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Towards uniform distributions of reactants via the aligned electrode design for vanadium redox flow batteries

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  • Sun, J.
  • Jiang, H.R.
  • Zhang, B.W.
  • Chao, C.Y.H.
  • Zhao, T.S.

Abstract

Enhancing the hydraulic permeability of electrodes along both the through-plane and in-plane directions is essential in flow-field structured vanadium redox flow batteries, as it can promote uniform distributions of reactants, lower the concentration overpotential, and therefore improve battery performances. In this work, uniaxially-aligned carbon fiber electrodes with the fiber diameter ranging from 7 to 12 µm (average ~10 µm) are fabricated by electrospinning method. Attributed to the enhanced permeability of the aligned structure, the battery assembled with the prepared electrodes exhibits an energy efficiency of 84.4% at a current density of 100 mA cm−2, which is 13.2% higher than that with conventional electrospun fiber electrodes. The permeability in the in-plane direction is further tailored by adjusting the orientation of aligned fibers against the flow channels. Results show that when the orientation of aligned fibers is perpendicular to the direction of flow channels, the battery delivers the largest discharge capacity and the highest limiting current density (~900 mA cm−2). Such an enhancement in the battery performance can be ascribed to the more uniform in-plane distribution of reactants and current by maximizing the permeability along the direction vertical to the flow channels, as evidenced by a three-dimensional model.

Suggested Citation

  • Sun, J. & Jiang, H.R. & Zhang, B.W. & Chao, C.Y.H. & Zhao, T.S., 2020. "Towards uniform distributions of reactants via the aligned electrode design for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 259(C).
    • Handle: RePEc:eee:appene:v:259:y:2020:i:c:s0306261919318859
    DOI: 10.1016/j.apenergy.2019.114198
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    References listed on IDEAS

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    1. Zeng, Yikai & Yang, Zhifei & Lu, Fei & Xie, Yongliang, 2019. "A novel tin-bromine redox flow battery for large-scale energy storage," Applied Energy, Elsevier, vol. 255(C).
    2. Zeng, Yikai & Li, Fenghao & Lu, Fei & Zhou, Xuelong & Yuan, Yanping & Cao, Xiaoling & Xiang, Bo, 2019. "A hierarchical interdigitated flow field design for scale-up of high-performance redox flow batteries," Applied Energy, Elsevier, vol. 238(C), pages 435-441.
    3. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    4. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
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    Citations

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    Cited by:

    1. Kurilovich, Aleksandr A. & Trovò, Andrea & Pugach, Mikhail & Stevenson, Keith J. & Guarnieri, Massimo, 2022. "Prospect of modeling industrial scale flow batteries – From experimental data to accurate overpotential identification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    2. Hsu, Ning-Yih & Devi, Nitika & Lin, Yu-I & Hu, Yi-Hsin & Ku, Hung-Hsien & Arpornwichanop, Amornchai & Chen, Yong-Song, 2022. "Study on the effect of electrode configuration on the performance of a hydrogen/vanadium redox flow battery," Renewable Energy, Elsevier, vol. 190(C), pages 658-663.
    3. Zhang, Kaiyue & Xiong, Jing & Yan, Chuanwei & Tang, Ao, 2020. "In-situ measurement of electrode kinetics in porous electrode for vanadium flow batteries using symmetrical cell design," Applied Energy, Elsevier, vol. 272(C).
    4. Wan, Shuaibin & Liang, Xiongwei & Jiang, Haoran & Sun, Jing & Djilali, Ned & Zhao, Tianshou, 2021. "A coupled machine learning and genetic algorithm approach to the design of porous electrodes for redox flow batteries," Applied Energy, Elsevier, vol. 298(C).
    5. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
    6. Sun, J. & Jiang, H.R. & Wu, M.C. & Fan, X.Z. & Chao, C.Y.H. & Zhao, T.S., 2020. "Aligned hierarchical electrodes for high-performance aqueous redox flow battery," Applied Energy, Elsevier, vol. 271(C).

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