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Hydrodynamic and Electrochemical Analysis of Compression and Flow Field Designs in Vanadium Redox Flow Batteries

Author

Listed:
  • Snigdha Saha

    (Department of Chemical Engineering, National Institute of Technology Warangal, Warangal 506004, Telangana, India)

  • Kranthi Kumar Maniam

    (Materials Innovation Centre, School of Engineering, University of Leicester, Leicester LE1 7RH, UK)

  • Shiladitya Paul

    (Materials Innovation Centre, School of Engineering, University of Leicester, Leicester LE1 7RH, UK
    Materials Performance and Integrity Group, TWI, Granta Park, Cambridge CB21 6AL, UK)

  • Venkata Suresh Patnaikuni

    (Department of Chemical Engineering, National Institute of Technology Warangal, Warangal 506004, Telangana, India)

Abstract

This numerical study investigates compression and flow field design effects on electrode behaviour in vanadium redox flow batteries (VRFBs). Through 3D simulations and analysis of various flow field designs, including conventional, serpentine, interdigitated, and parallel configurations, this study investigates three compression scenarios: uncompressed, non-homogeneously compressed, and homogeneously compressed electrodes. Hydrodynamic and electrochemical analyses reveal the impact on velocity, pressure, current density, overpotential, and charge–discharge performance. Interdigitated flow field is found to display the lowest charging potential and highest discharging potential among all flow fields under all three compression scenarios. Moreover, uncompressed electrode condition shows the conservative estimates of an average charging potential of 1.3647 V and average discharging potential of 1.3231 V in the case of interdigitated flow field, while compressed electrode condition and the non-homogeneously compressed electrode condition show an average charging potential of 1.3922 V and 1.3777 V, and an average discharging potential of 1.3019 V and 1.3224 V, respectively. Results highlight the significance of non-uniform compression while modelling and analysing the performance of VRFBs as it is a more realistic representation compared to the no-compression or homogeneous compression of the electrodes. The findings of this work provide insights for optimising VRFB performance by considering compression and flow field design.

Suggested Citation

  • Snigdha Saha & Kranthi Kumar Maniam & Shiladitya Paul & Venkata Suresh Patnaikuni, 2023. "Hydrodynamic and Electrochemical Analysis of Compression and Flow Field Designs in Vanadium Redox Flow Batteries," Energies, MDPI, vol. 16(17), pages 1-33, August.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:17:p:6311-:d:1229221
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    References listed on IDEAS

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    1. Igor Iwakiri & Tiago Antunes & Helena Almeida & João P. Sousa & Rita Bacelar Figueira & Adélio Mendes, 2021. "Redox Flow Batteries: Materials, Design and Prospects," Energies, MDPI, vol. 14(18), pages 1-45, September.
    2. Yin, Cong & Gao, Yan & Guo, Shaoyun & Tang, Hao, 2014. "A coupled three dimensional model of vanadium redox flow battery for flow field designs," Energy, Elsevier, vol. 74(C), pages 886-895.
    3. Chin-Lung Hsieh & Po-Hong Tsai & Ning-Yih Hsu & Yong-Song Chen, 2019. "Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery," Energies, MDPI, vol. 12(2), pages 1-11, January.
    4. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Numerical study on vanadium redox flow battery performance with non-uniformly compressed electrode and serpentine flow field," Applied Energy, Elsevier, vol. 220(C), pages 106-116.
    5. Chih-Hsun Chang & Han-Wen Chou & Ning-Yih Hsu & Yong-Song Chen, 2016. "Development of Integrally Molded Bipolar Plates for All-Vanadium Redox Flow Batteries," Energies, MDPI, vol. 9(5), pages 1-10, May.
    6. Duan, Z.N. & Qu, Z.G. & Wang, Q. & Wang, J.J., 2019. "Structural modification of vanadium redox flow battery with high electrochemical corrosion resistance," Applied Energy, Elsevier, vol. 250(C), pages 1632-1640.
    7. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
    8. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
    9. Tugrul Y. Ertugrul & Michael. C. Daugherty & Jacob R. Houser & Douglas S. Aaron & Matthew M. Mench, 2020. "Computational and Experimental Study of Convection in a Vanadium Redox Flow Battery Strip Cell Architecture," Energies, MDPI, vol. 13(18), pages 1-17, September.
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