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The recovery mechanism of proton exchange membrane fuel cell in micro-current operation

Author

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  • Pei, Pucheng
  • Jia, Xiaoning
  • Xu, Huachi
  • Li, Pengcheng
  • Wu, Ziyao
  • Li, Yuehua
  • Ren, Peng
  • Chen, Dongfang
  • Huang, Shangwei

Abstract

In the rapid development of new energy technologies, fuel cells have exhibited their great potential for green, low-carbon applications. However, the deterioration of their performance after a certain time of use is considered as a serious handicap for their wide application. In this study, a micro-current working condition was found to be effective in recovering the performance of proton exchange membrane fuel cell. To investigate the mechanism behind, a series of experiments were conducted to study the fuel cell’s performance recovery and its membrane electrode assembly parameters, and membrane water content and proton conductivity were simulated by a fuel cell model. The results showed that fuel cell saw a performance recovery by 40% after 20 hours’ micro-current operation. The reduced hydrogen crossover and ohmic resistance, and the increased electrochemical active surface area should explain the recovered performance of the fuel cell. In addition, the higher, more uniform membrane water content and proton conductivity found in simulation results may also contribute to fuel cell’s performance recovery. This study proposes a new recovery mechanism for proton exchange membrane fuel cell and offers plausible explanations, which is a new addition to fuel cell theory and provides a theoretical basis for on-line performance recovery of fuel cells.

Suggested Citation

  • Pei, Pucheng & Jia, Xiaoning & Xu, Huachi & Li, Pengcheng & Wu, Ziyao & Li, Yuehua & Ren, Peng & Chen, Dongfang & Huang, Shangwei, 2018. "The recovery mechanism of proton exchange membrane fuel cell in micro-current operation," Applied Energy, Elsevier, vol. 226(C), pages 1-9.
    • Handle: RePEc:eee:appene:v:226:y:2018:i:c:p:1-9
    DOI: 10.1016/j.apenergy.2018.05.100
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    References listed on IDEAS

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    Cited by:

    1. Ozden, Adnan & Shahgaldi, Samaneh & Li, Xianguo & Hamdullahpur, Feridun, 2019. "The impact of ionomer type on the morphological and microstructural degradations of proton exchange membrane fuel cell electrodes under freeze-thaw cycles," Applied Energy, Elsevier, vol. 238(C), pages 1048-1059.
    2. Zheng Huang & Laisuo Su & Yunjie Yang & Linsong Gao & Xinyu Liu & Heng Huang & Yubai Li & Yongchen Song, 2023. "Three-Dimensional Simulation on the Effects of Different Parameters and Pt Loading on the Long-Term Performance of Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 15(4), pages 1-22, February.
    3. Liu, Shihua & Li, Xiaoyang & Pang, Linjia & Geng, Tie & Guo, Yonggang & Jiang, Lin & Kang, Kejia & Wang, Xinchao & Liu, Zongyao, 2022. "Study on the effect of purging time on the performance of PEMFC with dead-ended anode under gravity," Renewable Energy, Elsevier, vol. 200(C), pages 1141-1151.
    4. Xuan, Lingfeng & Wang, Yancheng & Lan, Jinwei & Tao, Kai & Zhou, Caiying & Mei, Deqing, 2023. "Development of cathode ordered membrane electrode assembly based on TiO2 nanowire array and ultrasonic spraying," Energy, Elsevier, vol. 264(C).
    5. Chen, Kui & Laghrouche, Salah & Djerdir, Abdesslem, 2019. "Degradation model of proton exchange membrane fuel cell based on a novel hybrid method," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    6. Xu, Liangfei & Fang, Chuan & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2018. "Nonlinear dynamic mechanism modeling of a polymer electrolyte membrane fuel cell with dead-ended anode considering mass transport and actuator properties," Applied Energy, Elsevier, vol. 230(C), pages 106-121.
    7. Chen, Kui & Laghrouche, Salah & Djerdir, Abdesslem, 2021. "Prognosis of fuel cell degradation under different applications using wavelet analysis and nonlinear autoregressive exogenous neural network," Renewable Energy, Elsevier, vol. 179(C), pages 802-814.
    8. Huo, Sen & Jiao, Kui & Park, Jae Wan, 2019. "On the water transport behavior and phase transition mechanisms in cold start operation of PEM fuel cell," Applied Energy, Elsevier, vol. 233, pages 776-788.
    9. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    10. Chen, Hong & Zhan, Zhigang & Jiang, Panxing & Sun, Yahao & Liao, Liwen & Wan, Xiongbiao & Du, Qing & Chen, Xiaosong & Song, Hao & Zhu, Ruijie & Shu, Zhanhong & Li, Shang & Pan, Mu, 2022. "Whole life cycle performance degradation test and RUL prediction research of fuel cell MEA," Applied Energy, Elsevier, vol. 310(C).
    11. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.

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