IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v120y2017icp192-198.html
   My bibliography  Save this article

Methane recovery from natural gas hydrate with simulated IGCC syngas

Author

Listed:
  • Ding, Ya-Long
  • Xu, Chun-Gang
  • Yu, Yi-Song
  • Li, Xiao-Sen

Abstract

Methane (CH4) recovery from natural gas hydrates (NGHs) by CO2-CH4 replacement is considered as a win-win technology for producing CH4 and sequestrating CO2 synchronously. In this investigation, simulated Integrated Gasification Combined Cycle (IGCC) syngas of CO2/H2 gas mixture is used to replace CH4 from simulated methane hydrate which is formed in pure water at 274.15 K and 4.5 MPa. The changes of concentrations of CH4, CO2 and H2 in gas phase during the replacement process are supervised by Gas Chromatograph (GC), and the gas hydrates are determined through in situ Raman. Meanwhile, the CH4 recovery and the replacement mechanism are qualitatively analyzed. The results indicate that, on one hand, the replacement consists of two steps, CH4 hydrate dissociation at the first and followed by CO2 hydrate formation, on the other hand, the CH4 recovery from CH4-CO2/H2 replacement is more than 71% which is significantly higher than that from CH4-CO2 replacement. Notably, no H2 is found in the hydrate phase in the replacement process, which implying that H2 does not compete with CH4 molecules occupying hydrate cages but plays promotion role in CO2-CH4 replacement.

Suggested Citation

  • Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    • Handle: RePEc:eee:energy:v:120:y:2017:i:c:p:192-198
    DOI: 10.1016/j.energy.2016.12.129
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216319430
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.12.129?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    2. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    3. Li, Gang & Li, Xiao-Sen & Wang, Yi & Zhang, Yu, 2011. "Production behavior of methane hydrate in porous media using huff and puff method in a novel three-dimensional simulator," Energy, Elsevier, vol. 36(5), pages 3170-3178.
    4. Descamps, C. & Bouallou, C. & Kanniche, M., 2008. "Efficiency of an Integrated Gasification Combined Cycle (IGCC) power plant including CO2 removal," Energy, Elsevier, vol. 33(6), pages 874-881.
    5. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    6. Christian Deusner & Nikolaus Bigalke & Elke Kossel & Matthias Haeckel, 2012. "Methane Production from Gas Hydrate Deposits through Injection of Supercritical CO 2," Energies, MDPI, vol. 5(7), pages 1-29, June.
    7. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    8. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xu, Chun-Gang & Yan, Ran & Fu, Juan & Zhang, Shao-Hong & Yan, Ke-Feng & Chen, Zhao-Yang & Xia, Zhi-Ming & Li, Xiao-Sen, 2019. "Insight into micro-mechanism of hydrate-based methane recovery and carbon dioxide capture from methane-carbon dioxide gas mixtures with thermal characterization," Applied Energy, Elsevier, vol. 239(C), pages 57-69.
    2. Gajanan, K. & Ranjith, P.G. & Yang, S.Q. & Xu, T., 2024. "Advances in research and developments on natural gas hydrate extraction with gas exchange," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    3. Shi, Lingli & Li, Junhui & He, Yong & Lu, Jingsheng & Long, Zhen & Liang, Deqing, 2023. "Memory effect test and analysis in methane hydrates reformation process," Energy, Elsevier, vol. 272(C).
    4. Tsypkin, G.G., 2021. "Analytical study of CO2–CH4 exchange in hydrate at high rates of carbon dioxide injection into a reservoir saturated with methane hydrate and gaseous methane," Energy, Elsevier, vol. 233(C).
    5. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    6. Roostaie, M. & Leonenko, Y., 2020. "Gas production from methane hydrates upon thermal stimulation; an analytical study employing radial coordinates," Energy, Elsevier, vol. 194(C).
    7. Pandey, Gaurav & Poothia, Tejaswa & Kumar, Asheesh, 2022. "Hydrate based carbon capture and sequestration (HBCCS): An innovative approach towards decarbonization," Applied Energy, Elsevier, vol. 326(C).
    8. Xu, Chun-Gang & Cai, Jing & Yu, Yi-Song & Yan, Ke-Feng & Li, Xiao-Sen, 2018. "Effect of pressure on methane recovery from natural gas hydrates by methane-carbon dioxide replacement," Applied Energy, Elsevier, vol. 217(C), pages 527-536.
    9. Chaturvedi, Krishna Raghav & Sinha, A.S.K. & Nair, Vishnu Chandrasekharan & Sharma, Tushar, 2021. "Enhanced carbon dioxide sequestration by direct injection of flue gas doped with hydrogen into hydrate reservoir: Possibility of natural gas production," Energy, Elsevier, vol. 227(C).
    10. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    11. Chen, Jun & Chen, Guang-Jin & Yuan, Qing & Deng, Bin & Tao, Li-Ming & Li, Chuan-Hua & Xiao, Sheng-Xiong & Jiang, Jian-Hong & Li, Xu & Li, Jia-Yuan, 2019. "Insights into induction time and agglomeration of methane hydrate formation in diesel oil dominated dispersed systems," Energy, Elsevier, vol. 170(C), pages 604-610.
    12. Cao, Yang & He, Boshu & Ding, Guangchao & Su, Liangbin & Duan, Zhipeng, 2017. "Energy and exergy investigation on two improved IGCC power plants with different CO2 capture schemes," Energy, Elsevier, vol. 140(P1), pages 47-57.
    13. Yu, Yi-Song & Xu, Chun-Gang & Li, Xiao-Sen, 2018. "Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system," Energy, Elsevier, vol. 143(C), pages 546-553.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    2. Yu, Yi-Song & Zhang, Qing-Zong & Li, Xiao-Sen & Chen, Chang & Zhou, Shi-Dong, 2020. "Kinetics, compositions and structures of carbon dioxide/hydrogen hydrate formation in the presence of cyclopentane," Applied Energy, Elsevier, vol. 265(C).
    3. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    4. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    5. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    6. Yang, Mingjun & Zhou, Hang & Wang, Pengfei & Song, Yongchen, 2018. "Effects of additives on continuous hydrate-based flue gas separation," Applied Energy, Elsevier, vol. 221(C), pages 374-385.
    7. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    8. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    9. Zhao, Jiafei & Yu, Tao & Song, Yongchen & Liu, Di & Liu, Weiguo & Liu, Yu & Yang, Mingjun & Ruan, Xuke & Li, Yanghui, 2013. "Numerical simulation of gas production from hydrate deposits using a single vertical well by depressurization in the Qilian Mountain permafrost, Qinghai-Tibet Plateau, China," Energy, Elsevier, vol. 52(C), pages 308-319.
    10. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    11. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    12. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    13. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    14. Li, Xiao-Sen & Xu, Chun-Gang & Zhang, Yu & Ruan, Xu-Ke & Li, Gang & Wang, Yi, 2016. "Investigation into gas production from natural gas hydrate: A review," Applied Energy, Elsevier, vol. 172(C), pages 286-322.
    15. Yu, Yi-Song & Xu, Chun-Gang & Li, Xiao-Sen, 2018. "Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system," Energy, Elsevier, vol. 143(C), pages 546-553.
    16. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    17. Xu, Chun-Gang & Li, Xiao-Sen & Lv, Qiu-Nan & Chen, Zhao-Yang & Cai, Jing, 2012. "Hydrate-based CO2 (carbon dioxide) capture from IGCC (integrated gasification combined cycle) synthesis gas using bubble method with a set of visual equipment," Energy, Elsevier, vol. 44(1), pages 358-366.
    18. Wang, Lanyun & Zhang, Yajuan & Xie, Huilong & Lu, Xiaoran & Wen, Xinglin & Liu, Zhen & Zhou, Huajian & Liu, Zejian & Xu, Yongliang, 2022. "Effect of voltage and initial temperature on thermodynamics and kinetics of CO2 hydrate formation in an electrostatic spraying reactor," Energy, Elsevier, vol. 239(PD).
    19. Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    20. Wang, Pengfei & Chen, Yiqi & Teng, Ying & An, Senyou & Li, Yun & Han, Meng & Yuan, Bao & Shen, Suling & Chen, Bin & Han, Songbai & Zhu, Jinlong & Zhu, Jianbo & Zhao, Yusheng & Xie, Heping, 2024. "A comprehensive review of hydrogen purification using a hydrate-based method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 194(C).

    More about this item

    Keywords

    CH4 hydrate; Replacement; IGCC syngas; Raman;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:120:y:2017:i:c:p:192-198. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.