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CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters

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  • Kim, Soyoung
  • Choi, Sung-Deuk
  • Seo, Yongwon

Abstract

Tetrahydrofuran (THF) as a water-soluble sII clathrate former, cyclopentane (CP) as a water-insoluble sII clathrate former, and tetra n-butyl ammonium chloride (TBAC) as a water-soluble semiclathrate former were used to investigate their thermodynamic promotion effects on clathrate-based CO2 capture from simulated flue gas. The phase equilibria of CO2 (20%) + N2 (80%) + promoter clathrates at different promoter concentrations revealed that the presence of THF, CP, and TBAC could significantly reduce the clathrate formation pressure. THF solutions provided the highest gas uptake and steepest CO2 concentration changes in the vapor phase, whereas TBAC solutions showed the highest CO2 selectivity (∼61%) in the clathrate phase. CP solutions exhibited a slower formation rate, but their final gas uptake and CO2 selectivity in the clathrate phase were comparable to the THF solutions. Raman spectroscopy confirmed the enclathration of both CO2 and N2 in the clathrate cages and a structural transition due to the inclusion of promoters in the clathrate phase. The overall experimental results indicate that TBAC is a viable thermodynamic promoter for clathrate-based CO2 capture from simulated flue gas, considering the lower pressure requirement for clathrate formation, higher CO2 enrichment in the clathrate phase, non-toxicity, and non-volatility.

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  • Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    • Handle: RePEc:eee:energy:v:118:y:2017:i:c:p:950-956
    DOI: 10.1016/j.energy.2016.10.122
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    References listed on IDEAS

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    1. Mondal, Monoj Kumar & Balsora, Hemant Kumar & Varshney, Prachi, 2012. "Progress and trends in CO2 capture/separation technologies: A review," Energy, Elsevier, vol. 46(1), pages 431-441.
    2. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    3. Zhong, Dong-Liang & Wang, Jia-Le & Lu, Yi-Yu & Li, Zheng & Yan, Jin, 2016. "Precombustion CO2 capture using a hybrid process of adsorption and gas hydrate formation," Energy, Elsevier, vol. 102(C), pages 621-629.
    4. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    5. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    6. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    7. Kim, Soyoung & Seo, Yongwon, 2015. "Semiclathrate-based CO2 capture from flue gas mixtures: An experimental approach with thermodynamic and Raman spectroscopic analyses," Applied Energy, Elsevier, vol. 154(C), pages 987-994.
    8. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    9. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
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