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Experimental study on the effect of flow channel parameters on the durability of PEMFC stack and analysis of hydrogen crossover mechanism

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  • Chu, Tiankuo
  • Tang, Qianwen
  • Wang, Qinpu
  • Wang, Yanbo
  • Du, Hong
  • Guo, YuQing
  • Li, Bing
  • Yang, Daijun
  • Ming, Pingwen
  • Zhang, Cunman

Abstract

Polymer electrolyte membrane fuel cell (PEMFC) is a leading technology with a bright future in the field of transportation. The bipolar plate structure has a profound impact on the mass and heat transfer of PEMFC. In this study, the durability tests of two stacks with different channel depths are carried out for 1000 h respectively on the 1 kW fuel cell stack test platform. We detect the overall performance change of the stack and characterize the membrane electrode assembly at the end of the test. Based on the first principle calculation, the mechanism of membrane degradation and hydrogen crossover is analyzed, and some durability experimental results are explained. The results show that the durability of the PEMFC with a shallow flow channel is worse, the voltage drops significantly, and the hydrogen crossover increases significantly after 500 h. The first principle calculation results reveal that the chemical structure change of the membrane is caused by the free radical attack. Hydrogen crossover promotes ∙H to attack carbon-fluorine bonds. This paper reveals the mechanism of hydrogen crossover and its influence on the catalyst layer, which is helpful to improve the durability of PEMFC.

Suggested Citation

  • Chu, Tiankuo & Tang, Qianwen & Wang, Qinpu & Wang, Yanbo & Du, Hong & Guo, YuQing & Li, Bing & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2023. "Experimental study on the effect of flow channel parameters on the durability of PEMFC stack and analysis of hydrogen crossover mechanism," Energy, Elsevier, vol. 264(C).
    • Handle: RePEc:eee:energy:v:264:y:2023:i:c:s0360544222031723
    DOI: 10.1016/j.energy.2022.126286
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    References listed on IDEAS

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    1. Huu Linh Nguyen & Jeasu Han & Xuan Linh Nguyen & Sangseok Yu & Young-Mo Goo & Duc Dung Le, 2021. "Review of the Durability of Polymer Electrolyte Membrane Fuel Cell in Long-Term Operation: Main Influencing Parameters and Testing Protocols," Energies, MDPI, vol. 14(13), pages 1-34, July.
    2. Sayadi, Parvin & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, Elsevier, vol. 94(C), pages 292-303.
    3. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    4. Chen, Qin & Zhang, Guobin & Zhang, Xuzhong & Sun, Cheng & Jiao, Kui & Wang, Yun, 2021. "Thermal management of polymer electrolyte membrane fuel cells: A review of cooling methods, material properties, and durability," Applied Energy, Elsevier, vol. 286(C).
    5. Wilberforce, Tabbi & El Hassan, Zaki & Ogungbemi, Emmanuel & Ijaodola, O. & Khatib, F.N. & Durrant, A. & Thompson, J. & Baroutaji, A. & Olabi, A.G., 2019. "A comprehensive study of the effect of bipolar plate (BP) geometry design on the performance of proton exchange membrane (PEM) fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 236-260.
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    Cited by:

    1. Yu, Xianxian & Cai, Shanshan & Luo, Xiaobing & Tu, Zhengkai, 2024. "Barrel effect in an air-cooled proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 286(C).
    2. Antoine Bäumler & Jianwen Meng & Abdelmoudjib Benterki & Toufik Azib & Moussa Boukhnifer, 2023. "A System-Level Modeling of PEMFC Considering Degradation Aspect towards a Diagnosis Process," Energies, MDPI, vol. 16(14), pages 1-19, July.
    3. Nima Ahmadi & Sajad Rezazadeh, 2023. "An Innovative Approach to Predict the Diffusion Rate of Reactant’s Effects on the Performance of the Polymer Electrolyte Membrane Fuel Cell," Mathematics, MDPI, vol. 11(19), pages 1-25, September.
    4. Mathias Heidinger & Eveline Kuhnert & Kurt Mayer & Daniel Sandu & Viktor Hacker & Merit Bodner, 2023. "Photometric Method to Determine Membrane Degradation in Polymer Electrolyte Fuel Cells," Energies, MDPI, vol. 16(4), pages 1-12, February.
    5. Chen, Chaogang & Gao, Yuan, 2024. "Using multi-threshold non-local means joint distribution method to analysis the spatial distribution patterns of binder and fibers in gas diffusion layers of fuel cells," Applied Energy, Elsevier, vol. 358(C).

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