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Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids

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  • Yan, Jin
  • Lu, Yi-Yu
  • Zhong, Dong-Liang
  • Zou, Zhen-Lin
  • Li, Jian-Bo

Abstract

Coalbed methane (CBM) is a primary type of unconventional natural gas adsorbed in coal seams. Its amount around the world is estimated to be 260 × 1012 standard cubic meters (SCM). The low-concentration coalbed methane (LCCBM) with CH4 content less than 30 mol% is difficult to utilize because of its low combustion efficiency. This work reports an investigation of employing a graphite nanofluid to enhance CH4 recovery from LCCBM via gas hydrate formation. The CH4 separation efficiency was evaluated by comparing CH4 recovery ratio, the separation factor, and gas consumption with those reported in the literature, and the behavior of gas hydrate growth in graphite nanofluid was observed. The results indicated that hydrate nucleation was promoted when adding a mass fraction of 0.5% graphite nanoparticles (GNP) into the tetrahydrofuran and sodium dodecyl sulfate solution (THF/SDS solution) and gas consumption increased significantly in comparison with that obtained without GNP. The graphite nanofluid containing 0.5% GNP is preferred for CH4 separation among the three GNP mass concentrations (0.1%, 0.5%, and 3.0%) tested in this work. CH4 recovery ratio and the separation factor obtained in graphite nanofluid were higher than those obtained in other systems such as water-in-oil emulsions. CH4 concentration in LCCBM was increased from 30 mol% to 57.1 mol% via a one-stage hydrate based gas separation process. As a consequence, it has the potential to be an efficient approach to recover CH4 from LCCBM by forming gas hydrates in graphite nanofluid.

Suggested Citation

  • Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    • Handle: RePEc:eee:energy:v:180:y:2019:i:c:p:728-736
    DOI: 10.1016/j.energy.2019.05.117
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    1. Yang, Mingjun & Song, Yongchen & Jiang, Lanlan & Zhao, Yuechao & Ruan, Xuke & Zhang, Yi & Wang, Shanrong, 2014. "Hydrate-based technology for CO2 capture from fossil fuel power plants," Applied Energy, Elsevier, vol. 116(C), pages 26-40.
    2. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    3. Yang, Mingjun & Zhou, Hang & Wang, Pengfei & Song, Yongchen, 2018. "Effects of additives on continuous hydrate-based flue gas separation," Applied Energy, Elsevier, vol. 221(C), pages 374-385.
    4. Yi, Jie & Zhong, Dong-Liang & Yan, Jin & Lu, Yi-Yu, 2019. "Impacts of the surfactant sulfonated lignin on hydrate based CO2 capture from a CO2/CH4 gas mixture," Energy, Elsevier, vol. 171(C), pages 61-68.
    5. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    6. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    7. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    8. Huang, Yuping & Zheng, Qipeng P. & Fan, Neng & Aminian, Kashy, 2014. "Optimal scheduling for enhanced coal bed methane production through CO2 injection," Applied Energy, Elsevier, vol. 113(C), pages 1475-1483.
    9. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    10. Zhong, Dong-Liang & Wang, Wen-Chun & Zou, Zhen-Lin & Lu, Yi-Yu & Yan, Jin & Ding, Kun, 2018. "Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation," Applied Energy, Elsevier, vol. 227(C), pages 686-693.
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    6. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2021. "Coal mine gas separation of methane via clathrate hydrate process aided by tetrahydrofuran and amino acids," Applied Energy, Elsevier, vol. 287(C).
    7. Fan, Lurong & Xu, Jiuping, 2020. "Authority–enterprise equilibrium based mixed subsidy mechanism for carbon reduction and energy utilization in the coalbed methane industry," Energy Policy, Elsevier, vol. 147(C).
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