IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v226y2018icp1-9.html
   My bibliography  Save this article

The recovery mechanism of proton exchange membrane fuel cell in micro-current operation

Author

Listed:
  • Pei, Pucheng
  • Jia, Xiaoning
  • Xu, Huachi
  • Li, Pengcheng
  • Wu, Ziyao
  • Li, Yuehua
  • Ren, Peng
  • Chen, Dongfang
  • Huang, Shangwei

Abstract

In the rapid development of new energy technologies, fuel cells have exhibited their great potential for green, low-carbon applications. However, the deterioration of their performance after a certain time of use is considered as a serious handicap for their wide application. In this study, a micro-current working condition was found to be effective in recovering the performance of proton exchange membrane fuel cell. To investigate the mechanism behind, a series of experiments were conducted to study the fuel cell’s performance recovery and its membrane electrode assembly parameters, and membrane water content and proton conductivity were simulated by a fuel cell model. The results showed that fuel cell saw a performance recovery by 40% after 20 hours’ micro-current operation. The reduced hydrogen crossover and ohmic resistance, and the increased electrochemical active surface area should explain the recovered performance of the fuel cell. In addition, the higher, more uniform membrane water content and proton conductivity found in simulation results may also contribute to fuel cell’s performance recovery. This study proposes a new recovery mechanism for proton exchange membrane fuel cell and offers plausible explanations, which is a new addition to fuel cell theory and provides a theoretical basis for on-line performance recovery of fuel cells.

Suggested Citation

  • Pei, Pucheng & Jia, Xiaoning & Xu, Huachi & Li, Pengcheng & Wu, Ziyao & Li, Yuehua & Ren, Peng & Chen, Dongfang & Huang, Shangwei, 2018. "The recovery mechanism of proton exchange membrane fuel cell in micro-current operation," Applied Energy, Elsevier, vol. 226(C), pages 1-9.
    • Handle: RePEc:eee:appene:v:226:y:2018:i:c:p:1-9
    DOI: 10.1016/j.apenergy.2018.05.100
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918308171
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.05.100?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.
    2. Chen, Huicui & Pei, Pucheng & Song, Mancun, 2015. "Lifetime prediction and the economic lifetime of Proton Exchange Membrane fuel cells," Applied Energy, Elsevier, vol. 142(C), pages 154-163.
    3. Han, Hun Sik & Cho, Changhwan & Kim, Seo Young & Hyun, Jae Min, 2013. "Performance evaluation of a polymer electrolyte membrane fuel cell system for powering portable freezer," Applied Energy, Elsevier, vol. 105(C), pages 125-137.
    4. Tsai, Shang-Wen & Chen, Yong-Song, 2017. "A mathematical model to study the energy efficiency of a proton exchange membrane fuel cell with a dead-ended anode," Applied Energy, Elsevier, vol. 188(C), pages 151-159.
    5. Shahgaldi, Samaneh & Alaefour, Ibrahim & Li, Xianguo, 2018. "The impact of short side chain ionomer on polymer electrolyte membrane fuel cell performance and durability," Applied Energy, Elsevier, vol. 217(C), pages 295-302.
    6. Zhang, Tong & Wang, Peiqi & Chen, Huicui & Pei, Pucheng, 2018. "A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition," Applied Energy, Elsevier, vol. 223(C), pages 249-262.
    7. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    8. Panha, Karachakorn & Fowler, Michael & Yuan, Xiao-Zi & Wang, Haijiang, 2012. "Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 90-97.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ozden, Adnan & Shahgaldi, Samaneh & Li, Xianguo & Hamdullahpur, Feridun, 2019. "The impact of ionomer type on the morphological and microstructural degradations of proton exchange membrane fuel cell electrodes under freeze-thaw cycles," Applied Energy, Elsevier, vol. 238(C), pages 1048-1059.
    2. Zheng Huang & Laisuo Su & Yunjie Yang & Linsong Gao & Xinyu Liu & Heng Huang & Yubai Li & Yongchen Song, 2023. "Three-Dimensional Simulation on the Effects of Different Parameters and Pt Loading on the Long-Term Performance of Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 15(4), pages 1-22, February.
    3. Liu, Shihua & Li, Xiaoyang & Pang, Linjia & Geng, Tie & Guo, Yonggang & Jiang, Lin & Kang, Kejia & Wang, Xinchao & Liu, Zongyao, 2022. "Study on the effect of purging time on the performance of PEMFC with dead-ended anode under gravity," Renewable Energy, Elsevier, vol. 200(C), pages 1141-1151.
    4. Huo, Sen & Jiao, Kui & Park, Jae Wan, 2019. "On the water transport behavior and phase transition mechanisms in cold start operation of PEM fuel cell," Applied Energy, Elsevier, vol. 233, pages 776-788.
    5. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    6. Chen, Hong & Zhan, Zhigang & Jiang, Panxing & Sun, Yahao & Liao, Liwen & Wan, Xiongbiao & Du, Qing & Chen, Xiaosong & Song, Hao & Zhu, Ruijie & Shu, Zhanhong & Li, Shang & Pan, Mu, 2022. "Whole life cycle performance degradation test and RUL prediction research of fuel cell MEA," Applied Energy, Elsevier, vol. 310(C).
    7. Xuan, Lingfeng & Wang, Yancheng & Lan, Jinwei & Tao, Kai & Zhou, Caiying & Mei, Deqing, 2023. "Development of cathode ordered membrane electrode assembly based on TiO2 nanowire array and ultrasonic spraying," Energy, Elsevier, vol. 264(C).
    8. Chen, Kui & Laghrouche, Salah & Djerdir, Abdesslem, 2019. "Degradation model of proton exchange membrane fuel cell based on a novel hybrid method," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    9. Xu, Liangfei & Fang, Chuan & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2018. "Nonlinear dynamic mechanism modeling of a polymer electrolyte membrane fuel cell with dead-ended anode considering mass transport and actuator properties," Applied Energy, Elsevier, vol. 230(C), pages 106-121.
    10. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    11. Chen, Kui & Laghrouche, Salah & Djerdir, Abdesslem, 2021. "Prognosis of fuel cell degradation under different applications using wavelet analysis and nonlinear autoregressive exogenous neural network," Renewable Energy, Elsevier, vol. 179(C), pages 802-814.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hu, Zunyan & Xu, Liangfei & Huang, Yiyuan & Li, Jianqiu & Ouyang, Minggao & Du, Xiaoli & Jiang, Hongliang, 2018. "Comprehensive analysis of galvanostatic charge method for fuel cell degradation diagnosis," Applied Energy, Elsevier, vol. 212(C), pages 1321-1332.
    2. Ma, Suhui & Qin, Yanzhou & Liu, Yuwen & Sun, Liancheng & Guo, Qiaoyu & Yin, Yan, 2022. "Delamination evolution of PEM fuel cell membrane/CL interface under asymmetric RH cycling and CL crack location," Applied Energy, Elsevier, vol. 310(C).
    3. Yu, Yang & Yu, Qinghua & Luo, RunSen & Chen, Sheng & Yang, Jiebo & Yan, Fuwu, 2024. "Degradation and polarization curve prediction of proton exchange membrane fuel cells: An interpretable model perspective," Applied Energy, Elsevier, vol. 365(C).
    4. Ke Song & Yimin Wang & Xiao Hu & Jing Cao, 2020. "Online Prediction of Vehicular Fuel Cell Residual Lifetime Based on Adaptive Extended Kalman Filter," Energies, MDPI, vol. 13(23), pages 1-21, November.
    5. Jouin, Marine & Bressel, Mathieu & Morando, Simon & Gouriveau, Rafael & Hissel, Daniel & Péra, Marie-Cécile & Zerhouni, Noureddine & Jemei, Samir & Hilairet, Mickael & Ould Bouamama, Belkacem, 2016. "Estimating the end-of-life of PEM fuel cells: Guidelines and metrics," Applied Energy, Elsevier, vol. 177(C), pages 87-97.
    6. Zuo, Jian & Lv, Hong & Zhou, Daming & Xue, Qiong & Jin, Liming & Zhou, Wei & Yang, Daijun & Zhang, Cunman, 2021. "Deep learning based prognostic framework towards proton exchange membrane fuel cell for automotive application," Applied Energy, Elsevier, vol. 281(C).
    7. Lorenzo, Charles & Bouquain, David & Hibon, Samuel & Hissel, Daniel, 2021. "Synthesis of degradation mechanisms and of their impacts on degradation rates on proton-exchange membrane fuel cells and lithium-ion nickel–manganese–cobalt batteries in hybrid transport applicati," Reliability Engineering and System Safety, Elsevier, vol. 212(C).
    8. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    9. Pei, Pucheng & Chen, Dongfang & Wu, Ziyao & Ren, Peng, 2019. "Nonlinear methods for evaluating and online predicting the lifetime of fuel cells," Applied Energy, Elsevier, vol. 254(C).
    10. Zou, Wei & Froning, Dieter & Shi, Yan & Lehnert, Werner, 2021. "An online adaptive model for the nonlinear dynamics of fuel cell voltage," Applied Energy, Elsevier, vol. 288(C).
    11. Zhang, Caizhi & Zeng, Tao & Wu, Qi & Deng, Chenghao & Chan, Siew Hwa & Liu, Zhixiang, 2021. "Improved efficiency maximization strategy for vehicular dual-stack fuel cell system considering load state of sub-stacks through predictive soft-loading," Renewable Energy, Elsevier, vol. 179(C), pages 929-944.
    12. Bressel, Mathieu & Hilairet, Mickael & Hissel, Daniel & Ould Bouamama, Belkacem, 2016. "Extended Kalman Filter for prognostic of Proton Exchange Membrane Fuel Cell," Applied Energy, Elsevier, vol. 164(C), pages 220-227.
    13. Yu, Xiao & Sandhu, Navjot S. & Yang, Zhenyi & Zheng, Ming, 2020. "Suitability of energy sources for automotive application – A review," Applied Energy, Elsevier, vol. 271(C).
    14. Sanghyun Yun & Jinwon Yun & Jaeyoung Han, 2023. "Development of a 470-Horsepower Fuel Cell–Battery Hybrid Xcient Dynamic Model Using Simscape TM," Energies, MDPI, vol. 16(24), pages 1-22, December.
    15. Nicu Bizon & Mircea Raceanu & Emmanouel Koudoumas & Adriana Marinoiu & Emmanuel Karapidakis & Elena Carcadea, 2020. "Renewable/Fuel Cell Hybrid Power System Operation Using Two Search Controllers of the Optimal Power Needed on the DC Bus," Energies, MDPI, vol. 13(22), pages 1-26, November.
    16. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    17. Ma, Rui & Yang, Tao & Breaz, Elena & Li, Zhongliang & Briois, Pascal & Gao, Fei, 2018. "Data-driven proton exchange membrane fuel cell degradation predication through deep learning method," Applied Energy, Elsevier, vol. 231(C), pages 102-115.
    18. Zhang, Tong & Wang, Peiqi & Chen, Huicui & Pei, Pucheng, 2018. "A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition," Applied Energy, Elsevier, vol. 223(C), pages 249-262.
    19. Chu, Tiankuo & Tang, Qianwen & Wang, Qinpu & Wang, Yanbo & Du, Hong & Guo, YuQing & Li, Bing & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2023. "Experimental study on the effect of flow channel parameters on the durability of PEMFC stack and analysis of hydrogen crossover mechanism," Energy, Elsevier, vol. 264(C).
    20. Pei, Pucheng & Meng, Yining & Chen, Dongfang & Ren, Peng & Wang, Mingkai & Wang, Xizhong, 2023. "Lifetime prediction method of proton exchange membrane fuel cells based on current degradation law," Energy, Elsevier, vol. 265(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:226:y:2018:i:c:p:1-9. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.