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Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application

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  • Kim, Shol
  • Lee, Seong Hyuk
  • Kang, Yong Tae

Abstract

CO2 conversion by gas hydrate is considered one of most practical technologies in the fields of Carbon Capture, Utilization and Storage (CCUS). In this study, the effects of hydrate formation pressure and concentration of tetrahydrofuran (THF) on the CO2 + THF hydrate formation and dissociation performance are investigated, and the reduction of CO2 emission by applying the CO2 + THF hydrate for district cooling system is also evaluated. The CO2 capture ratio tends to increase with increasing the hydrate formation pressure and THF concentration. It is found that the CO2 regeneration rate increases with decreasing the formation pressure and the increasing rate decreases with time. It is concluded that the optimum conditions for the CO2 + THF hydrate formation and dissociation are 1.5 MPa, THF 1.5 mol% to use hydrate slurry as the working fluid for district cooling application. Also, the dissociation enthalpy of CO2 + THF hydrate was measured by using the high pressure micro-differential scanning calorimeter. The cycle simulation of hydrate cooling system is conducted, and the COP is estimated as 11.55. Finally, it is estimated that 20,684 tons of CO2 emission could be reduced per year if the CO2 + THF hydrate technology is applied to the district cooling system of 51,600 RT.

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  • Kim, Shol & Lee, Seong Hyuk & Kang, Yong Tae, 2017. "Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application," Energy, Elsevier, vol. 120(C), pages 362-373.
    • Handle: RePEc:eee:energy:v:120:y:2017:i:c:p:362-373
    DOI: 10.1016/j.energy.2016.11.086
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    1. Song, Yongchen & Cheng, Chuanxiao & Zhao, Jiafei & Zhu, Zihao & Liu, Weiguo & Yang, Mingjun & Xue, Kaihua, 2015. "Evaluation of gas production from methane hydrates using depressurization, thermal stimulation and combined methods," Applied Energy, Elsevier, vol. 145(C), pages 265-277.
    2. Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    3. Choi, Jae Woo & Chung, Jin Tack & Kang, Yong Tae, 2014. "CO2 hydrate formation at atmospheric pressure using high efficiency absorbent and surfactants," Energy, Elsevier, vol. 78(C), pages 869-876.
    4. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    5. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
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