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Earth-abundant redox couples using durable boron doped diamond electrodes: Beyond vanadium redox couples

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  • Bates, Alex M.
  • Paxton, William F.
  • Spurgeon, Joshua M.
  • Park, Sam D.
  • Sunkara, Mahendra K.

Abstract

In this study, boron doped diamond (BDD) is utilized as a redox flow battery (RFB) electrode, demonstrating its capability with several low-cost redox couples for the first time. Active species cost, electrode corrosion, energy density, and power density are the current issues hindering the widespread adoption of RFBs. Several high-potential and low-cost redox couples, including Ce3+/Ce4+ and Mn2+/Mn3+, are shown to exhibit low overpotentials, high efficiency, and good cyclability on BDD electrodes. Using the Ce3+/Ce4+ redox couple, a formal potential of 1.67 V vs. SHE and a peak separation of 288 mV during cyclic voltammetry was obtained. Low-cost redox species significantly decrease RFB system cost while high potentials increase energy and power density. Demonstrated here, high potentials cannot be supported by traditional carbon-based RFB electrodes due to significant corrosion and gas evolution; however, the inherent properties of BDD negate this effect. This study exhibits the potential of BDD, as an alternative to traditional carbon-based electrodes, to enable a long cycle life, at high coulombic efficiencies, and with high-potential and low-cost redox couples.

Suggested Citation

  • Bates, Alex M. & Paxton, William F. & Spurgeon, Joshua M. & Park, Sam D. & Sunkara, Mahendra K., 2021. "Earth-abundant redox couples using durable boron doped diamond electrodes: Beyond vanadium redox couples," Applied Energy, Elsevier, vol. 282(PB).
    • Handle: RePEc:eee:appene:v:282:y:2021:i:pb:s0306261920316433
    DOI: 10.1016/j.apenergy.2020.116252
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    References listed on IDEAS

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