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Experimental study on hydrate-based CO2 removal from CH4/CO2 mixture

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  • Wang, Fei
  • Fu, Shanfei
  • Guo, Gang
  • Jia, Zhen-Zhen
  • Luo, Sheng-Jun
  • Guo, Rong-Bo

Abstract

In this work, hydrate-based CO2 removal from a CH4/CO2 mixture was studied. CH4/CO2 led to faster hydrate formation than pure CH4, because the existence of CO2 resulted in easier hydrate nucleation. Kinetic separation of CO2 was observed in the CH4/CO2 hydrate formation with different initial CO2 proportions (1.83–27.76%) due to the higher CO2 affinity of formation of hydrates. However, the initial CO2 proportion of CH4/CO2 showed no obvious effects on the hydration ratio of CH4 and CO2 and the separation efficiency when the gas was superfluous in hydrate formation. In addition, hydrate-based multistage separation of CH4/CO2 was established and conducted at different initial pressures (4, 5 and 6 MPa). The CH4 proportions were increased from 72.24% to 97.30%, 97.22% and 97.14% after separation by four, five and seven stages at initial pressures of 4, 5, and 6 MPa, respectively.

Suggested Citation

  • Wang, Fei & Fu, Shanfei & Guo, Gang & Jia, Zhen-Zhen & Luo, Sheng-Jun & Guo, Rong-Bo, 2016. "Experimental study on hydrate-based CO2 removal from CH4/CO2 mixture," Energy, Elsevier, vol. 104(C), pages 76-84.
    • Handle: RePEc:eee:energy:v:104:y:2016:i:c:p:76-84
    DOI: 10.1016/j.energy.2016.03.107
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    1. Kondo, Wataru & Ohtsuka, Kaoru & Ohmura, Ryo & Takeya, Satoshi & Mori, Yasuhiko H., 2014. "Clathrate-hydrate formation from a hydrocarbon gas mixture: Compositional evolution of formed hydrate during an isobaric semi-batch hydrate-forming operation," Applied Energy, Elsevier, vol. 113(C), pages 864-871.
    2. Pöschl, Martina & Ward, Shane & Owende, Philip, 2010. "Evaluation of energy efficiency of various biogas production and utilization pathways," Applied Energy, Elsevier, vol. 87(11), pages 3305-3321, November.
    3. Luo, Gang & Wang, Wen & Angelidaki, Irini, 2014. "A new degassing membrane coupled upflow anaerobic sludge blanket (UASB) reactor to achieve in-situ biogas upgrading and recovery of dissolved CH4 from the anaerobic effluent," Applied Energy, Elsevier, vol. 132(C), pages 536-542.
    4. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    5. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    6. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    7. Chen, Shaoqing & Chen, Bin, 2014. "Energy efficiency and sustainability of complex biogas systems: A 3-level emergetic evaluation," Applied Energy, Elsevier, vol. 115(C), pages 151-163.
    8. Sun, Qie & Li, Hailong & Yan, Jinying & Liu, Longcheng & Yu, Zhixin & Yu, Xinhai, 2015. "Selection of appropriate biogas upgrading technology-a review of biogas cleaning, upgrading and utilisation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 521-532.
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