang Sun & Aixian Liu & Lanying Yang & Jing Gong & Xuqiang Guo, 2021. "The Thermodynamic and Kinetic Effects of Sodium Lignin Sulfonate on Ethylene Hydrate Formation," Energies, MDPI, vol. 14(11), pages 1-19, June.
    4. Chen, Chen & Yuan, Haoyu & Bi, Rongshan & Wang, Na & Li, Yujiao & He, Yan & Wang, Fei, 2022. "A novel conceptual design of LNG-sourced natural gas peak-shaving with gas hydrates as the medium," Energy, Elsevier, vol. 253(C).
    5. Zhang, Yue & Deng, Shuai & Zhao, Li & Nie, Xianhua & Xu, Weicong & He, Junnan, 2020. "Exploring a potential application of hydrate separation for composition adjustable combined cooling and power system," Applied Energy, Elsevier, vol. 268(C).
    6. Mu, Liang & Zhou, Ziqi & Zhao, Huixing & Zhu, Xiaohai & Cui, Qingyan, 2024. "High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions," Energy, Elsevier, vol. 290(C).
    7. Ouyang, Qian & Zheng, Junjie & Pandey, Jyoti Shanker & von Solms, Nicolas & Linga, Praveen, 2024. "Coupling amino acid injection and slow depressurization with hydrate swapping exploitation: An effective strategy to enhance in-situ CO2 storage in hydrate-bearing sediment," Applied Energy, Elsevier, vol. 366(C).
    8. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2023. "Kinetic evaluation of hydrate-based coalbed methane recovery process promoted by structure II thermodynamic promoters and amino acids," Energy, Elsevier, vol. 274(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    2. Wang, Yiwei & Du, Mei & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Chen, Bo & Chen, Guangjin & Sun, Changyu & Yang, Lanying, 2017. "Experiments and simulations for continuous recovery of methane from coal seam gas (CSG) utilizing hydrate formation," Energy, Elsevier, vol. 129(C), pages 28-41.
    3. Sa, Jeong-Hoon & Sum, Amadeu K., 2019. "Promoting gas hydrate formation with ice-nucleating additives for hydrate-based applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    4. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    5. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    6. Zhong, Dong-Liang & Wang, Wen-Chun & Zou, Zhen-Lin & Lu, Yi-Yu & Yan, Jin & Ding, Kun, 2018. "Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation," Applied Energy, Elsevier, vol. 227(C), pages 686-693.
    7. Yang, Mingjun & Zhou, Hang & Wang, Pengfei & Song, Yongchen, 2018. "Effects of additives on continuous hydrate-based flue gas separation," Applied Energy, Elsevier, vol. 221(C), pages 374-385.
    8. Mu, Liang & Zhou, Ziqi & Zhao, Huixing & Zhu, Xiaohai & Cui, Qingyan, 2024. "High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions," Energy, Elsevier, vol. 290(C).
    9. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    10. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    11. Cheng, Zucheng & Li, Shaohua & Liu, Yu & Zhang, Yi & Ling, Zheng & Yang, Mingjun & Jiang, Lanlan & Song, Yongchen, 2022. "Post-combustion CO2 capture and separation in flue gas based on hydrate technology：A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    12. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    13. Liu, Jun & Ding, Jia-Xiang & Liang, De-Qing, 2018. "Experimental study on hydrate-based gas separation of mixed CH4/CO2 using unstable ice in a silica gel bed," Energy, Elsevier, vol. 157(C), pages 54-64.
    14. Cai, Jing & Zhang, Yu & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2018. "Raman spectroscopic studies on carbon dioxide separation from fuel gas via clathrate hydrate in the presence of tetrahydrofuran," Applied Energy, Elsevier, vol. 214(C), pages 92-102.
    15. Liu, Fa-Ping & Li, Ai-Rong & Qing, Sheng-Lan & Luo, Ze-Dong & Ma, Yu-Ling, 2022. "Formation kinetics, mechanism of CO2 hydrate and its applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    16. Zang, Xiaoya & Wang, Jing & He, Yong & Zhou, Xuebing & Liang, Deqing, 2022. "Formation kinetics and microscopic characteristics of synthesized ternary gas mixture hydrates in TBAB aqueous solutions," Energy, Elsevier, vol. 245(C).
    17. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    18. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2023. "Kinetic evaluation of hydrate-based coalbed methane recovery process promoted by structure II thermodynamic promoters and amino acids," Energy, Elsevier, vol. 274(C).
    19. Xia, Zhi-ming & Li, Xiao-sen & Chen, Zhao-yang & Li, Gang & Cai, Jing & Wang, Yi & Yan, Ke-feng & Xu, Chun-gang, 2017. "Hydrate-based acidic gases capture for clean methane with new synergic additives," Applied Energy, Elsevier, vol. 207(C), pages 584-593.
    20. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:150:y:2018:i:c:p:377-395. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.