IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v303y2021ics0306261921010485.html
   My bibliography  Save this article

Failure of cathode gas diffusion layer in 1 kW fuel cell stack under new European driving cycle

Author

Listed:
  • Yang, Yange
  • Zhou, Xiangyang
  • Li, Bing
  • Zhang, Cunman

Abstract

One of the main limitations of the proton exchange membrane fuel cells’ lifetime is the gradual diminishment of output power for the absence of a robust gas diffusion layer. Therefore, it is necessary to understand the decay process of the gas diffusion layer in actual working conditions. This study aims to investigate how the operation of automobile to push the degradation of gas diffusion layer by conducting a 1000 h in-situ durability test using a 1 kW stack under a simulative operation condition - New European Driving Cycle. The results demonstrate that the degradation of gas diffusion layer makes about 20% contribution to the decreased power density of proton exchange membrane fuel cells stack. The support failure caused by the collapse of structure and degradation of carbon fiber is the main reason for the attenuation of gas diffusion layer. Moreover, repeating operation of high voltage causes the structural collapse and the loss of polytetrafluoroethylene, which both change the ratio of hydrophilic surface to hydrophobic. Deeper analysis shows that the mass transport resistance of the degraded gas diffusion layer is almost three times than that of the fresh layer under the same current density due to decreased effective pore volume. Therefore, this work provides new ideas for the durability investigation of stack and gas diffusion layer.

Suggested Citation

  • Yang, Yange & Zhou, Xiangyang & Li, Bing & Zhang, Cunman, 2021. "Failure of cathode gas diffusion layer in 1 kW fuel cell stack under new European driving cycle," Applied Energy, Elsevier, vol. 303(C).
  • Handle: RePEc:eee:appene:v:303:y:2021:i:c:s0306261921010485
    DOI: 10.1016/j.apenergy.2021.117688
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921010485
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2021.117688?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Huu Linh Nguyen & Jeasu Han & Xuan Linh Nguyen & Sangseok Yu & Young-Mo Goo & Duc Dung Le, 2021. "Review of the Durability of Polymer Electrolyte Membrane Fuel Cell in Long-Term Operation: Main Influencing Parameters and Testing Protocols," Energies, MDPI, vol. 14(13), pages 1-34, July.
    2. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Chu, Tiankuo & Zhang, Ruofan & Wang, Yanbo & Ou, Mingyang & Xie, Meng & Shao, Hangyu & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2021. "Performance degradation and process engineering of the 10 kW proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 219(C).
    4. Zhang, Tong & Wang, Peiqi & Chen, Huicui & Pei, Pucheng, 2018. "A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition," Applied Energy, Elsevier, vol. 223(C), pages 249-262.
    5. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    6. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    7. Kurnia, Jundika C. & Sasmito, Agus P. & Shamim, Tariq, 2019. "Advances in proton exchange membrane fuel cell with dead-end anode operation: A review," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    8. Qiu, Diankai & Janßen, Holger & Peng, Linfa & Irmscher, Philipp & Lai, Xinmin & Lehnert, Werner, 2018. "Electrical resistance and microstructure of typical gas diffusion layers for proton exchange membrane fuel cell under compression," Applied Energy, Elsevier, vol. 231(C), pages 127-137.
    9. Lee, Yongtaek & Kim, Bosung & Kim, Yongchan & Li, Xianguo, 2011. "Degradation of gas diffusion layers through repetitive freezing," Applied Energy, Elsevier, vol. 88(12), pages 5111-5119.
    10. Shahgaldi, Samaneh & Ozden, Adnan & Li, Xianguo & Hamdullahpur, Feridun, 2020. "A scaled-up proton exchange membrane fuel cell with enhanced performance and durability," Applied Energy, Elsevier, vol. 268(C).
    11. Kong, Im Mo & Jung, Aeri & Kim, Min Soo, 2016. "Investigations on the double gas diffusion backing layer for performance improvement of self-humidified proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 176(C), pages 149-156.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yang, Yange & Li, Xiang & Chu, Tiankuo & Li, Bing & Zhang, Cunman, 2022. "Property evolution of gas diffusion layer and performance shrink of fuel cell during operation," Renewable Energy, Elsevier, vol. 194(C), pages 596-603.
    2. Yang, Yange & Li, Xiang & Tang, Fumin & Ming, Pingwen & Li, Bing & Zhang, Cunman, 2022. "Power evolution of fuel cell stack driven by anode gas diffusion layer degradation," Applied Energy, Elsevier, vol. 313(C).
    3. Shu, Qingzhu & Shi, Jiefu & Li, Zhuxin & Xing, Danmin & Sun, Xin & Zhang, Yong & Song, Shuqin & Tang, Yu & Yang, Shuxiu & Gao, Han & Xia, Chuxuan & Zhao, Mingming & Li, Xufeng & Zhao, Hong, 2024. "Failure of Au-coated metallic bipolar plates for fuel cell in a 3-kW stack under the new European driving cycle," Applied Energy, Elsevier, vol. 355(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Yange & Li, Xiang & Tang, Fumin & Ming, Pingwen & Li, Bing & Zhang, Cunman, 2022. "Power evolution of fuel cell stack driven by anode gas diffusion layer degradation," Applied Energy, Elsevier, vol. 313(C).
    2. Niu, Zhiqiang & Bao, Zhiming & Wu, Jingtian & Wang, Yun & Jiao, Kui, 2018. "Two-phase flow in the mixed-wettability gas diffusion layer of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 232(C), pages 443-450.
    3. Suárez, Christian & Toharias, Baltasar & Salva Aguirre, María & Chesalkin, Artem & Rosa, Felipe & Iranzo, Alfredo, 2023. "Experimental dynamic load cycling and current density measurements of different inlet/outlet configurations of a parallel-serpentine PEMFC," Energy, Elsevier, vol. 283(C).
    4. Zheng Huang & Laisuo Su & Yunjie Yang & Linsong Gao & Xinyu Liu & Heng Huang & Yubai Li & Yongchen Song, 2023. "Three-Dimensional Simulation on the Effects of Different Parameters and Pt Loading on the Long-Term Performance of Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 15(4), pages 1-22, February.
    5. Ahmed Mohmed Dafalla & Lin Wei & Bereket Tsegai Habte & Jian Guo & Fangming Jiang, 2022. "Membrane Electrode Assembly Degradation Modeling of Proton Exchange Membrane Fuel Cells: A Review," Energies, MDPI, vol. 15(23), pages 1-26, December.
    6. Wang, Mingkai & Pei, Pucheng & Xu, Yiming & Fan, Tengbo & Ren, Peng & Zhu, Zijing & Chen, Dongfang & Fu, Xi & Song, Xin & Wang, He, 2024. "CO-tolerance behaviors of proton exchange membrane fuel cell stacks with impure hydrogen fuel," Applied Energy, Elsevier, vol. 366(C).
    7. Zhao, Jian & Shahgaldi, Samaneh & Alaefour, Ibrahim & Xu, Qian & Li, Xianguo, 2018. "Gas permeability of catalyzed electrodes in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 209(C), pages 203-210.
    8. Sagar Roy & Smruti Ragunath, 2018. "Emerging Membrane Technologies for Water and Energy Sustainability: Future Prospects, Constraints and Challenges," Energies, MDPI, vol. 11(11), pages 1-32, November.
    9. Chu, Tiankuo & Tang, Qianwen & Wang, Qinpu & Wang, Yanbo & Du, Hong & Guo, YuQing & Li, Bing & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2023. "Experimental study on the effect of flow channel parameters on the durability of PEMFC stack and analysis of hydrogen crossover mechanism," Energy, Elsevier, vol. 264(C).
    10. Pei, Pucheng & Jia, Xiaoning & Xu, Huachi & Li, Pengcheng & Wu, Ziyao & Li, Yuehua & Ren, Peng & Chen, Dongfang & Huang, Shangwei, 2018. "The recovery mechanism of proton exchange membrane fuel cell in micro-current operation," Applied Energy, Elsevier, vol. 226(C), pages 1-9.
    11. Jiang, Wei & Zhang, Kai & Huang, Xing & Cai, Zhen & Zheng, Jinjin & Kai, Yue & Zheng, Bailin & Song, Ke, 2024. "Influence of clamping pressure on contact pressure uniformity and electrical output performance of proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 353(PA).
    12. Kong, Im Mo & Jung, Aeri & Kim, Young Sang & Kim, Min Soo, 2017. "Numerical investigation on double gas diffusion backing layer functionalized on water removal in a proton exchange membrane fuel cell," Energy, Elsevier, vol. 120(C), pages 478-487.
    13. Yu, Yang & Yu, Qinghua & Luo, RunSen & Chen, Sheng & Yang, Jiebo & Yan, Fuwu, 2024. "Degradation and polarization curve prediction of proton exchange membrane fuel cells: An interpretable model perspective," Applied Energy, Elsevier, vol. 365(C).
    14. Dinesh Kumar Madheswaran & Mohanraj Thangamuthu & Sakthivel Gnanasekaran & Suresh Gopi & Tamilvanan Ayyasamy & Sujit S. Pardeshi, 2023. "Powering the Future: Progress and Hurdles in Developing Proton Exchange Membrane Fuel Cell Components to Achieve Department of Energy Goals—A Systematic Review," Sustainability, MDPI, vol. 15(22), pages 1-24, November.
    15. Yan, Xiaohui & Lin, Chen & Zheng, Zhifeng & Chen, Junren & Wei, Guanghua & Zhang, Junliang, 2020. "Effect of clamping pressure on liquid-cooled PEMFC stack performance considering inhomogeneous gas diffusion layer compression," Applied Energy, Elsevier, vol. 258(C).
    16. Liu, Ze & Zhang, Baitao & Xu, Sichuan, 2022. "Research on air mass flow-pressure combined control and dynamic performance of fuel cell system for vehicles application," Applied Energy, Elsevier, vol. 309(C).
    17. Abdul Ghani Olabi & Tabbi Wilberforce & Abdulrahman Alanazi & Parag Vichare & Enas Taha Sayed & Hussein M. Maghrabie & Khaled Elsaid & Mohammad Ali Abdelkareem, 2022. "Novel Trends in Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 15(14), pages 1-35, July.
    18. Li, Linjun & Wang, Shixue & Yue, Like & Wang, Guozhuo, 2019. "Cold-start method for proton-exchange membrane fuel cells based on locally heating the cathode," Applied Energy, Elsevier, vol. 254(C).
    19. Yin, Cong & Song, Yating & Liu, Meiru & Gao, Yan & Li, Kai & Qiao, Zemin & Tang, Hao, 2022. "Investigation of proton exchange membrane fuel cell stack with inversely phased wavy flow field design," Applied Energy, Elsevier, vol. 305(C).
    20. Ma, Suhui & Qin, Yanzhou & Liu, Yuwen & Sun, Liancheng & Guo, Qiaoyu & Yin, Yan, 2022. "Delamination evolution of PEM fuel cell membrane/CL interface under asymmetric RH cycling and CL crack location," Applied Energy, Elsevier, vol. 310(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:303:y:2021:i:c:s0306261921010485. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.