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Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation

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  • Wang, Yiwei
  • Deng, Ye
  • Guo, Xuqiang
  • Sun, Qiang
  • Liu, Aixian
  • Zhang, Guangqing
  • Yue, Gang
  • Yang, Lanying

Abstract

The effects of temperature, pressure, initial promoter concentration and coal seam gas/liquid ratio on the separation of methane from coal seam gas were experimentally investigated. Low temperature, high pressure and high promoter concentration lead to high separation efficiency and high recovery rate of CH4, but reduce the CH4 capture selectivity in hydrate. Experimental simulation of a three-stage separation shows that CH4 can be concentrated from 34.6 to 81.3 mol% in the dissociated gas, while its content is only 7.2 mol% in the residual gas. An innovative model was established to predict the separation performance. The modeling results reasonably match the experimental data in predicting the effects of different influential factors, with an average relative deviation of 2.83%, the maximum relative deviation 11.2%, and the average relative variance 0.1044. The modeling results of a three-stage separation process include 81.0 mol% of CH4 in the final dissociated gas and 5.5 mol% of CH4 in the final residual gas. The recovery rate of CH4 was 90.1 mol% and the separation factor was 73.0.

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  • Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    • Handle: RePEc:eee:energy:v:150:y:2018:i:c:p:377-395
    DOI: 10.1016/j.energy.2018.01.171
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    as
    1. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    2. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2016. "Energy and entropy analyses of hydrate dissociation in different scales of hydrate simulator," Energy, Elsevier, vol. 102(C), pages 176-186.
    3. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    4. Zhou, H. & de Sera, I.E.E. & Infante Ferreira, C.A., 2015. "Modelling and experimental validation of a fluidized bed based CO2 hydrate cold storage system," Applied Energy, Elsevier, vol. 158(C), pages 433-445.
    5. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    6. Yang, Ming, 2009. "Climate change and energy policies, coal and coalmine methane in China," Energy Policy, Elsevier, vol. 37(8), pages 2858-2869, August.
    7. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    8. Cai, Jing & Xu, Chun-Gang & Lin, Fu-Hua & Yu, Hai-Zhu & Li, Xiao-Sen, 2016. "A novel method for evaluating effects of promoters on hydrate formation," Energy, Elsevier, vol. 102(C), pages 567-575.
    9. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    10. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    11. Cai, Jing & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2017. "Hydrate-based methane separation from coal mine methane gas mixture by bubbling using the scale-up equipment," Applied Energy, Elsevier, vol. 204(C), pages 1526-1534.
    12. Pivezhani, Farzane & Roosta, Hadi & Dashti, Ali & Mazloumi, S. Hossein, 2016. "Investigation of CO2 hydrate formation conditions for determining the optimum CO2 storage rate and energy: Modeling and experimental study," Energy, Elsevier, vol. 113(C), pages 215-226.
    13. Huen Lee & Jong-won Lee & Do Youn Kim & Jeasung Park & Yu-Taek Seo & Huang Zeng & Igor L. Moudrakovski & Christopher I. Ratcliffe & John A. Ripmeester, 2005. "Tuning clathrate hydrates for hydrogen storage," Nature, Nature, vol. 434(7034), pages 743-746, April.
    14. Wang, Fei & Fu, Shanfei & Guo, Gang & Jia, Zhen-Zhen & Luo, Sheng-Jun & Guo, Rong-Bo, 2016. "Experimental study on hydrate-based CO2 removal from CH4/CO2 mixture," Energy, Elsevier, vol. 104(C), pages 76-84.
    15. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    16. Wang, Yiwei & Du, Mei & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Chen, Bo & Chen, Guangjin & Sun, Changyu & Yang, Lanying, 2017. "Experiments and simulations for continuous recovery of methane from coal seam gas (CSG) utilizing hydrate formation," Energy, Elsevier, vol. 129(C), pages 28-41.
    17. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2017. "An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application," Applied Energy, Elsevier, vol. 188(C), pages 190-199.
    18. Huang, Yuping & Zheng, Qipeng P. & Fan, Neng & Aminian, Kashy, 2014. "Optimal scheduling for enhanced coal bed methane production through CO2 injection," Applied Energy, Elsevier, vol. 113(C), pages 1475-1483.
    19. Hashimoto, Hidenori & Yamaguchi, Tsutomu & Kinoshita, Takahiro & Muromachi, Sanehiro, 2017. "Gas separation of flue gas by tetra-n-butylammonium bromide hydrates under moderate pressure conditions," Energy, Elsevier, vol. 129(C), pages 292-298.
    20. Bi, Yuehong & Chen, Jie & Miao, Zhen, 2016. "Thermodynamic optimization for dissociation process of gas hydrates," Energy, Elsevier, vol. 106(C), pages 270-276.
    21. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    22. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    23. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    24. Renault-Crispo, Jean-Sébastien & Coulombe, Sylvain & Servio, Phillip, 2017. "Kinetics of carbon dioxide gas hydrates with tetrabutylammonium bromide and functionalized multi-walled carbon nanotubes," Energy, Elsevier, vol. 128(C), pages 414-420.
    25. Sarhosis, V. & Jaya, A.A. & Thomas, H.R., 2016. "Economic modelling for coal bed methane production and electricity generation from deep virgin coal seams," Energy, Elsevier, vol. 107(C), pages 580-594.
    26. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2017. "Entropy generation analysis of hydrate dissociation by depressurization with horizontal well in different scales of hydrate reservoirs," Energy, Elsevier, vol. 125(C), pages 62-71.
    27. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    28. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    29. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    30. Kim, Shol & Lee, Seong Hyuk & Kang, Yong Tae, 2017. "Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application," Energy, Elsevier, vol. 120(C), pages 362-373.
    31. Xia, Zhi-Ming & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Yan, Ke-Feng & Xu, Chun-Gang & Lv, Qiu-Nan & Cai, Jing, 2016. "Hydrate-based CO2 capture and CH4 purification from simulated biogas with synergic additives based on gas solvent," Applied Energy, Elsevier, vol. 162(C), pages 1153-1159.
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